2-Bromopyridine-5-Boronic Acid 2-溴吡啶-5-硼酸

CAS 223463-14-7 MFCD03411558

化学结构图

223463-14-7
SMILES: OB(O)C1C=CC(Br)=NC=1

化学属性

Mol. FormulaC5H5BBrNO2
Mol. Weight202
Melting Point161-166 °C
TSCANo
Density1.78

别名和识别编码

Chemical Name2-Bromopyridine-5-Boronic Acid
CAS Number223463-14-7
Alfabeta NameBROMOPYRIDYLBORONICACID 25---
MDL NumberMFCD03411558
Synonym 2-溴吡啶-5-硼酸 2-Bromo-5-pyridylboronic acid
PubChem Substance ID87560688
Reaxys-RN9119918
EC Number000-000-0
Beilstein Registry Number9119918
Chemical Name Translation2-溴吡啶-5-硼酸
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分类

  • {SNA} Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Heteroaryl Boronic Acids, Organometallic Reagents

相关文献及参考

  • 1. G. Burzicki, et al., Synthesis of new [2,3':6',3'']terpyridines using iterative cross-coupling reactions Synthesis 16 , 2804-2810, (2010)
  • 2. A. S. Voisin-Chiret, et al., Synthesis of new phenylpyridyl scaffolds using the Garlanding approach Tetrahedron 66 , 8000-8005, (2010)
  • 3. C. W. Liskey, et al., Cyanation of Arenes via Iridium-Catalyzed Borylation J. Am. Chem. Soc. 132 , 11389-11391, (2010)
  • 4. G. Burzicki, et al., Synthesis of dihalo bi- and terpyridines by regioselective Suzuki-Miyaura cross-coupling reactions Tetrahedron 65 , 5413-5417, (2009)
  • 5. A. S. Voisin, et al., Unusual behaviour of pyridinylboronic acids in the Petasis boronic Mannich reaction Tetrahedron Lett. 47 , 2165-2169, (2006)

安全信息

Warnings IRRITANT
WGK Germany3
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
UN Number
Hazard Codes
Packing GroupIII

系列性分类


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