Amygdalin 扁桃苷

CAS 29883-15-6 MFCD00006598

化学结构图

29883-15-6
SMILES: N#CC(O[C@@H]1O[C@H](CO[C@@H]2O[C@H](CO)[C@@H](O)[C@H](O)[C@H]2O)[C@@H](O)[C@H](O)[C@H]1O)C1C=CC=CC=1

化学属性

Mol. FormulaC20H27NO11
Mol. Weight457
Melting Point223-226
TSCANo
Density1.59

别名和识别编码

Chemical NameAmygdalin
Synonym Amygdaloside D-Mandelonitrile-beta-D-glucosido-6-beta-D-glucoside D-扁桃腈-β-龙胆二糖苷 D-扁桃腈-β-龙胆二糖苷 D-扁桃腈6-O-β-D-葡糖基-β-D-葡萄糖苷 苦杏仁苷 R-Amygdalin 扁桃苷 苦杏仁苷
MDL NumberMFCD00006598
PubChem Substance ID87562069
Beilstein Registry Number66856
EC Number249-925-3
CAS Number29883-15-6
Merck Number14,597
Reaxys-RN1695110
Chemical Name Translation扁桃苷
Wiswesser Line NotationT6OTJ BOYR&CN CQ DQ EQ F1O- BT6OTJ CQ DQ EQ F1Q -D(-)
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分类

  • {SNA} Carbohydrates A to Z, Carbohydrates A-C, Disaccharide, Other Biochemical, Phytochemicals by Chemical Classification, 生化试剂, 碳水化合物, 细胞生物学, 营养研究
  • {SNA} Carbohydrates A to Z, Carbohydrates A-C, Other Biochemical, Phytochemicals by Chemical Classification, 生化试剂, 碳水化合物,
  • {SNA} Carbohydrates A to Z, Carbohydrates A-C, Other Biochemical, Phytochemicals by Chemical Classification, 生化试剂, 碳水化合物, 细胞生物学, 营养研究
  • {SNA} Other Biochemical, Phytochemicals by Chemical Classification, 细胞

产品应用

  • 生氰的糖苷是苦杏仁和杏仁凹点的组成部分。没有科学证据证明扁桃苷是抗癌物。最近的研究：联上瘤单克隆抗体的β−葡糖苷（β−glucoside）在瘤细胞里释放出氰，显示出很明显的细胞毒性。

相关文献及参考

  • Merck: 14,597
  • Merck: 14,597 Beilstein:17(3/4)3614

安全信息

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RTECSOO8450000
Hazard statements
  • H302 Harmful if swallowed 吞食有害
WGK Germany3
Signal word Warning
GHS Symbol
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Codes Xn
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P301+P312+P330
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 405 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Vol

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human - infant
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Behavioral - coma
   Lungs, Thorax, or Respiration - dyspnea
   Gastrointestinal - nausea or vomiting
REFERENCE :
   JAMAAP JAMA, Journal of the American Medical Association.  (AMA, 535 N.
   Dearborn St., Chicago, IL 60610)  V.1-    1883-  Volume(issue)/page/year:
   238,482,1977

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 443 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
   YAKUD5 Gekkan Yakuji.  Pharmaceuticals Monthly.  (Yakugyo Jihosha, Inaoka
   Bldg., 2-36 Jinbo-cho, Kanda, Chiyoda-ku, Tokyo 101, Japan)  V.1-   1959-
   Volume(issue)/page/year: 29,1291,1987

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB288-559

TYPE OF TEST            : Host-mediated assay
TEST SYSTEM             : Rodent - mouse Bacteria - Salmonella typhimurium
DOSE/DURATION           : 250 mg/kg
REFERENCE :
   SCIEAS Science.  (American Assoc. for the Advancement of Science, 1333 H
   St., NW, Washington, DC 20005)  V.1-    1895-  Volume(issue)/page/year:
   198,625,1977

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - hamster
DOSE                    : 300 mg/kg
SEX/DURATION            : female 8 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - Central Nervous System
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   SCIEAS Science.  (American Assoc. for the Advancement of Science, 1333 H
   St., NW, Washington, DC 20005)  V.1-    1895-  Volume(issue)/page/year:
   215,1513,1982

其他信息

  • 三水合物为斜方柱状结晶(水), lg溶于900ml乙醇及11ml沸乙醇, 易溶于沸水。UVλMeOHmax nm(ε): 268(179), 262(255), 257(256), 251198), 208(7210); IRνmax cmˉ1: 3330, 2860, 1640, 1590, 1490, 1450, 1270, 1160, 1060, 690[1]。 植物来源：蔷薇科植物桃Prunus persica （L.）Batsch种子，巴旦杏P.amygdalus Batsch
  • lg溶于900ml乙醇及11ml沸乙醇, 易溶于沸水。UVλMeOHmax nm(ε): 268(179), 262(255), 257(256), 251198), 208(7210); IRνmax cmˉ1: 3330, 2860, 1640, 1590, 1490, 1450, 1270, 1160, 1060, 690[1]。 水中溶解度:83 G/L (25°C)，溶于醇、醚 植物来源：蔷薇科植物桃Prunus persica （L.）Batsch种子，巴旦杏P.am

系列性分类

  1. Life Science 生命科学
  2. Nutrition Research 营养研究
  3. Phytochemicals by Chemical Classification - Nutrition Research
  4. Plant Extracts - Phytochemicals by Chemical Classification
  1. Life Science 生命科学
  2. Nutrition Research 营养研究
  3. Phytochemicals by Chemical Classification - Nutrition Research
  4. Other Biochemical - Phytochemicals by Chemical Classification
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Biochemicals Found in Plants
  4. Lipids
  5. Polyunsaturated
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Nutrition Research
  4. Biochemicals Found in Plants
  5. Lipids
  6. Polyunsaturated

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