1,2,3,4-Tetrahydroquinoline 1,2,3,4-四氢喹啉

CAS 635-46-1 MFCD00006693

化学结构图

635-46-1
SMILES: c1ccc2c(c1)CCCN2

化学属性

Mol. FormulaC9H11N
Mol. Weight133
Refractive index1.5910 to 1.5960
Boiling Point249
Density1.061
Melting Point9-14
Flash Point113°C(lit.)
TSCAYes
Appearance 浅黄色油状液体,密度 1.061,熔点 15-17℃ ,沸点 249℃,折射率 1.593-1.595,闪点 100 ℃,水溶性 <;1g/L (20℃)
Solubility<1 g/L (20 °C)

别名和识别编码

Chemical Name1,2,3,4-Tetrahydroquinoline
CAS Number635-46-1
Alfabeta NameTETRAHYDROQUINOLINE 1234-,,,
MDL NumberMFCD00006693
Synonym 1,2,3,4-TETRAHYDROQUINOLINE 1,2,3,4-四硝基喹啉 1-AZATETRALIN Quinoline,1,2,3,4-tetrahydro- THQ
PubChem Substance ID69460
Beilstein Registry Number20,262
EC Number211-237-6
Chemical Name Translation1,2,3,4-四氢喹啉
Reaxys-RN116149
LabNetwork Molecule IDLN00173493
InChIInChI=1S/C9H11N/c1-2-6-9-8(4-1)5-3-7-10-9/h1-2,4,6,10H,3,5,7H2
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分类

  • Building Blocks, C8 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Quinolines
  • {SNA} Alphabetical Listings, Flavors and Fragrances, Q-Z
  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Isoquinolines

相关文献及参考

  • Beilstein:20,262
  • 1,2,3,4-Tetrahydroquinoline derivatives are oxidized to N-hydroxy lactams by H2O2 in the presence of tungstate ion: J. Org. Chem., 55, 1744 (1990):
  • 2-Metallation can be effected in a one-pot sequence via the Li carbamate: J. Chem. Soc., Perkin 1, 17 (1989); cf Indole, A14427.

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard Codes T Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H350 May cause cancer 可能致癌
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Signal word Danger Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R45 May cause cancer 可能致癌
Storage condition 储存温度2-8℃ 0-10°C

其他信息

  • 用途一:用于有机合成
  • MOL 文件:635-46-1.mol
  • TCI Shanghai:1,2,3,4-四氢喹啉 1,2,3,4-Tetrahydroquinoline,>;95.0%(GC)(635-46-1)
  • 1,2,3,4-四氢喹啉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010240 1,2,3,4-四氢喹啉 100g 360元 2011/04/16 T0113 1,2,3,4-四氢喹啉 1,2,3,4-Tetrahydroquinoline 25ML 208元 2011/04/16 T0113 1,2,3,4-四氢喹啉 1,2,3,4-Tetrahydroquinoline 500ML 1550元
  • Alfa Aesar:1,2,3,4-四氢喹啉,99% 1,2,3,4-Tetrahydroquinoline, 99%(635-46-1)
  • 水中溶解度: <1 g/L (20°C), 溶于乙醇。
  • 海关编码:29334990
  • Acros Organics:1,2,3,4-四氢喹啉 1,2,3,4-Tetrahydroquinoline, 98%(635-46-1)
  • 检测方法:GC,NMR
  • MSDS 信息:1,2,3,4-Tetrahydroquinoline(635-46-1).msds
  • Sigma Aldrich:635-46-1(sigmaaldrich)
  • 图谱信息:1,2,3,4-四氢喹啉(635-46-1)质谱(MS) 1,2,3,4-四氢喹啉(635-46-1)核磁图( 13 CNMR) 1,2,3,4-四氢喹啉(635-46-1)核磁图( 1 HNMR) 1,2,3,4-四氢喹啉(635-46-1)红外图谱(IR1)

系列性分类


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