Lead(II) Carbonate Basic 碱式碳酸铅(II)

CAS 1319-46-6 MFCD00078155

化学结构图

1319-46-6
SMILES: O=C([O-])[O-].O=C([O-])[O-].O[PbH2]O.[PbH6+2].[PbH6+2]

化学属性

Mol. FormulaC2H2O8Pb3
Mol. Weight775.63
Melting Point400 °C
Density6.14
SolubilitySoluble in acids, insoluble in water or alcohol
TSCAYes
Appearance 白色粉末状，六方晶系。 不溶于水及乙醇，可溶于醋酸、硝酸。
Stability对湿度敏感

别名和识别编码

Chemical NameLead(II) Carbonate Basic
MDL NumberMFCD00078155
CAS Number1319-46-6
PubChem Substance ID24854621
EC Number215-290-6
Synonym Lead carbonate hydroxide {LY} Lead carbonate hydroxide {} {LY} Lead carbonate hydroxide {} {} {LY} Lead carbonate hydroxide {} {} {} {LY} Lead carbonate hydroxide {} {} {} {} {LY} Lead carbonate hydroxide {} {} {} {} {} {LY} Lead carbonate hydroxide {} {} {} {} {} {} {LY} Lead carbonate hydroxide {} {} {} {} {} {} {} {LY} Lead carbonate hydroxide {} {} {} {} {} {} {} {} {LY} Lead carbonate hydroxide {} {} {} {} {} {} {} {} {} {LY} Lead carbonate hydroxide {} {} {} {} {} {} {} {} {} {} {LY} Lead carbonate hydroxide {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Lead carbonate hydroxide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Lead carbonate hydroxide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Lead carbonate hydroxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Lead carbonate hydroxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Lead carbonate hydroxide {} {} {} {} {} {} {} {} {} {} {}
Merck Number14,1005
Chemical Name Translation碱式碳酸铅(II)
LabNetwork Molecule IDLN00197931
Canonical SMILESO=C([Pb][Pb][Pb]C(OOO)=O)OOO
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分类

  • {SNA} Essential Chemicals, Lead Salts, Materials Science, Metal and Ceramic Science, Research Essentials, Salts
  • {SNA} Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, Puriss
  • {SNA} Essential Chemicals, Lead Salts, Metal and Ceramic Science, Research Essentials, Salts, 材料科学

产品应用

  • 防锈漆，滤光着色玻璃。

相关文献及参考

  • Merck: 14,1005

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P304+P340+P312
  • P308+P313
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P312+P330
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Signal word Danger
Hazard statements
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H302+H332
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
RTECSOF9275000
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Gloves, type P2 (EN 143) respirator cartridges
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Packing GroupIII
UN Number UN3077 UN 2291 6.1/PG 3 2291
Risk Statements
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R33 Danger of cumulative effects 有累积作用的危险
  • R50/53
Hazard Codes T,N T;N
Hazard Class6.1
Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store

其他信息

  • 方法一:云母钛珠光颜料的制备方法如下： 云母粉→研磨→分级→脱水→合成→洗涤→干燥→煅烧→表面处理→干燥→包装→成品
  • {Che
  • 水中溶解度(g/100ml):每100毫升水中的溶解克数: 7.269×10-5/20℃
  • 用途四:无机颜料。可用于圆网或凹版壁纸生产线。用于涂料的氨基或丙烯酸类烘漆：加量2%～8%。涂装于汽车、摩托车、自行车
  • 有毒，能溶于乙酸或稀硝酸而起泡沫，不溶于水或醇。在400度分解而析出一氧化铅的残留物，商业上常将本品称为碳酸铅。
  • 用途六:是制陶瓷彩釉、绘画涂料和化妆用品的原料。用作聚氯乙烯塑料稳定剂。用于制珠光塑料、珠光漆料以及户外用漆。
  • 图谱信息:碱式碳酸铅(1319-46-6)Raman光谱 碱式碳酸铅(1319-46-6)红外图谱(IR2) 碱式碳酸铅(1319-46-6)红外图谱(IR1)
  • 所属类别二:颜料: 无机颜料
  • 碱式碳酸铅价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 20021360 碱式碳酸铅 500g 43元 2010/06/21 222710100 碱式碳酸铅 Lead(II) carbonate, basic , extra pure, -325 mesh 10 KG 39
  • 毒性:早期症状为齿龈边缘出现铅线及尿中毒。慢性中毒有神经系统的变化，出现衰弱综合症、脑病、运动失调、血液系统改变、代谢和内分泌障碍、胃肠道的改变及心血管系统的改变。 铅及铅的无机化合物的最高容许浓度为0.01 mg/m 3 ，工作日平均浓度为0.07 mg/m 3 。 中毒出现绞痛时，应皮下注射阿托品、吗啡，静脉注射硫酸镁、硫代硫酸钠、氯化钙。工作时戴口罩可阻滞95%～97%的铅粉尘；蒸气浓度高时，可使用过滤式防毒面具，强制供给新鲜空气。工作场所严禁进食、吸烟，工作后必须洗浴，饭前班后要漱口、刷牙；洗浴之前，用1%醋酸溶液或去污膏清洗手和其他污染部位。
  • 方法三:沉淀法。反应方程式： 2PbO+2HAc→Pb(Ac)2·Pb(OH)2 3[Pb(Ac)2·Pb(OH)2]+2CO2→3Pb(Ac)2+2PbCO2·Pb(OH)2+2H2O 操作方法：将水、冰醋酸投入反应器中，配成6.0%～6.5%(质量）的醋酸溶液，加热至50～60℃，强烈搅拌下加入黄丹配成总浓度200～240 gPbO/L及碱度105～125gPbO/L的碱式醋酸铅溶液，在90℃反应3h，使生成碱式醋酸铅。经澄清后的清液取出，通入净化的二氧化碳碳化，二氧化碳压力20～40kPa，碳
  • 防护措施:早期症状为齿龈边缘出现铅线及尿中毒。慢性中毒有神经系统的变化，出现衰弱综合症、脑病、运动失调、血液系统改变、代谢和内分泌障碍、胃肠道的改变及心血管系统的改变。 铅及铅的无机化合物的最高容许浓度为0.01mg/m3，工作日平均浓度为0.07mg/m3。 中毒出现绞痛时，应皮下注射阿托品、吗啡，静脉注射硫酸镁、硫代硫酸钠、氯化钙。工作时戴口罩可阻滞95%～97%的铅粉尘；蒸气浓度高时，可使用过滤式防毒面具，强制供给新鲜空气。工作场所严禁进食、吸烟，工作后必须洗浴，饭前班后要漱口、刷牙；洗浴之前，用1%醋酸溶液或去污膏清洗手和其他污染部位。
  • Acros Organics:碱式碳酸
  • {C
  • 用途三:用作分析试剂，也用于油漆、颜料配制
  • 参考质量标准:参考标准 指标名称 指标 碱式碳酸铅[以2PbCO3·Pb(OH)2计]/%≥ 98.5 水分/%≤ 1 醋酸不溶物/%≤ 0.5 吸油量/% 8～12 外观 疏松白色粉末
  • 方法二:化学法将醋酸铅、氧化铅、无离子水配成反应液，通以二氧化碳、去离子水进行反应，然后经沉淀、加入硝化棉浆制浆、析出结晶、离心脱水、用酒精洗涤、干燥，制得碱式碳酸铅。酒精废液经处理回收。其 Pb(Ac)2+PbO+H2O→Pb(Ac)2·Pb(OH)2 3[Pb(Ac)2·Pb(OH)2]+2CO2→3Pb(Ac)2+2PbCO3·Pb(OH)2+2H2O 醋酸法将黄丹、冰醋酸与水在母液槽中混合，使混合液中氧化铅的浓度达230～250 g/L，在搅拌下，使之悬浮，于90℃保温3
  • 所属类别一:无机化工产品: 无机盐: Cd硝酸盐

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss - Analytical Reagents for General Use
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Salts 金属盐
  4. Lead Salts - Salts
  1. Analytical & Chromatography 分析化学与色谱
  2. Adsorbents, Filter Aids and Drying Agents
  3. Other Drying Agents
  1. Functional Group 官能团索引
  2. carbonic acid derivative

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