(Methyl(Phenyl)Amino)Triphenylphosphonium Iodide （N-甲基-N-苯基氨基）三苯基碘化物
CAS 34257-63-1 MFCD00040544
化学结构图
SMILES: [I-].CN(C1C=CC=CC=1)[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1
化学属性
| Mol. Formula | C25H23INP |
|---|---|
| Mol. Weight | 495.34 |
| Melting Point | 238-239° |
| TSCA | No |
别名和识别编码
| Chemical Name | (Methyl(Phenyl)Amino)Triphenylphosphonium Iodide |
|---|---|
| Synonym | Murahashi reagent N-Methylanilinotriphenylphosphonium iodide Murahashi's Reagent |
| MDL Number | MFCD00040544 |
| Beilstein Registry Number | 4075159 |
| CAS Number | 34257-63-1 |
| Chemical Name Translation | （N-甲基-N-苯基氨基）三苯基碘化物 |
| Reaxys-RN | 4075159 |
| PubChem Substance ID | 87573114 |
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相关文献及参考
- In the presence of an alcohol, generates an alkylating species (cf Mitsunobu reaction). Primary or secondary amines are N-alkylated in high yield: Tetrahedron Lett., 471 (1975). Similarly, unsymmetrical sulfides can be prepared from thiols: Tetrahedron Lett., 4655 (1977). In the presence of CuI, allylic, benzylic and cyclopropylmethyl alcohols alkylate organolithium reagents. With allylic alcohols, the reaction is both regio- and stereoselective, and is therefore a valuable alkene synthesis: J. Am. Chem. Soc., 99, 2361 (1977).
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- H315 Causes skin irritation 会刺激皮肤
GHS Symbol
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P302+P352+P332+P313+P362+P364
- P332+P313
- P305+P351+P338+P337+P313
- P302+P350
- P337+P313
- P305+P351+P338
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