Alternative reagent with enhanced stability for many of the reactions conventionally carried out using 3-Chloroperoxybenzoic acid, L00286. For a comparative study of the two reagents, see: Synthesis, 1015 (1987).
For regioselective epoxidation of allylic alcohols in water, see: J. Org. Chem., 57, 1198 (1992).
Cyclic ketones undergo the Baeyer-Villiger reaction to give lactones in high yield, in acetonitrile: Synth. Commun., 26, 4591 (1996), or in methanol-water in the presence of NaHCO3: J. Org. Chem., 62, 2633 (1997); the latter method has been used in the synthesis of massoia lactone.
安全信息
Safety Statements
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
S37 Wear suitable gloves 戴适当手套;
Risk Statements
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性