Phenol, pentachloro-, sodium salt 五氯酚钠

CAS 131-52-2 MFCD00149086

化学结构图

131-52-2
SMILES: [Na+].[O-]c1c(Cl)c(Cl)c(Cl)c(Cl)c1Cl

化学属性

Mol. FormulaC6Cl5O.Na
Mol. Weight288.30
Melting Point>300 ºC
Solubility易溶于水,易溶于醇、丙酮,不溶于苯。

别名和识别编码

Chemical NamePhenol, pentachloro-, sodium salt
Synonym Pentachlorophenolsodium Pentachlorophenol sodium salt Pentachlorphenol Natrium-Salz pcp,sodiumsalt Sodium pentachlorophenolate Pentaphenate 1,2,3,4,5-五氯酚钠 dowdormantfu Mystox D pentachlorophenol, sodium salt gr48-32s Santobrite Santobrite D Witophen N Dow dormant fungicide PCP-Sodium Sodium pentachlorophenate SODIUM PENTACHLOROPHENOL SODIUM PENTACHLOROPHENATE napclor-g PENTACHLOROPHENOL SODIUM SALT HYDRATE Sodium pentachlorophenoxide Sapco 25 PENTACHLOROPHENOL SODIUM SALT Natriumpentachlorphenolat 五氯酚钠 caswellno.784 dowicideg-st dowicideg {haz (pentachlorophenoxy)-sodiu Pentachlorophenate sodium GR 48-11PS Dowicide G-ST nolongerclearedasinert) SODIUM PENTACHLOROPHENOLATE Sodium pentachlorphenate Pentachlorphenol-Natriumsalz pentachloro-phenol sodium-compound Pentanot 25 mystoxd Phenol, pentachloro-, sodium salt 五氯苯酚钠 sodium pentachlorophenolate Dowicide G ai3-16418 Sodium, (pentachlorophenoxy)- Sodium pentaehlorophenol Sodium pentachlorophenol gr48-11ps epapesticidechemicalcode063003 Weedbeads Pentachlorophenol, sodium salt Sodium PCP Pentachlorophenoxy sodium 五氯苯酚钠盐 五氯酚钠(0308限出口) pentachlorophenol sodium salt
MDL NumberMFCD00149086
EC Number205-025-2
CAS Number131-52-2
Chemical Name Translation五氯酚钠
Wiswesser Line NotationQR BG CG DG EG FG &-NA-
PubChem Substance ID23663539
InChIInChI=1S/C6HCl5O.Na/c7-1-2(8)4(10)6(12)5(11)3(1)9;/h12H;/q;+1/p-1
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 2fragments; ionic

相关文献及参考

  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Hazard Codes T+,N T+;N
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S1/2 None 上锁保管并避免儿童触及;
  • S52 Not recommended for interior use on large surface areas 建议不在表面积大的区域内部使用;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R26 Very toxic by inhalation 吸入极毒
  • R50/53
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 2567
Packing GroupII
Hazard Class6.1(a)
RTECSSM6490000
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 66 mg/kg
TOXIC EFFECTS :
   Vascular - BP elevation not characterized in autonomic section
   Endocrine - hyperglycemia
   Nutritional and Gross Metabolic - body temperature increase
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 76,104,1942

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intratracheal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 146 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   MZUZA8 Meditsinskii Zhurnal Uzbekistana.  (V/O Mezhdunarodnaya Kniga, 113095
   Moscow, USSR) No.1-    1957-  Volume(issue)/page/year: (9),29,1959

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 197 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,106,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 124 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   G

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 5 ug/disc
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 40,19,1976

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 360 mg/kg
SEX/DURATION            : female 8-19 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   CHYCDW Zhonghua Yufangyixue Zazhi.  Chinese Journal of Preventive Medicine.
   (China International Book Trading Corp., POB 2820, Beijing, Peop. Rep.
   China)  Beginning history not known.  Volume(issue)/page/year: 13,8,1979

其他信息

  • 注意事项:[1]该药为灭生性除草剂苗期用药严禁加水喷雾。苗嫩、叶片上露水未干不能 用药,不得在水稻和其他作物上进行叶面喷雾,以防产生药害。 [2]稻田使用在规定时间内不能串灌和排水。漏水田、砂质田、积水田不能用药。 [3]对鱼类剧毒,注意不要在靠近鱼塘的地方拌药,洗刷容器后的污水切不可随便倾入河川
  • 方法一:由六氯苯水解制得。
  • 可燃性危险特性:可燃;有腐蚀性; 燃烧释放有毒氯化物烟雾
  • 类别:农药
  • 毒性分级:高毒
  • 上游原料:苯酚 --> 六氯苯
  • 中毒症状:对眼睛、皮肤有强烈刺激作用,常引起打喷嚏、流泪、皮肤红肿等。口服中毒症状为大量出汗、体温升高、恶心呕吐、腹痛、腹泻、昏迷、抽搐、心力衰竭、肺水肿等。最具特征是强烈的口渴感。
  • 用途一:五氯酚钠用作非选择性接触型除草剂、收获前的脱叶剂、木材防腐剂,还可用于杀灭血吸虫的中间宿主钉螺,防治血吸虫病。作为除草剂,主要除以种子繁殖的杂草,是一种杀伤范围很广的除草剂,主要用于水稻田。用于杀灭钉螺,在25℃时,10ppm的花液能使96.7%的钉螺死亡,半致死浓度为2ppm。
  • Sigma Aldrich:131-52-2(sigmaaldrich)
  • 下游产品:五氯苯酚 --> 四氯苯醌 --> 月桂酸五氯苯酯
  • 急性毒性:口服-大鼠 LD50: 126 毫克/公斤;口服-小鼠 LD50: 197 毫克/公斤
  • 急救治疗:经口中毒应立即进行催吐、洗胃,可用2%碳酸氢钠洗胃。切勿用阿托品、巴比妥类药物。抽搐用牛黄安宫丸,脱水可用25-30mg氯丙嗪溶于500ml葡萄糖生理盐水中,静脉滴注,必要时输氧。心力衰竭、肺水肿应对症治 疗。在治疗时要保护肝、肾。
  • 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
  • 外观性质:工业品呈淡黄色鳞片状晶体, 有臭味。
  • MOL 文件:131-52-2.mol
  • 灭火剂:水、泡沫、二氧化碳、砂土。
  • MSDS 信息:五氯酚钠(131-52-2).msds
  • 五氯酚钠价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K7648001 五氯苯酚钠 (剧毒) 100g 500元 2011/08/23 80097060 五氯酚钠盐(剧毒) 100g 170元

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