4-Pyridinemethanol, 97.5% 4-吡啶甲醇

CAS 586-95-8 MFCD00006442

化学结构图

586-95-8
SMILES: OCc1ccncc1

化学属性

Mol. FormulaC6H7NO
Mol. Weight109.13
Boiling Point107-110°C at 760 mmHg
Melting Point52-56°C
TSCAT
Flash Point113°C
Solubility可溶
Density1.131
Stability易吸潮

别名和识别编码

Chemical Name4-Pyridinemethanol, 97.5%
CAS Number586-95-8
Alfabeta NamePYRIDINEMETHANOL 4--
MDL NumberMFCD00006442
Synonym 4-Pyridinemethanol {LY} 4-Pyridinemethanol {} {LY} 4-Pyridinemethanol {} {} {LY} 4-Pyridinemethanol {} {} {} {LY} 4-Pyridinemethanol {} {} {} {} {LY} 4-Pyridinemethanol {} {} {} {} {} {LY} 4-Pyridinemethanol {} {} {} {} {} {} {LY} 4-Pyridinemethanol {} {} {} {} {} {} {} {LY} 4-Pyridinemethanol {} {} {} {} {} {} {} {} {LY} 4-Pyridinemethanol {} {} {} {} {} {} {} {} {} {LY} 4-Pyridinemethanol {} {} {} {} {} {} {} {} {} {} {LY} 4-Pyridinemethanol {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Pyridinemethanol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Pyridinemethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Pyridinemethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Pyridinemethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Pyridinemethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Pyridinemethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Pyridinemethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Pyr
EC Number209-590-6
Beilstein Registry Number107850
PubChem Substance ID11472
Reaxys-RN107850
Chemical Name Translation4-吡啶甲醇
InChIKeyPTMBWNZJOQBTBK-UHFFFAOYSA-N
Wiswesser Line NotationT6NJ D1Q
LabNetwork Molecule IDLN00004770
InChIInChI=1S/C6H7NO/c8-5-6-1-3-7-4-2-6/h1-4,8H,5H2
Canonical SMILESOCC1=CC=NC=C1
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分类

  • {SNA} Building Blocks, C6, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines

相关文献及参考

  • Beilstein:21(3/4)507
  • Has been used to prepare 4-picolyl esters, by DCC coupling, as a polar protection method for the carboxyl group during peptide synthesis: J. Chem. Soc. (C), 1911 (1969). For further details of the 'handle' method of peptide synthesis, see 4-Chloromethyl­pyridine hydrochloride, A12859.

安全信息

Warnings IRRITANT, HYGROSCOPIC, KEEP COLD
RTECSUT4691000
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {}
GHS Symbol
WGK Germany3
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Hazard Codes Xi
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PHARAT Pharmazie.  (VEB Verlag Volk und Gesundheit, Neue Gruenstr. 18,
   Berlin DDR-1020, Ger. Dem. Rep.)  V.1-    1946-  Volume(issue)/page/year:
   11,242,1956

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 422 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,355,1983

其他信息

  • MSDS 信息:4-(Hydroxymethyl)pyridine(586-95-8).msds
  • 溶于水。
  • 海关编码:29333999
  • TCI Shanghai:4-吡啶甲醇 4-Pyridinemethanol,>;97.0%(GC)(586-95-8)
  • 存储注意事项:空气敏感;湿度敏感
  • Acros Organics:4-吡啶甲醇 4-(Hydroxymethyl)pyridine, 99%(586-95-8)
  • 图谱信息:4-吡啶甲醇(586-95-8)核磁图( 13 CNMR) 4-吡啶甲醇(586-95-8)红外图谱(IR2) 4-吡啶甲醇(586-95-8)核磁图( 1 HNMR) 4-吡啶甲醇(586-95-8)质谱(MS) 4-吡啶甲醇(586-95-8)红外图谱(IR1)
  • Alfa Aesar:4-吡啶甲醇,99% 4-Pyridinemethanol, 99%(586-95-8)
  • Sigma Aldrich:586-95-8(sigmaaldrich)
  • Hazard Note:Irritant
  • 敏感性:Hygroscopic
  • MOL 文件:586-95-8.mol
  • F:10-21
  • 4-吡啶甲醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0751 4-吡啶甲醇 4-Pyridinemethanol 25G 437元 2014/06/02 P0751 4-吡啶甲醇 4-Pyridinemethanol 500G 4040元 2010/06/21 166110250 4-吡啶甲醇 4-(Hydroxymethyl)pyridine 99% 25 GR 754元
  • 下游产品:1,2-二(4-吡啶基)乙烯 --> 2-氰基吡啶-4-醛 --> 4-羟甲基吡啶-2-腈
  • TSCA:T

系列性分类


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