1,2,3-Trichloropropene 1,2,3-三氯丙烯

CAS 96-19-5 MFCD00018931

化学结构图

96-19-5
SMILES: Cl/C=C(\Cl)CCl

化学属性

Mol. FormulaC3H3Cl3
Mol. Weight145.41
Refractive index1.5000 to 1.5020
Flash Point82°C(lit.)
Appearance 本品为无色液体,b.p.142℃,相对密度1.414,溶于四氯化碳和氯仿,不溶于水。
Boiling Point145°C
Density1,43 g/cm3

别名和识别编码

Chemical Name1,2,3-Trichloropropene
MDL NumberMFCD00018931
CAS Number96-19-5
Synonym 1,2,3-Trichloropropene (1Z)-1,2,3-Trichloro-1-propene 1,2,3-trichloro-propen 1,2,3-TRICHLORO-1-PROPENE, CIS-TRANS 1,2,3-trichlor-1-propene 1-Propene, 1,2,3-trichloro- 1,2,3-Trichlor-1-propen 1,2,3-TRICHLOROPROPENE 1,2,3-Trichloro-1-propene 1,2,3-trichloro-1-propen 2,3-Dichloroallyl chloride 1,2,3-三氯丙烯 2,3-dichloroallylchloride 1,2,3-Trichloropropene, E&Z; 1-Propene,1,2,3-trichloro- Propene,1,2,3-trichloro- Propene, 1,2,3-trichloro- 1,2,3-trichloro-propene 1,2,3-trichloropropylene 1,2,3-TRICHLOROPROPENE (CIS- AND TRANS- MIXTURE) 1,2,3-Trichloroprop-1-ene
Beilstein Registry Number1(4)748
PubChem Substance ID87576352
Chemical Name Translation1,2,3-三氯丙烯
EC Number202-487-7
Wiswesser Line NotationG1YGU1G
LabNetwork Molecule IDLN01746432
InChIInChI=1S/C3H3Cl3/c4-1-3(6)2-5/h1H,2H2/b3-1-
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分类

  • {Chemicalbook} 农药中间体: 除草剂中间体: 氨基甲酸酯类除草剂
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: IV/8J Title: Densities of Halohydrocarbons Author: Frenkel, M.; Hong, X.; Dong, Q.; Yan, X.; Chirico, R.D. Editor: Frenkel, M.; Marsh,K.N. Source: Landolt-Börnstein, New Series Volume: IV/8J Year: 2003 Keyword: thermodynamics ISBN: 978-3-540-00083-9 ISBN: 3-540-00083-6 Internet Resource: DOI:10.1007/b10103 RefComment: XII, 600 p., 160 illus., Hardcover RefComment: Written for Scientists and engineers in the fields of physics, chemistry and physical chemistry Abstract: Critically evaluated experimental data covering the densities of organic compounds are essential for both scientific and industrial applications. Knowledge of densities is important in many areas, including custody transfer of materials, product specification, development of various predictive methods, and for characterizing compounds and estimating their purity. This volume contains tables with the original literature data along with their estimated uncertainties and the evaluated data in both numerical form and as coefficients to equations with selected statistical information. When data cover a sufficient temperature range, graphical plots of the deviations of the experimental data from the recommended equation are given. A C

安全信息

RTECSUD2450000
UN Number 2810
Signal word
Hazard statements
  • H227 Combustible liquid 可燃液体
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P304+P340+P310
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P302+P350
  • P337+P313
  • P403+P233
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P305+P351+P338
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P332+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P305+P351+P338+P337+P313
  • P405 Store locked up. 上锁保管。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
Packing GroupII
Hazard Class6.1
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
GHS Symbol
TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 5/4/1960

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 616 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 5/4/1960

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 640 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 umol/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 2,59,1980

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Human HeLa cell
DOSE/DURATION           : 1700 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 92,427,1982

其他信息

  • 方法一:其制备方法是将四氯丙烷及乙醇加到反应釜中,搅拌加热至回流,在1 h内分批加入氢氧化钾,加毕回流2 h,冷却、过滤,滤液水洗2次,水层用二氯乙烷萃取,并与油层合并,脱溶,减压蒸馏,收集74~91℃/13.3 kPa馏分即为成品。 ClCH 2 Cl 2 CH 2 Cl+KOH→ClCH 2 ClC=CHCl+KCl+H 2 O
  • MOL 文件:96-19-5.mol
  • 用途一:1,2,3-三氯丙烯是除草剂燕麦敌的中间体。
  • 上游原料:二氯乙烷
  • 图谱信息:1,2,3-三氯丙烯(96-19-5)质谱(MS) 1,2,3-三氯丙烯(96-19-5)红外图谱(IR1)
  • Sigma Aldrich:96-19-5(sigmaaldrich)
  • TCI Shanghai:1,2,3-三氯丙烯 (顺反异构体混合物) 1,2,3-Trichloropropene (cis- and trans- mixture),>;95.0%(GC)(96-19-5)
  • 1,2,3-三氯丙烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0396 1,2,3-三氯丙烯 (顺反异构体混和物) 1,2,3-Trichloropropene (cis- and trans- mixture) 500G 3140元 2014/06/02 T0396 1,2,3-三氯丙烯 (顺反异构体混和物) 1,2,3-Trichloropropene (cis- and trans- mixture) 25G 435元

系列性分类


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