Piperazine-2,5-Dione 2,5-哌嗪二酮

CAS 106-57-0 MFCD00006009

化学结构图

106-57-0
SMILES: O=C1CNC(=O)CN1

化学属性

Mol. FormulaC4H6N2O2
Mol. Weight114.10
Melting Point300°C
TSCAYes
Boiling Point573.6°C at 760 mmHg

别名和识别编码

Chemical NamePiperazine-2,5-Dione
MDL NumberMFCD00006009
CAS Number106-57-0
Synonym Piperazine-2,5-dione {LY} Piperazine-2,5-dione {} {LY} Piperazine-2,5-dione {} {} {LY} Piperazine-2,5-dione {} {} {} {LY} Piperazine-2,5-dione {} {} {} {} {LY} Piperazine-2,5-dione {} {} {} {} {} {LY} Piperazine-2,5-dione {} {} {} {} {} {} {LY} Piperazine-2,5-dione {} {} {} {} {} {} {} {LY} Piperazine-2,5-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Piperazine-2,5-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Piperazine-2,5-dione {} {} {} {} {} {} {} {} {} {} {LY} Piperazine-2,5-dione {} {} {} {} {} {} {} {} {} {} {} {LY} Piperazine-2,5-dione {} {} {} {} {} {} {} {} {} {} {} {} {LY} Piperazine-2,5-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Piperazine-2,5-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Piperazine-2,5-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Piperazine-2,5-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID7817
Beilstein Registry Number24,264
EC Number203-411-5
Merck Number7466
Chemical Name Translation2,5-哌嗪二酮
Reaxys-RN112112
LabNetwork Molecule IDLN00194244
InChIInChI=1S/C4H6N2O2/c7-3-1-5-4(8)2-6-3/h1-2H2,(H,5,8)(H,6,7)
Canonical SMILESO=C(CN1)NCC1=O
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分类

  • {SA} Amino Acid Derivatives, Chemical Biology, Chemical Synthesis, Glycine, Peptide Chemistry
  • {uni_hamburg} no charge; nitrogen heterocycle; alicycle; 6RingOnly; 6ring; amide; lactame; 1fragment
  • {SNA} A - H, Amino Acids, Modified Amino Acids, 生化试剂
  • {SNA} A - H, Amino Acids, Biochemicals and Reagents, Modified Amino Acids

相关文献及参考

  • Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.
  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
  • {uni_ham

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
RTECSTL6325250
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 6,227,1954

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Alfa Aesar:甘氨酸酐,99% Glycine anhydride, 99%(106-57-0)
  • Sigma Aldrich:106-57-0(sigmaaldrich)
  • 用途一:用作生化试剂。被碱、酸或热水水解可得甘氨酰甘氨酸。
  • Acros Organics:甘氨酸酐/2,5-哌嗪二酮 Glycine anhydride, 98%(106-57-0)
  • 方法一:由甘氨酸缩合而得。将甘氨酸与乙二胺按1:5混合后搅拌加热,174-176℃反应50min,然后置于冰室中过认,过滤出结晶,用甲醇洗涤,干燥得甘氨酰酐。也可以由甘氨酸在脱水的甘油中缩合而制备。
  • 下游产品:2-对氯苯基肌氨酸
  • MOL 文件:106-57-0.mol
  • 甘氨酸酐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 G0100 甘氨酸酐 Glycine Anhydride 25G 332元 2014/06/02 G0100 甘氨酸酐 Glycine Anhydride 500G 2760元 2010/06/21 120080050 甘氨酸酐 Glycine anhydride 98% 5 GR 444元
  • 图谱信息:甘氨酸酐(106-57-0)核磁图( 13 CNMR) 甘氨酸酐(106-57-0)质谱(MS) 甘氨酸酐(106-57-0)红外图谱(IR1) 甘氨酸酐(106-57-0)红外图谱(IR2) 甘氨酸酐(106-57-0)核磁图( 1 HNMR)
  • TCI Shanghai:甘氨酸酐 Glycine Anhydride,>;98.0%(N)(106-57-0)

系列性分类


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