(S)-Cbz-Phenylalaninol Cbz-L-苯丙氨醇
CAS 6372-14-1 MFCD00191138
化学结构图
SMILES: O=C(N[C@H](CO)Cc1ccccc1)OCc1ccccc1
化学属性
| Mol. Formula | C17H19NO3 |
|---|---|
| Mol. Weight | 285.34 |
| Melting Point | 92-95 °C |
| TSCA | No |
| Density | 1.422 |
| Solubility | 不溶 |
| Refractive index | -42 ° (C=2, MeOH) |
| Boiling Point | 489 °C at 760 mmHg |
别名和识别编码
| Chemical Name | (S)-Cbz-Phenylalaninol |
|---|---|
| Synonym | Z-Phenylalaninol {LY} Z-Phenylalaninol {} {LY} Z-Phenylalaninol {} {} {LY} Z-Phenylalaninol {} {} {} {LY} Z-Phenylalaninol {} {} {} {} {LY} Z-Phenylalaninol {} {} {} {} {} {LY} Z-Phenylalaninol {} {} {} {} {} {} {LY} Z-Phenylalaninol {} {} {} {} {} {} {} {LY} Z-Phenylalaninol {} {} {} {} {} {} {} {} {LY} Z-Phenylalaninol {} {} {} {} {} {} {} {} {} {LY} Z-Phenylalaninol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Phenylalaninol {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Phenylalaninol {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Phenylalaninol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Phenylalaninol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Phenylalaninol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Phenylalaninol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Phenylalaninol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Pheny |
| Beilstein Registry Number | 2816420 |
| PubChem Substance ID | 853481 |
| CAS Number | 6372-14-1 |
| MDL Number | MFCD00191138 |
| Reaxys-RN | 2816420 |
| EC Number | 250-023-7 |
| Chemical Name Translation | Cbz-L-苯丙氨醇 |
| LabNetwork Molecule ID | LN00011089 |
| InChI | InChI=1S/C17H19NO3/c19-12-16(11-14-7-3-1-4-8-14)18-17(20)21-13-15-9-5-2-6-10-15/h1-10,16,19H,11-13H2,(H,18,20)/t16-/m0/s1 |
| Canonical SMILES | OC[C@@H](NC(OCC1=CC=CC=C1)=O)CC2=CC=CC=C2 |
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分类
- {SNA} Amino Acid Derivatives, Amino Alcohols, Chemical Biology, Chemical Synthesis, Peptide Chemistry
- {SNA} Amino Acids & Derivatives, Amino Alcohols, Chemical Biology, Chemical Synthesis, Peptide Chemistry
相关文献及参考
- 1. Aldrichimica Acta 28 , 13, (1995)
- 2. Scholz, D. et al. J. Med. Chem. 37 , 3079, (1994) 摘要
- 3. Liu, C. et al. Org. Process Res. Dev. 1 , 45, (1997)
- 4. Beaulieu, P.L. Wernic, D. J. Org. Chem. 61 , 3635, (1996) 摘要
- 5. Lam, P.Y.S. et al. J. Med. Chem. 39 , 3514, (1996) 摘要
- 6. Hodge, C.N. et al. Chem. Biol. 3 , 301, (1996) 摘要
- 7. Pierce, M.E. et al. J. Org. Chem. 61 , 444, (1996) 摘要
- FT-IR 2 (2), 3037:C / Structure Index 1 , 325:E:7
安全信息
GHS Symbol
- S22 Do not breathe dust 不要吸入粉尘；
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
其他信息
- MOL 文件:6372-14-1.mol
- Alfa Aesar:N-苄氧羰基-L-苯氨基丙醇,98% N-Benzyloxycarbonyl-L-phenylalaninol, 98%(6372-14-1)
- Acros Organics:(S)-(-)-2-(Carbobenzyloxyamino)-3-phenyl-1-propanol, 98%(6372-14-1)
- F:10-23
- Cbz-L-苯丙氨醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1610 N-苄氧羰基-L-苯丙胺醇 N-Carbobenzoxy-L-phenylalaninol 5G 889元 2014/06/02 C1610 N-苄氧羰基-L-苯丙胺醇 N-Carbobenzoxy-L-phenylalaninol 1G 322元 2010/06/21 334710010 Cbz-L-苯丙氨醇 (S)-(-)-2-(Carbobenzyloxyamino)-3-phenyl-1-propanol 98% 1 GR 424元
- Sigma Aldrich:6372-14-1(sigmaaldrich)
- 比旋光度:-45 ° (c=2, MeOH)
- TCI Shanghai:N-苄氧羰基-L-苯丙胺醇 N-Carbobenzoxy-L-phenylalaninol,>;98.0%(LC)(6372-14-1)
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