3-Hydroxy-6-methylpyridine 3-羟基-6-甲基吡啶

CAS 1121-78-4 MFCD00006339

化学结构图

1121-78-4
SMILES: Cc1ccc(O)cn1

化学属性

Mol. FormulaC6H7NO
Mol. Weight109
Melting Point168-170
TSCANo

别名和识别编码

Chemical Name3-Hydroxy-6-methylpyridine
CAS Number1121-78-4
Alfabeta NameHYDROXYMETHYLPYRIDINE 52---
MDL NumberMFCD00006339
Synonym 2-METHYL-5-HYDROXY PYRIDINE 2-Methylpyridin-5-ol 2-甲基-5-羟基吡啶 3-HYDOXY-6-METHYLPYRIDINE 3-HYDROXY-6-METHYLPYRIDINE 3-HYDROXY-6-METHYLPYRIDINE 99% 3-Hydroxy-6-methylpyridine 3-羟基-6-甲基吡啶 5-HYDROXY-2-METHYLPYRIDINE 5-HYDROXY-2-METHYLPYRIDINE 99% 5-Hydroxy-2-picoline 5-Hydroxy-2-picoline,6-Methyl-3-pyridinol 5-羟基-2-甲基吡啶 6-METHYL-3-HYDROXYPYRIDINE 6-METHYL-3-PYRIDINOL 6-METHYLPYRIDIN-3-OL 6-Methyl-3-pyridineol 6-Methyl-3-pyridinol 6-methyl-3-pyridino 6-甲基-3-吡啶醇 TIMTEC-BB SBB004349
PubChem Substance ID87571128
EC Number214-337-8
Beilstein Registry Number107077
Reaxys-RN107077
Chemical Name Translation3-羟基-6-甲基吡啶
Wiswesser Line NotationT6NJ B1 EQ
LabNetwork Molecule IDLN00004546
InChIInChI=1S/C6H7NO/c1-5-2-3-6(8)4-7-5/h2-4,8H,1H3
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分类

  • {SNA} Building Blocks, C6, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines

相关文献及参考

  • Starting material for two different diastereoselective synthetic routes to the antibiotic L-azatyrosine: J. Org. Chem., 59, 6850 (1994); 61, 813 (1996).

安全信息

Warnings IRRITANT
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
RTECSUU7714900
Signal word Danger
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Hazard Codes Xn
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 846 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TOXIA6 Toxicon.  (Pergamon Press Ltd., Headington Hill Hall, Oxford OX3 OBW,
   UK)  V.1-    1962-  Volume(issue)/page/year: 23,815,1985

其他信息

  • 3-羟基-6-甲基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0763 5-羟基-2-甲基吡啶 5-Hydroxy-2-methylpyridine 25G 811元 2010/06/21 148110250 3-羟基-6-甲基吡啶 3-Hydroxy-6-methylpyridine 99% 25 GR 848元 2010/06/21 148111000 3-羟基-6-甲基吡啶 3-Hydroxy-6-methylpyridine 99% 100 GR 1861元
  • TCI Shanghai:5-羟基-2-甲基吡啶 5-Hydroxy-2-methylpyridine,>;98.0%(T)(1121-78-4)
  • Alfa Aesar:5-羟基-2-甲基吡啶,99% 5-Hydroxy-2-methylpyridine, 99%(1121-78-4)
  • Sigma Aldrich:1121-78-4(sigmaaldrich)
  • MSDS 信息:6-Methyl-3-pyridinol(1121-78-4).msds
  • Acros Organics:3-羟基-6-甲基吡啶 3-Hydroxy-6-methylpyridine, 99%(1121-78-4)
  • MOL 文件:1121-78-4.mol
  • 图谱信息:3-羟基-6-甲基吡啶(1121-78-4)核磁图( 1 HNMR) 3-羟基-6-甲基吡啶(1121-78-4)红外图谱(IR1) 3-羟基-6-甲基吡啶(1121-78-4)红外图谱(IR2) 3-羟基-6-甲基吡啶(1121-78-4)质谱(MS) 3-羟基-6-甲基吡啶(1121-78-4)核磁图( 13 CNMR)
  • 下游产品:6-溴-5-甲氧基-2-羧酸吡啶 --> 4,5-二氯-2-甲基吡啶 --> 2-溴-3-甲氧基-6-甲基吡啶 --> 3-羟基-6-甲基-2-吡啶甲醇 --> 2-溴-3-羟基-6-甲基吡啶
  • 上游原料:盐酸 --> 亚硝酸钠 --> 3-氨基-6-甲基吡啶

系列性分类


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