Silver(I) 2,2,2-trifluoroacetate 三氟乙酸银

CAS 2966-50-9 MFCD00013199

化学结构图

2966-50-9
SMILES: O=C([O-])C(F)(F)F.[Ag+]

化学属性

Mol. FormulaC2AgF3O2
Mol. Weight220.88
Melting Point257-260°C
TSCAT
Solubility可溶
Boiling Point72.2°C at 760 mmHg

别名和识别编码

Chemical NameSilver(I) 2,2,2-trifluoroacetate
CAS Number2966-50-9
Alfabeta NameTRIFLUOROACETICACIDSILVERSALT
MDL NumberMFCD00013199
Synonym Silver(I) 2,2,2-trifluoroacetate {LY} Silver(I) 2,2,2-trifluoroacetate {} {LY} Silver(I) 2,2,2-trifluoroacetate {} {} {LY} Silver(I) 2,2,2-trifluoroacetate {} {} {} {LY} Silver(I) 2,2,2-trifluoroacetate {} {} {} {} {LY} Silver(I) 2,2,2-trifluoroacetate {} {} {} {} {} {LY} Silver(I) 2,2,2-trifluoroacetate {} {} {} {} {} {} {LY} Silver(I) 2,2,2-trifluoroacetate {} {} {} {} {} {} {} {LY} Silver(I) 2,2,2-trifluoroacetate {} {} {} {} {} {} {} {} {LY} Silver(I) 2,2,2-trifluoroacetate {} {} {} {} {} {} {} {} {} {LY} Silver(I) 2,2,2-trifluoroacetate {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) 2,2,2-trifluoroacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) 2,2,2-trifluoroacetate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) 2,2,2-trifluoroacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) 2,2,2-trifluoroacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver(I) 2,2,2-trifluoroa
Beilstein Registry Number3634022
PubChem Substance ID76299
EC Number221-004-0
Chemical Name Translation三氟乙酸银
InChIKeyKZJPVUDYAMEDRM-UHFFFAOYSA-M
LabNetwork Molecule IDLN00115869
InChIInChI=1S/C2HF3O2.Ag/c3-2(4,5)1(6)7;/h(H,6,7);/q;+1/p-1
Canonical SMILESO=C(C(F)(F)F)O[Ag]
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分类

  • Catalysis and Inorganic Chemistry, Chemical Synthesis, Gold Catalysis, Materials Science, Micro/NanoElectronics, Silver, Silver Additives, Solution Deposition Precursors
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics,
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Silver, Silver Additives, Solution Deposition Precursors, 材料科学
  • {SNA} Micro/NanoElectronics, Silver, Solution Deposition Precursors, 材料科学
  • {SNA} Materials Science, Micro/NanoElectronics, Silver, Solution Deposition Precursors

产品应用

  • 在有机合成中用作氧化腙的催化剂与碘合用作为芳环碘化及区域选择性烷基化反应的催化剂。

相关文献及参考

  • Beil. 2 ,IV,461
  • Corp MSDS 1 (2), 3099:B / FT-IR 1 (2), 1242:A / FT-IR 2 (1), 876:B / IR-Spectra (3), 327:G / IR-Spectra (2), 294:D / RegBook 1 (1), 623:I / Structure Index 1 , 90:C:6
  • Fieser 1 ,1018 / Fieser 7 ,323 / Fieser 8 ,444 / Fieser 10 ,355 / Fieser 11 ,557 / Fieser 12 ,529 / Fieser 16 ,301 / Fieser 17 ,313
  • Helv. Chim. Acta 72 , 1362, (1989)

安全信息

Warnings LIGHT SENSITIVE, HYGROSCOPIC, TOXIC
Precautionary statements
  • P305+P351+P338
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes Xi;N Xi,T,N Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S37 Wear suitable gloves 戴适当手套；
UN Number UN3077
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R50 Very toxic to aquatic organisms 对水生生物极毒
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Light Sensitive & Hygroscopic {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C,
Packing GroupIII

其他信息

  • 图谱信息:三氟乙酸银(2966-50-9)红外图谱(IR2) 三氟乙酸银(2966-50-9)红外图谱(IR1)
  • Sigma Aldrich:2966-50-9(sigmaaldrich)
  • Hazard Note:Toxic/Hygroscopic
  • TSCA:T
  • MOL 文件:2966-50-9.mol
  • Alfa Aesar:三氟乙酸银(I),98% Silver trifluoroacetate, 98%(2966-50-9)
  • 用途一:在有机合成中用作氧化腙的催化剂与碘合用作为芳环碘化及区域选择性烷基化反应的催化剂。
  • 外观性质:无色固体。熔点：257-260℃
  • 敏感性:Hygroscopic
  • F:3-8
  • Acros Organics:三氟乙酸银 Trifluoroacetic acid, silver salt, 98%(2966-50-9)
  • 三氟乙酸银价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 139730250 三氟乙酸银 Trifluoroacetic acid, silver salt 98% 25 GR 1736元 2010/06/21 139730050 三氟乙酸银 Trifluoroacetic acid, silver salt 98% 5 GR 485元 2010/05/25 13933 三氟乙酸银(I), 98% Silver trifluoroacetate, 98% 5g 440元
  • MSDS 信息:Silver trifluoroacetate(2966-50-9).msds
  • 海关编码:28432900

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Silver 银
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Silver 银
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Solution Deposition Precursors - Micro/NanoElectronics
  4. Silver - Solution Deposition Precursors

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