2-(4-fluorophenyl)-2-oxoacetaldehyde 2-(4-氟苯基)-2-氧代乙醛
CAS 403-32-7 MFCD01320770
化学结构图
SMILES: O=CC(=O)c1ccc(F)cc1
化学属性
| Mol. Formula | C8H5FO2 |
|---|---|
| Mol. Weight | 152.13 |
| Boiling Point | 115°/35mm |
| Melting Point | 80-82° |
| TSCA | No |
别名和识别编码
| Chemical Name | 2-(4-fluorophenyl)-2-oxoacetaldehyde |
|---|---|
| CAS Number | 403-32-7 |
| Alfabeta Name | FLUOROPHENYLGLYOXALHYDRATE 4- |
| MDL Number | MFCD01320770 |
| Beilstein Registry Number | 2354778 |
| Chemical Name Translation | 2-(4-氟苯基)-2-氧代乙醛 |
| Synonym | 4-Fluoro-alpha-oxobenzeneacetaldehyde |
| InChIKey | IPWSCROFORAGJW-UHFFFAOYSA-N |
| PubChem Substance ID | 101249 |
| InChI | InChI=1S/C8H5FO2/c9-7-3-1-6(2-4-7)8(11)5-10/h1-5H |
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相关文献及参考
- Aryl glyoxals have been used in the formation of 1,5-disubstituted hydantoins and thiohydantoins; J. Heterocycl. Chem., 18, 1651 (1981); the reaction was subsequently reported to be accelerated under solvent-free conditions using microwaves: Synthesis, 75 (2002).
- Also find extensive use in multi-component reactions to obtain a wide variety of heterocycles including butenolides: Org. Lett., 3, 2875 (2001); oxazoles via a Passerini reaction: Liebigs Ann. Chem., 1107 (1991), and pyrazines via a four-component Ugi reaction: Synthesis, 1553 (2003).
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 681 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - respiratory depression Nutritional and Gross Metabolic - body temperature decrease REFERENCE : JICSAH Journal of the Indian Chemical Society. (Indian Chemical Soc., 92, Acharya Prafulla Chandra Rd., Calcutta 700009, India) V.5- 1928- Volume(issue)/page/year: 60,369,1983
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