Chlorodiethylphosphine 氯二乙基膦
CAS 686-69-1 MFCD00013621
化学结构图
SMILES: CCP(Cl)CC
化学属性
| Mol. Formula | C4H10ClP |
|---|---|
| Mol. Weight | 124.55 |
| Refractive index | n20/D 1.475(lit.) |
| Boiling Point | 133-134 °C(lit.) |
| Density | 1.023 g/mL at 25 °C(lit.) |
| Flash Point | 18°(66°F) |
| TSCA | No |
| Stability | 对空气敏感，对湿度敏感 |
别名和识别编码
| Chemical Name | Chlorodiethylphosphine |
|---|---|
| Synonym | DIETHYLCHLOROPHOSPHINE , COLORLESS-LIGHT YELLOW LIQUID CHLORO(DIETHYL)PHOSPHINE Diethylchlorophosphine, min. 95% DIETHYLCHLOROPHOSPHINE Diethylchlorophosphine Phosphinous chloride, diethyl- {uni_ham Chlorodiethyl phosphine 氯化二乙基膦 氯化二乙基磷 Diethylphosphinous acidchloride 二乙基氯化膦,氯化二乙基膦 Diethylchlorophosphine,min.95% 二乙基氯化膦 AURORA KA-1317 diethyl-chloro-phosphine Et2PCl Chlorodiethylphosphine Diethylchlorophosphine Et2PCl 二乙基氯化膦 Diethylchlorophosphine; Diethylphosphine chloride; Diethylphosphinous chloride Chloro(diethyl)phosphine DIETHYLPHOSPHINOUS CHLORIDE 氯(二乙基)膦 Phosphinous chloride, diethyl |
| MDL Number | MFCD00013621 |
| CAS Number | 686-69-1 |
| PubChem Substance ID | 69639 |
| EC Number | 211-689-4 |
| Chemical Name Translation | 氯二乙基膦 |
| InChIKey | INJBDKCHQWVDGT-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN02003224 |
| InChI | InChI=1S/C4H10ClP/c1-3-6(5)4-2/h3-4H2,1-2H3 |
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分类
- {uni_hamburg} no charge; 1fragment
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors
相关文献及参考
- Short: II/25C Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25C Year: 2001 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-66774-1 ISBN: 978-3-540-66774-2 Internet Resource: DOI:10.1007/b71431 RefComment: VIII, 481 pages. Hardcover Abstract: This volume contains data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc.) of free polyatomic molecules including free radicals and molecular ions. This survey on structure data is made of four subvolume, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this third subvolume, the structure of molecules containing three for four carbon atoms are listed.
- Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Dat
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
- P422 Store contents under… 存储目录在…之下。
- P231+P232
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P370+P378
- R11 Highly flammable 非常易燃
- R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
- R14 Reacts violently with water 遇水会猛烈反应
- R34 Causes burns 会导致灼伤
- R17 Spontaneously flammable in air 在空气中能够自燃
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
其他信息
- Alfa Aesar:氯(二乙基)膦 Chloro(diethyl)phosphine(686-69-1)
- MOL 文件:686-69-1.mol
- Sigma Aldrich:686-69-1(sigmaaldrich)
- Acros Organics:Chloro(diethyl)phosphine, 95%(686-69-1)
- 氯化二乙基磷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 350310010 氯化二乙基磷 Chloro(diethyl)phosphine 95% 1 GR 1062元 2010/06/21 350310050 氯化二乙基磷 Chloro(diethyl)phosphine 95% 5 GR 3985元 2010/05/25 30204 氯(二乙基)膦 Chloro(diethyl)phosphine 5g 2282元
- 敏感性:Air & Moisture Sensitive
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