1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 1,2-双((2S,5S)-2,5-二甲基磷)乙烷(环辛二烯)四氟硼酸铑
CAS 213343-65-8 MFCD04038742
化学结构图
SMILES: C1=C\CC/C=C\CC/1.C[C@H]1CC[C@H](C)P1CCP1[C@@H](C)CC[C@@H]1C.F[B-](F)(F)F.[Rh]
化学属性
| Melting Point | 152.2-156.3 °C |
|---|---|
| Mol. Formula | Rh(C8H12)(C14H28P2)+BF4ae |
| Mol. Weight | 556 |
| Appearance | red-orange xtl. |
| Stability | air sensitive |
别名和识别编码
| Chemical Name | 1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate |
|---|---|
| Chemical Name Translation | 1,2-双((2S,5S)-2,5-二甲基磷)乙烷(环辛二烯)四氟硼酸铑 |
| Synonym | 1,2-双[(2S,5S)-2,5-二甲基磷]乙烷(环辛二烯)四氟硼酸铑(I) |
| PubChem Substance ID | 12964417 |
| InChI | InChI=1S/C14H28P2.C8H12.BF4.Rh/c1-11-5-6-12(2)15(11)9-10-16-13(3)7-8-14(16)4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h11-14H,5-10H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;/t11-,12-,13-,14-;;;/m0.../s1 |
| MDL Number | MFCD04038742 |
| CAS Number | 213343-65-8 |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
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