2-Amino-4-methyl-3-nitropyridine 2-氨基-4-甲基-3-硝基吡啶

CAS 6635-86-5 MFCD00006315

化学结构图

6635-86-5
SMILES: Cc1ccnc(N)c1[N+](=O)[O-]

化学属性

Mol. FormulaC6H7N3O2
Mol. Weight153.14
Melting Point136-140°C
TSCANo
Density1.354
Boiling Point306.8°C at 760 mmHg

别名和识别编码

Chemical Name2-Amino-4-methyl-3-nitropyridine
CAS Number6635-86-5
Alfabeta NameAMINOMETHYLNITROPYRIDINE 243-----
MDL NumberMFCD00006315
Synonym 2-Amino-4-methyl-3-nitropyridine {LY} 2-Amino-4-methyl-3-nitropyridine 2-amino-4-methyl-3-nitropyridine {} {LY} 2-Amino-4-methyl-3-nitropyridine {} {} {LY} 2-Amino-4-methyl-3-nitropyridine {} {} {} {LY} 2-Amino-4-methyl-3-nitropyridine {} {} {} {} {LY} 2-Amino-4-methyl-3-nitropyridine {} {} {} {} {} {LY} 2-Amino-4-methyl-3-nitropyridine {} {} {} {} {} {} {LY} 2-Amino-4-methyl-3-nitropyridine {} {} {} {} {} {} {} {LY} 2-Amino-4-methyl-3-nitropyridine {} {} {} {} {} {} {} {} {LY} 2-Amino-4-methyl-3-nitropyridine {} {} {} {} {} {} {} {} {} {LY} 2-Amino-4-methyl-3-nitropyridine {} {} {} {} {} {} {} {} {} {} {LY} 2-Amino-4-methyl-3-nitropyridine {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Amino-4-methyl-3-nitropyridine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Amino-4-methyl-3-nitropyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Amino-4-methyl-3-nitropyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Amino-4-methyl-3-nitropyridine {} {} {}
EC Number000-000-0
Beilstein Registry Number139111
PubChem Substance ID243166
Reaxys-RN139111
Chemical Name Translation2-氨基-4-甲基-3-硝基吡啶
LabNetwork Molecule IDLN00219820
InChIInChI=1S/C6H7N3O2/c1-4-2-3-8-6(7)5(4)9(10)11/h2-3H,1H3,(H2,7,8)
Canonical SMILESNC1=NC=CC(C)=C1[N+]([O-])=O
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分类

  • {SNA} Building Blocks, C6, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines
  • Heterocycles
  • Amines
  • Aromatics

相关文献及参考

  • Beilstein:22(5)9,343

安全信息

Warnings IRRITANT
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn Xi Xi,Xn
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • MOL 文件:6635-86-5.mol
  • Acros Organics:2-氨基-3-硝基-4-甲基吡啶 2-Amino-3-nitro-4-picoline, 98%(6635-86-5)
  • 2-氨基-3-硝基-4-甲基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A1888 2-氨基-4-甲基-3-硝基吡啶 2-Amino-4-methyl-3-nitropyridine 1G 237元 2014/06/02 A1888 2-氨基-4-甲基-3-硝基吡啶 2-Amino-4-methyl-3-nitropyridine 5G 659元 2010/06/21 319550050 2-氨基-3-硝基-4-甲基吡啶 2-Amino-3-nitro-4-picoline 98% 5 GR 852元
  • 图谱信息:2-氨基-3-硝基-4-甲基吡啶(6635-86-5)核磁图( 1 HNMR) 2-氨基-3-硝基-4-甲基吡啶(6635-86-5)核磁图( 13 CNMR) 2-氨基-3-硝基-4-甲基吡啶(6635-86-5)质谱(MS) 2-氨基-3-硝基-4-甲基吡啶(6635-86-5)红外图谱(IR1)
  • 下游产品:N-(4-甲基-2-氨基吡啶-3-基)-2-氯吡啶-3-甲酰胺
  • Hazard Note:Irritant
  • TCI Shanghai:2-氨基-4-甲基-3-硝基吡啶 2-Amino-4-methyl-3-nitropyridine,>;98.0%(GC)(T)(6635-86-5)
  • Alfa Aesar:2-氨基-4-甲基-3-硝基吡啶,97% 2-Amino-4-methyl-3-nitropyridine, 97%(6635-86-5)
  • F:10
  • Sigma Aldrich:6635-86-5(sigmaaldrich)

系列性分类

  1. C6 - Pyridines
  1. C6 to C7 - Pyridines
  1. C5
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶

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