Azinphos-ethyl 乙基古硫磷标准溶液

CAS 2642-71-9 MFCD00055539

化学结构图

2642-71-9
SMILES: CCOP(=S)(OCC)SCn1nnc2ccccc2c1=O

化学属性

Mol. FormulaC12H16N3O3PS2
Mol. Weight345.40
Density0.7915
Refractive index1.5928
Boiling Point111℃
Melting Point53℃
Solubility不溶于水,溶于多数有机溶剂。

别名和识别编码

Chemical NameAzinphos-ethyl
MDL NumberMFCD00055539
Beilstein Registry Number0297468
CAS Number2642-71-9
EC Number220-147-6
Synonym ,3-benzotriazin-4(3h)-one 3,4-Dihydro-4-oxo-3-benzotriazinylmethyl O,O-diethyl phosphorodithioate 3,4-dihydro-4-oxo-3-benzotriazinylmethylo,o-diethylphosphorodithio 3-diethyloxyphosphinothioylthiomethyl-1,2,3-benzotriazin-4(3h)-one O,O-diethyl S-[(4-oxo-1,2,3-benzotriazin- O,O-diethyl S-[(4-oxo-1,2,3-benzotriazin-3(4H)-yl)methyl] phosphorodithioate AZINUGEC E Azinophos-ethyl Azinos Azinphos-ethyl (ISO) Azinphos-etile Bayer 16259 Bionex COTNION-ETHYL Cotnion-ethyl Ethyl Guthion GUTHION ETHYL O,O-DIETHYL-S-[4-OXO-1,2,3-BENZO TRIAZIN-3-[4H]-YLMETHYL]PHOSPHORODITHIOATE O,O-Diaethyl-S-(4-oxobenzotriazin-3-methyl)-dithiophosphat O,O-Diethyl phosphorodithioate S-ester with {PubChem}
Chemical Name Translation乙基古硫磷标准溶液
Wiswesser Line NotationT66 BNNNVJ D1SPS&O2&O2
PubChem Substance ID17531
InChIInChI=1S/C12H16N3O3PS2/c1-3-17-19(20,18-4-2)21-9-15-12(16)10-7-5-6-8-11(10)13-14-15/h5-8H,3-4,9H2,1-2H3
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分类

  • A, A-B, AR to AZ, Acaricides, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Insecticides, Method Specific, Oeko-Tex Standard 100, Organophorous, Pesticides, Pesticides & Metabolites
  • {SNA} A-B, Acaricides, Additional Standards, Analytical Standards, Insecticides, Method and Regulation Specific, Oeko-Tex Standard 100, Organophorous, Pesticid
  • {uni_hamburg} no charge; nitrogen heterocycle; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; amide; lactame; 1fragment

产品应用

  • 该品味有机磷杀虫杀螨剂,有很好的稳定性和持久性,主要用于防治棉花,果树,蔬菜等作物的害虫。

相关文献及参考

  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSTD8400000
GHS Symbol
WGK Germany3
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P301+P316
  • P302+P352
  • P302+P352+P312
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H300 Fatal if swallowed 吞食致命
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Hazard Codes T+,N
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Signal word Danger
Packing GroupII
Hazard Class6.1(a)
Storage condition 储存温度2-8℃ 0-6°C
UN Number 2783
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Risk Statements
  • R24 Toxic in contact with skin 与皮肤接触有毒
  • R50/53
  • R28 Very toxic if swallowed 吞咽极毒
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OB

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 7 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARSIM* Agricultural Research Service, USDA Information Memorandum.
   (Beltsville, MD 20705)  Volume(issue)/page/year: 20,2,1966

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 390 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GYAV "Pflanzenschutz-und Schaedlingsbekaempfungsmittel: Abriss einer
   Toxikologie und Therapie von Vergiftungen," 2nd ed., Klimmer, O.R.,
   Hattingen, Fed. Rep. Ger., Hundt-Verlag, 1971  Volume(issue)/page/year:
   -,16,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - chicken
DOSE/DURATION           : 34400 ug/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - flaccid paralysis without anesthesia
   (usually neuromuscular blockage)
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   11,49,1967

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :

其他信息

  • 灭火剂:砂土、干粉、泡沫
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • Sigma Aldrich:2642-71-9(sigmaaldrich)
  • 类别:农药
  • 毒性分级:剧毒
  • MOL 文件:2642-71-9.mol
  • 杀虫剂单一组分标准液
  • 用途一:该品为有机磷杀虫杀螨剂,有很好的稳定性和持久性,主要用于防治棉花、果树、蔬菜等作物的害虫。
  • 上游原料:氨茴酸甲酯
  • 溶于苯、丙酮,不溶于水,20℃时的蒸气压为0.293*10-4pa,对热稳定性好,遇碱易水解。
  • 方法一:由邻氨基苯甲酸甲酯经重氮化、环合、羟甲基化、氯甲基化、缩合而得。
  • 急性毒性:口服-大鼠 LD50: 7 毫克/公斤
  • 可燃性危险特性:明火可燃; 受热放出有毒氧化氮、氧化硫、氧化磷气体
  • MSDS 信息:乙基谷硫磷(2642-71-9).msds
  • 外观性质:无色针状结晶。

系列性分类


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