Di-Tert-Butyl Diisopropylphosphoramide 二叔丁基二异丙基磷酰胺

CAS 137348-86-8 MFCD00153506

化学结构图

137348-86-8
SMILES: CC(C)N(C(C)C)P(OC(C)(C)C)OC(C)(C)C

化学属性

Mol. FormulaC14H32NO2P
Mol. Weight277
Refractive index1.4370 to 1.4410
Density0.879
Boiling Point85-90

别名和识别编码

Chemical NameDi-Tert-Butyl Diisopropylphosphoramide
CAS Number137348-86-8
Synonym Di-tert-butoxy(diisopropylamino)phosphine N,N-Bis(1-methylethyl)phosphoramidous Acid Bis(1,1-dimethylethyl)ester N,N-二异丙基亚磷酰胺二叔丁酯
Beilstein Registry Number4858847
MDL NumberMFCD00153506
PubChem Substance ID160871438
Chemical Name Translation二叔丁基二异丙基磷酰胺
Reaxys-RN4858847
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分类

  • Phosphorylating and Phosphitylating Agents
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Biology, Chemical Synthesis, Coupling Reagents, Nucleoside Chemistry, Phosphine Compounds, Phosphine Ligands

产品应用

  • A phosphinane derivative with immunomodulating activity.

相关文献及参考

  • Mandala, S., et al.: Science, 296, 346

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Hazard Codes Xi
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 0-10°C

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体

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