Sodium tetrahydroborate-​d4 氘代硼氢化钠

CAS 15681-89-7 MFCD00003519

化学结构图

15681-89-7
SMILES: [Na+].[2H][B-]([2H])([2H])[2H]

化学属性

Mol. FormulaNaBD4
Mol. Weight42
Autoignition Point752 °F
Density1.187
Melting Point>;300 °C (dec.)(lit.)
TSCANo

别名和识别编码

Chemical NameSodium tetrahydroborate-​d4
CAS Number15681-89-7
Synonym Sodium tetradeuteridoborate Sodium tetradeuterioboron Sodium tetrahydridoborate, deuterated Natriumbordeuterid Sodium borodeuteride-d4 硼氘化钠 sodium [2H4]tetrahydroborate(1-) Borate(1-), tetrahydro-d4-, sodium Sodium tetradeuteroborate sodium [2H4]tetrahydroborate(1-) Sodium Tetrahydro-d4-borate Natriumbordeuterid-d4 Sodium tetrahydroborate-d4 Borate(1-), tetrahydro-d4-, sodium Sodium Borodeuteride Natriumtetradeuteridoborat Deuterated sodium borohydride Sodium tetradeuterioboron Sodium tetradeuterioborate
MDL NumberMFCD00003519
EC Number239-764-7
PubChem Substance ID24852210
Beilstein Registry Number2384789
Chemical Name Translation氘代硼氢化钠
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分类

  • Miscellaneous Reagents
  • Labeling and Diagnostics Reagents
  • {uni_hamburg} no charge; isotope; 2fragments; ionic
  • {SNA} Alphabetical Listings, Alternative Energy, Deuterated Materials, Materials Science, Materials for Hydrogen Storage, Q-S, Stable Isotopes
  • Aliphatics
  • {SNA} Alphabetical Listings, Alternative Energy, Deuterated Materials, Materials for Hydrogen Storage, Q-S, Stable Isotopes, 材料科学

产品应用

  • Labelled Sodium Borohydride used as a reagent used to prepare ?,?-dideutero-?-amino acids. Sodium Borohydride-d4 is also used to prepare amine-stabilized, deuterated borane-THF.

相关文献及参考

  • Todd, R.C. et al.: Tetrahedron Lett., 48, 2335 (2007); Synthesis, 4013, (2006);
  • Short: III/31a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cu Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/31a Year: 1993 Keyword: NQR ISBN: 3-540-55146-8 ISBN: 978-3-540-55146-1 Internet Resource: DOI:10.1007/b43999 RefComment: VIII, 437 pages. Hardcover Abstract: Volume III/31 continues the compilation of nuclear quadrupole resonance spectroscopy data of solid substances which started in with volume III/20 in 1987 covering the literature from the beginning of nuclear quadrupole resonance spectroscopy in 1951 to 1982 and containing the data for 8000 substances in the solid state, distributed among three subvolumes III/20 a, b, and c. Volume III/31 covers the literature published in the period from the end of 1982 through the end of 1989. Included are the data for substances studied for the first time, as well as data for substances already present in the previous volume III/20 if the data published there could be completed or improved by new studies. In total there are 2500 substances in volume III/31, showing the scope and significance of nuclear quadrupole resonance spectroscopy up to recent times.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P301+P310
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P422 Store contents under… 存储目录在…之下。
  • P231+P232
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P370+P378
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Risk Statements
Packing GroupI
UN Number UN1426
Storage condition Moisture Sensitive
Hazard Codes F,T

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Analytical & Chromatography 分析化学与色谱
  2. Stable Isotopes 稳定同位素
  3. Alphabetical Listings for Stable Isotope Labeled Products
  4. Q-S - Alphabetical Listings
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Titration - Analytical Reagents
  4. Complexometric Titration Reagents (EDTA Titration) - Titration
  5. Complexometric Solutions (IDRANAL™) - Complexometric Titration Reagents (EDTA Titration)
  1. Chemical Synthesis 化学合成
  2. Others

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