1-Amino-2,4-Dibromoanthraquinone 1-氨基-2,4-二溴蒽醌

CAS 81-49-2 MFCD00019155

化学结构图

81-49-2
SMILES: Nc1c(Br)cc(Br)c2c1C(=O)c1ccccc1C2=O

化学属性

Mol. FormulaC14H7Br2NO2
Mol. Weight381.02
Melting Point226 °C
TSCAYes
Solubility<0.1 G/100 ML AT 23 ºC
Appearance 红色粉末，熔点226℃。
Boiling Point550.4±50.0 °C at 760 mmHg

别名和识别编码

Chemical Name1-Amino-2,4-Dibromoanthraquinone
CAS Number81-49-2
Synonym 1-Amino-2,4-dibromoanthraquinone {LY} 1-Amino-2,4-dibromoanthraquinone {} {LY} 1-Amino-2,4-dibromoanthraquinone {} {} {LY} 1-Amino-2,4-dibromoanthraquinone {} {} {} {LY} 1-Amino-2,4-dibromoanthraquinone {} {} {} {} {LY} 1-Amino-2,4-dibromoanthraquinone {} {} {} {} {} {LY} 1-Amino-2,4-dibromoanthraquinone {} {} {} {} {} {} {LY} 1-Amino-2,4-dibromoanthraquinone {} {} {} {} {} {} {} {LY} 1-Amino-2,4-dibromoanthraquinone {} {} {} {} {} {} {} {} {LY} 1-Amino-2,4-dibromoanthraquinone {} {} {} {} {} {} {} {} {} {LY} 1-Amino-2,4-dibromoanthraquinone {} {} {} {} {} {} {} {} {} {} {LY} 1-Amino-2,4-dibromoanthraquinone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Amino-2,4-dibromoanthraquinone {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Amino-2,4-dibromoanthraquinone {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Amino-2,4-dibromoanthraquinone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Amino-2,4-dibromoa
MDL NumberMFCD00019155
EC Number201-354-0
Chemical Name Translation1-氨基-2,4-二溴蒽醌
Wiswesser Line NotationL C666 BV IVJ DZ EE GE
Beilstein Registry Number1993373
LabNetwork Molecule IDLN00714673
PubChem Substance ID6681
InChIInChI=1S/C14H7Br2NO2/c15-8-5-9(16)12(17)11-10(8)13(18)6-3-1-2-4-7(6)14(11)19/h1-5H,17H2
Canonical SMILESC1=CC2=C(C=C1)C(=O)C3=C(C(=CC(=C3C2=O)Br)Br)N
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相关文献及参考

安全信息

Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
RTECSCB5500000 
TYPE OF TEST            : Morphological transformation
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 329 gm/kg/39W (Continuous)
REFERENCE :
   PAACA3 Proceedings of the American Association for Cancer Research. (Waverly
   Press, 428 E. Preston St., Baltimore, MD 21202)  V.1-    1954-
   Volume(issue)/page/year: 26,78,1985

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 333 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 5(Suppl
   1),3,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 333 ug/plate
REFERENCE :
   NTPTB* NTP Technical Bulletin.  (National Toxicology Program, Landow Bldg.
   3A-06, 7910 Woodmont Ave., Bethesda, MD 20205)  Volume(issue)/page/year:
   JAN1982

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C,

其他信息

  • 用途二:染料及其它有机化工原料中间体。
  • 储运特性:库房通风低温干燥
  • 下游产品:酸性兰138
  • 用途一:用作染料中间体
  • Alfa Aesar:1-氨基-2,4-二溴蒽醌,97% 1-Amino-2,4-dibromoanthraquinone, 97%(81-49-2)
  • 上游原料:次氯酸钠 --> 1-氨基蒽醌 --> 亚硫酸氢钠溶液 --> 分散磨
  • 方法一:由1-氨基蒽醌和水在锅中搅匀，经胶体磨细，再加入溴化锅中，加水调整体积。然后加入30%盐酸和溴，搅拌1h，慢慢加入10%次氯酸钠溶液。2h升温到50℃，保温2h，于3h内升温到80℃，保温反应至终点（测定熔点在220℃以上。）。加入10%亚硫酸氢钠溶液，冷到50℃以下，过滤，洗至中性，烘干即得。当每批加料1-氨基蒽醌50.17kg、溴48kg时，可得1-氨基-2,4-二溴蒽醌81.45kg。
  • MSDS 信息:1-Amino-2,4-dibromoanthraquinone(81-49-2).msds
  • 1-氨基-2,4-二溴蒽醌价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 A19700 1-氨基-2,4-二溴蒽醌, 97% 1-Amino-2,4-dibromoanthraquinone, 97% 50g 455元 2010/05/25 A19700 1-氨基-2,4-二溴蒽醌, 97% 1-Amino-2,4-dibromoanthraquinone, 97% 250g 1820元
  • MOL 文件:81-49-2.mol
  • 可燃性危险特性:可燃;燃烧产生有毒氮氧化物和溴化物烟雾
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • Sigma Aldrich:81-49-2(sigmaaldrich)
  • 刺激数据:眼睛-兔子 500 毫克/24小时 轻度
  • 类别:有毒物品

系列性分类

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