Tris(Trimethylsilyl)Phosphine 三(三甲基甲硅烷基)膦
CAS 15573-38-3 MFCD00015487
化学结构图
SMILES: C[Si](C)(C)P([Si](C)(C)C)[Si](C)(C)C
化学属性
| Refractive index | 1.5020 |
|---|---|
| TSCA | No |
| Mol. Formula | C9H27PSi3 |
| Mol. Weight | 250.54 |
| Appearance | colorless liq. colorless to pale yellow, low melting solid |
| Stability | air sensitive |
| Density | 0.863 |
| Flash Point | -1°F |
| Boiling Point | 102-105°C/16 mm |
| Melting Point | 24°C |
别名和识别编码
| Chemical Name | Tris(Trimethylsilyl)Phosphine |
|---|---|
| Synonym | Tris(trimethylsilyl)phosphine 1,1,1,3,3,3-hexamethyl-2-trimethylsilanyl-disilaphosphane Phosphine, tris(trimethylsilyl)- [Tris(trimethylsilyl)]phosphin [Tris(trimethylsilyl)]phosphine {uni_hamburg} 三(三甲硅基)膦 |
| PubChem Substance ID | 354334074 |
| Chemical Name Translation | 三(三甲基甲硅烷基)膦 |
| Reaxys-RN | 1701643 |
| MDL Number | MFCD00015487 |
| CAS Number | 15573-38-3 |
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分类
- {uni_hamburg} no charge; 1fragment
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
相关文献及参考
- Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
- Short: III/35F Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Silicon-29 Author: Marsmann, H.C.; Uhlig, F.; Gupta, R.R.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35F Year: 2008 Keyword: NMR; Si-29; chemical shifts; coupling constants; nuclear magnetic resonance; silicon-29 ISBN: 978-3-540-45277-5 (print) ISBN: 978-3-540-45278-2 (electronic) Internet Resource: DOI: 10.1007/978-3-540-45278-2 RefComment: X, 46
安全信息
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
- R17 Spontaneously flammable in air 在空气中能够自燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S37 Wear suitable gloves 戴适当手套；
- S17 Keep away from combustible material 远离可燃物料；
- S7 Keep container tightly closed 保存在严格密闭容器中；
- P302+P352+P332+P313+P362+P364
- P304+P340+P312
- P222 Do not allow contact with air. 不要与空气接触。
- P305+P351+P338
- P422 Store contents under… 存储目录在…之下。
- P231 Handle under inert gas. 在惰性气体中操作。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P305+P351+P338+P337+P313
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
- P405 Store locked up. 上锁保管。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P308+P313
- P301+P310+P331
- P403+P233
- P273 Avoid release to the environment. 避免释放到环境中。
- P241+P242+P243
- P233 Keep container tightly closed. ?保持容器密闭。
- H315 Causes skin irritation 会刺激皮肤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
- H319 Causes serious eye irritation 严重刺激眼睛
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
GHS Symbol
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