2-Phenylpyridine 2-苯基吡啶

CAS 1008-89-5 MFCD00006280

化学结构图

1008-89-5
SMILES: c1ccc(-c2ccccn2)cc1

化学属性

Refractive index1.6220 to 1.6270
TSCANo
Melting Point-5°
Solubility不与水混溶,溶于乙醇、乙醚。
Mol. FormulaC11H9N
Mol. Weight155
Density1.086
Flash Point230°C
Appearance amber liquid
Stabilityair sensitive
Boiling Point268-270

别名和识别编码

Chemical Name2-Phenylpyridine
Alfabeta NamePHENYLPYRIDINE 2-
MDL NumberMFCD00006280
PubChem Substance ID13887
EC Number213-763-1
Beilstein Registry Number110445
Reaxys-RN110445
Synonym 2-Azabiphenyl
Chemical Name Translation2-苯基吡啶
LabNetwork Molecule IDLN00009070
InChIInChI=1S/C11H9N/c1-2-6-10(7-3-1)11-8-4-5-9-12-11/h1-9H
CAS Number1008-89-5
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分类

  • {SNA} Building Blocks, C11, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines
  • Building Blocks, C11, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines
  • {uni_hamburg} no charge; nitrogen heterocycle; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

产品应用

  • 常用的合成中间体。

相关文献及参考

  • Short: II/3
  • With terminal alkenes in the presence of Wilkinson's catalyst (Chlorotris(triphenyl­phosphine)­rhodium(I)­, 10468), alkylation occurs in the benzene ring, to give mainly the 2-alkylphenyl derivative, together with some of the 2,6-dialkyl derivative: J. Chem. Soc., Perkin 1, 2201 (1996).
  • Beilstein:20(3/4)3639
  • Short: III/35B

安全信息

Warnings IRRITANT, IRRITANT-HARMFUL
GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSUT7140900
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Signal word Warning
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Storage condition 充氩保存
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 200 ppm
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 163,23,1986

TYPE OF TEST            : Sex chromosome loss and nondisjunction
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 250 ppm
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 163,23,1986

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 300 ppm
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 163,23,1986

其他信息

  • 2-苯基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xp300021 3-苯基吡啶;β-吡啶基苯 5ml 298元 2011/04/16 P1039 2-苯基吡啶 2-Phenylpyridine 5G 451元 2011/04/16 P1039 2-苯基吡啶 2-Phenylpyridine 25G 1600元
  • MOL 文件:1008-89-5.mol
  • 外观:棕色液体
  • 用途一:常用的合成中间体。
  • Sigma Aldrich:1008-89-5(sigmaaldrich)
  • 图谱信息:2-苯基吡啶(1008-89-5)红外图谱(IR1) 2-苯基吡啶(1008-89-5)质谱(MS) 2-苯基吡啶(1008-89-5)核磁图( 1 HNMR) 2-苯基吡啶(1008-89-5)核磁图( 13 CNMR)
  • 不与水混溶,溶于乙醇、乙醚。
  • Alfa Aesar:2-苯基吡啶,98% 2-Phenylpyridine, 98%(1008-89-5)
  • 海关编码:29333999
  • F:10
  • TCI Shanghai:2-苯基吡啶 2-Phenylpyridine,>;98.0%(GC)(1008-89-5)
  • MSDS 信息:2-Phenylpyridine(1008-89-5).msds
  • Acros Organics:2-苯基吡啶 2-Phenylpyridine,97%(1008-89-5)

系列性分类