EPN 苯硫磷

CAS 2104-64-5 MFCD00055309

化学结构图

2104-64-5
SMILES: CCOP(=S)(Oc1ccc([N+](=O)[O-])cc1)c1ccccc1

化学属性

Mol. FormulaC14H14NO4PS
Mol. Weight323.32
Flash Point2 °C
Solubility不溶于水,易溶于多数有机溶剂。
Density1.27
Refractive index1.6021
Melting Point36℃

别名和识别编码

Chemical NameEPN
Synonym {uni_hamburg} {Chemicalbook} Benzenepho {Chem Ethyl (p-nitrophenyl) benzenethiophosphonate O-ethyl O-4-nitrophenyl phenylphosphonothioate O-Ethyl O-(4-nitrophenyl) benzenethionophosphonate PIN O-ethyl O-(4-nitrophenyl)phenylphosphonothioate O-Ethyl O-(p-nitrophenyl) phenylphosphorothioate Ethoxy-4-nitrophenoxyphenylphosphine sulfide 苯硫膦 Benzenephosphonic acid, thiono-, ethyl-(p-nitrophenyl) ester Ethoxy-(((4-nitrophenoxy)phenyl)phosphine) sulfide Ethyl p-nitrophenyl phenylphosphorothioate EPN O-Ethyl phenyl (p-nitrophenyl) thiophosphonate O-Aethyl-O-(4-nitro-phenyl)-phenyl-monothiophosphonat O-ETHYL-O-P-NITROPHENYL PHENYLTHIO-PHOSPHONATE O-E O-Ethyl-O-4-nitrophenylphenylthiophosphonat O-Ethyl O-(4-nitrophenyl) phenylphosphonothioate Ethyl (p-nitrophenyl) phenylphosphonothioate ethoxy-4-nitrophenoxyphenylphosphinesulfide Ethyl (p-nitrophenyl) benzenethionophosphonate 伊皮斯 O-乙基-O-(对硝基苯基)苯基硫代膦酸酯 {u {uni phosphonothioic acid, phenyl-, O-ethyl O-(p-nitrophenyl) ester 对硝基苯基苯基硫代膦酸乙酯 Ethyl (p-nitrophenyl) benzenethiophosphate Ethyl (p-nitrophenyl) phenylphosphonothioate O-乙基-O-(4-硝基苯)苯基硫代膦酰酯 EPN标准品 O-乙基-O-(4-硝基苯基)苯基硫代磷酸酯 ETHYL P-NITROPHENYL THIONOBENZENEPHOSPHONATE 伊皮恩 Ethyl (p-nitrophenyl) benzenethiophosphonate Ethyl (p-nitrophenyl) thionobenzenephosphonate Phosphonothioic acid, phenyl-, O-ethyl O-(4-nitrophenyl) ester O-Ethyl O-p-nitrophenyl benz
MDL NumberMFCD00055309
Beilstein Registry Number2542580
CAS Number2104-64-5
EC Number218-276-8
Chemical Name Translation苯硫磷
Merck Number13,3656
Wiswesser Line NotationWNR DOPS&R&O2
PubChem Substance ID16421
InChIInChI=1S/C14H14NO4PS/c1-2-18-20(21,14-6-4-3-5-7-14)19-13-10-8-12(9-11-13)15(16)17/h3-11H,2H2,1H3
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分类

  • {SNA} Analytical Standards, E-G, Insecticides, Organophorous, 农残和代谢标准品, 分析/色谱, 按照字母排序
  • Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, E, E-G,
  • {SA} Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, E, E-G, EP, Environmental Standards, Insecticides, Organophorous, Pesticides, Pesticide
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

产品应用

  • 苯硫硝基酚钠与O-乙基苯基硫代磷酰氯反应而得。苯硫磷系触杀杀虫杀螨剂,对多种害虫有效。用于防治水稻二化螟,三化螟,稻螟铃,叶蝉,飞虱,稻苞虫等均有很高的杀虫效力。

相关文献及参考

  • Short: EINECS
  • Short: IV/8A
  • Merck:13,3656

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P302+P350
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H310 Fatal in contact with skin 皮肤接触致命
  • H300 Fatal if swallowed 吞食致命
Hazard Codes T+,N T+,N,Xn,F
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
RTECSTB1925000
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Storage condition APPROX 4°C 2-8℃
Risk Statements
  • R11 Highly flammable 非常易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R50/53
  • R36 Irritating to eyes 刺激眼睛
  • R27/28 Very toxic in contact with skin and if swallowed 皮肤接触及吞食都有剧毒
UN Number 3018
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 7200 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   APCRAW Advances in Pest Control Research.  (New York, NY)  V.1-18, 1957-68.
   Vo

{hazard_com

TYPE OF TEST            : LDLo - Lowest published

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : 5 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   20,57,1971

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 7 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 112,29,1954

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - pigeon
DOSE/DURATION           : 4210 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ASTTA8 ASTM Special Technical Publication.  (American Soc. for Testing
   Materials, 1916 Race St., Philadelphia, PA 19103)  No.1-    1911-
   Volume(issue)/page/year: (680),157,1979

TYPE OF TEST

{

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 132 mg/kg
SEX/DURATION            : female 6-16 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   JPFCD2 Journal of Environmental Science and Health, Part B: Pesticides, Food
   Contaminants, and Agricultural Wastes.  (Marcel Dekker, 270 Madison Ave.,
   New York, NY 10016)  V.B11-    1976-  Volume(issue)/page/year: 20,373,1985

其他信息

  • 生产方法:由对硝基酚钠与O-乙基苯基硫代磷酰氯反应而得。
  • 用途:苯硫磷系触杀杀虫杀螨剂,对多种害虫有效。用于防治水稻二化螟、三化螟、稻螟铃、叶蝉、飞虱、稻苞虫等均有很高的杀虫效力。
  • MOL 文件:2104-64-5.mol
  • HazardClass:6.1(a)
  • 外观性质:纯品为淡黄色晶状粉末, 工业品为深黄色液体。
  • PackingGroup:II
  • 蒸气压(100℃)为0.04pa,溶于苯、甲苯、二甲苯、丙酮,异丙醇,甲醇,试剂上不溶于水。在中性和酸性介质中稳定,但遇碱分解。
  • RTECS号:TB1925000

系列性分类


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