Bis(Cyclopentadienyl)Magnesium 双(环戊二烯)镁

CAS 1284-72-6 MFCD00134487

化学结构图

1284-72-6
SMILES: [C-]1=CC=CC1.[C-]1=CC=CC1.[Mg+2]

化学属性

TSCANo
Flash Point290°C
Mol. FormulaC10H10Mg
Mol. Weight154.49
Appearance white to light pink xtl. white to light-pink xtl.
Stabilityair sensitive, moisture sensitive
Boiling Point290 °C at 760 mmHg
Melting Point180 °C

别名和识别编码

Chemical NameBis(Cyclopentadienyl)Magnesium
Synonym Bis(cyclopentadienyl)magnesium {LY} Bis(cyclopentadienyl)magnesium {} {LY} Bis(cyclopentadienyl)magnesium {} {} {LY} Bis(cyclopentadienyl)magnesium {} {} {} {LY} Bis(cyclopentadienyl)magnesium {} {} {} {} {LY} Bis(cyclopentadienyl)magnesium {} {} {} {} {} {LY} Bis(cyclopentadienyl)magnesium {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)magnesium {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)magnesium {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)magnesium {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)magnesium {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)magnesium {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)magnesium {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)magnesium {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)magnesium {} {}
PubChem Substance ID21881267
Chemical Name Translation双(环戊二烯)镁
InChIKeyUSZGMDQWECZTIQ-UHFFFAOYSA-N
LabNetwork Molecule IDLN02144206
MDL NumberMFCD00134487
CAS Number1284-72-6
InChIInChI=1S/2C5H5.Mg/c2*1-2-4-5-3-1;/h2*1-3H,4H2;/q2*-1;+2
Canonical SMILES[][Mg][].c1cccc1.c2cccc2
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分类

  • {uni_hamburg} no charge; metal-organic; other heterocycle; carbocycle; alicycle; fused rings; 3ring; 4ring; 5ring; 6ring; 1fragment; zwitterion
  • {SNA} CVD and ALD Precursors by Metal, Magnesium, Materials Science, Micro/NanoElectronics, Vapor Deposition Precursors

相关文献及参考

  • Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
  • Short: III/35D5 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 5: Organometallic Compounds Author: Mikhova, Bozhana Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D5 Year: 2008 Keyword: Carbon-13; chemical shift; magnetic properties of nuclei; nuclear magnetic resonance data ISBN: 978-3-540-74188-6 (print) ISBN: 978-3-540-74189-3 (electronic) Internet Resource: DOI:10.1007/978-3-540-74189-3 RefComment: VIII, 241 p., Hardcover RefComment: Written

安全信息

GHS Symbol
WGK Germany3
Hazard Codes F,C
Hazard statements
  • H228 Flammable solid 易燃固体
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P222 Do not allow contact with air. 不要与空气接触。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P231+P232
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P302+P334
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P335+P334
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P402+P404
  • P405 Store locked up. 上锁保管。
  • P422 Store contents under… 存储目录在…之下。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S8 Keep container dry 保持容器干燥；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
UN Number UN3391 UN 3393 4.2/PG 1
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Air & Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, prote
Packing GroupI
Hazard Class4.2

其他信息

  • MOL 文件:1284-72-6.mol
  • Sigma Aldrich:1284-72-6(sigmaaldrich)
  • 敏感性:Air & Moisture Sensitive
  • 二茂镁价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 43434 双(环戊二烯)镁 , sublimed, 97% Bis(cyclopentadienyl)magnesium, sublimed, 97% 5g 4018元 2010/05/25 43434 双(环戊二烯)镁 , sublimed, 97% Bis(cyclopentadienyl)magnesium, sublimed, 97% 1g 1009元
  • Alfa Aesar:双(环戊二烯)镁,sublimed,97% Bis(cyclopentadienyl)magnesium, sublimed, 97%(1284-72-6)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors by Metal - Vapor Deposition Precursors
  5. Magnesium - CVD and ALD Precursors by Metal
  1. CVD & ALD Precursors
  2. Magnesium
  1. Organometallics for CVD & ALD
  2. Magnesium
  1. Metallocenes, Derivatives & Cp Precursors
  2. Magnesium

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