Thallium acetate 醋酸铊

CAS 563-68-8 MFCD00013045

化学结构图

563-68-8
SMILES: CC(=O)O[TlH2]

化学属性

Mol. FormulaC2H3O2.Tl
Mol. Weight263.42
Melting Point131°
TSCAYes
SolubilitySoluble in water, alcohol
Density3.77

别名和识别编码

Chemical NameThallium acetate
Synonym ACETIC ACID THALLIUM SALT ACETIC ACID THALLOUS SALT ACETIC ACID, THALLIUM(I) SALT Acetic acid, thallium(1) salt Acetic acid, thallium(1+) salt Acetic acid, thallium(I) salt Aceticacid,thallium(1+)salt Essigsäure Thallium(I)-Salz RCRA waste number U214 Rcra waste number U214 THALLIUM ACETATE THALLIUM ACETATE (OUS) THALLIUM(+1)ACETATE THALLIUM(I) ACETATE THALLIUM(OUS) ACETATE THALLOUS ACETATE Thallium (I) acetate Thallium acetate Thallium acetate (TlOAc) Thallium acetate Tl(OAc) Thallium monoacetate Thallium(1+) acetate Thallium(I) acetate Thallium(I)-acetat Thallous acetate acetic acid thallium(I) salt
Beilstein Registry Number3693914
PubChem Substance ID11247
CAS Number563-68-8
EC Number209-257-5
MDL NumberMFCD00013045
Merck Number14,9257
Chemical Name Translation醋酸铊
Wiswesser Line NotationQV1 &-TL-
InChIInChI=1S/C2H4O2.Tl/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1
LabNetwork Molecule IDLN02144315
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分类

  • Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors, Thallium
  • {uni_hamburg} no charge; carboxylate; 2fragments; ionic
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Thallium

相关文献及参考

  • Merck 14 ,9257
  • Beil. 2 ,III,195
  • Aldrich MSDS 1 , 1693:B / Corp MSDS 1 (2), 3315:C / RegBook 1 (1), 603:J / Sax 6 , 2555 / Structure Index 1 , 86:C:7
  • Short: III/10a Title: Structure Data of Organic Crystals: C ... C 15 Author: Schudt-Weitz, G.; Strell, I. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/10a Year: 1985 ISBN: 3-540-07834-7 ISBN: 978-3-540-07834-0 Internet Resource: DOI:10.1007/b19984 RefComment: XXII, 634 pages. Hardcover Abstract: The volume includes an alphabetical index of all substances and a separate "ring index" with all cyclic compounds.
  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.
  • Short: LC Title: LiqCryst 4.6 - Database of Liquid Crystals Author: Vill, V. Year: 2005 Keyword: Flüssigkristalle; LCD; Phasenumwandlung Internet Resource: http://liqcryst.chemie.uni-hamburg.de/
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P203
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P316
  • P304+P340
  • P307+P311
  • P308+P313
  • P308+P316
  • P309+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P316
  • P318
  • P319
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗(见本标签上的)。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
WGK Germany3
GHS Symbol
Signal word Danger
Hazard statements
  • H300 Fatal if swallowed 吞食致命
  • H330 Fatal if inhaled 吸入致命
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Hazard Codes T+,N
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
UN Number UN1707 UN 1707 6.1/PG 2
Risk Statements
  • R51/53
  • R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒
  • R33 Danger of cumulative effects 有累积作用的危险
Storage condition Store at RT. Hygroscopic
RTECSAJ5425000
Packing GroupII
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Class6.1
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 13 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem. Rep.)  Volume(issue)/page/year: 4,1406,1935

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 26 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   21,399,1960

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Human - child
DOSE/DURATION           : 8 mg/kg
TOXIC EFFECTS :
   Skin and Appendages - hair
   Behavioral - anorexia (human)
   Kidney, Ureter, Bladder - urine volume decreased
REFERENCE :
   AJCPAI American Journal of Clinical Pathology.  (Lippincott/Harper, Journal
   Fulfillment Dept., 2350 Virginia Ave., Hagerstown, MD 21740)  V.1-    1931-
   Volume(issue)/page/year: 13,422,1943

T

{

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 9 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   21,399,1960

TYPE OF TEST            : LDLo - Lowe

TYPE OF TEST

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - hamster Embryo
DOSE/DURATION           : 100 umol/L
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   39,193,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 30 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 24(2),46A,1981

其他信息

  • 灭火剂:水、泡沫、砂土、二氧化碳
  • MOL 文件:563-68-8.mol
  • MSDS 信息:乙酸亚铊(563-68-8).msds
  • 毒性分级:剧毒
  • Sigma Aldrich:563-68-8(sigmaaldrich)
  • 可燃性危险特性:遇明火、高热可燃; 受热产生有毒含铊化物烟雾
  • 用途一:用于比重液的配制
  • 类别:有毒物品
  • 敏感性:Hygroscopic
  • 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
  • 乙酸铊价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80126214 乙酸铊(剧毒) 25g 500元 2011/08/23 80126224 乙酸铊(剧毒) 25g 350元 2011/08/23 K8820401 乙酸铊(剧毒) 5g 400元
  • Alfa Aesar:醋酸铊(I),Puratronic|r,99.9985%(metalsbasis) Thallium(I) acetate, Puratronic, 99.9985% (metals basis)(563-68-8)
  • 急性毒性:口服- 大鼠 LD50: 41.3 毫克/ 公斤; 口服- 小鼠 LD50: 35 毫克/ 公斤
  • 职业标准:TLV-TWA 0.1 毫克(铊)/ 立方米
  • 外观性质:白色针状结晶,易潮解。
  • Acros Organics:乙酸铊 Thallous acetate, 99%(563-68-8)

系列性分类


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