Triethyl Borate 硼酸三乙酯

CAS 150-46-9 MFCD00009073

化学结构图

150-46-9
SMILES: CCOB(OCC)OCC

化学属性

Mol. FormulaC6H15BO3
Mol. Weight145.99
Density0.858
Refractive index1.3730 to 1.3770
Flash Point11°C(lit.)
TSCAYes
Boiling Point117-118
Melting Point-85
Solubility可混溶于乙醇、乙醚。
Vapor Density5.04 (vs air)
Stability易吸潮

别名和识别编码

Chemical NameTriethyl Borate
Synonym Triethyl borate {LY} Triethyl borate Triethyl borate, 98+% Triethylboratecolorlessliq Triethylester kyseliny borite boricacid(h3bo3),triethylester triethylesterkyselinyborite {} {LY} Triethyl borate {} {} {LY} Triethyl borate {} {} {} {LY} Triethyl borate {} {} {} {} {LY} Triethyl borate {} {} {} {} {} {LY} Triethyl borate {} {} {} {} {} {} {LY} Triethyl borate {} {} {} {} {} {} {} {LY} Triethyl borate {} {} {} {} {} {} {} {} {LY} Triethyl borate {} {} {} {} {} {} {} {} {} {LY} Triethyl borate {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Triethyl borate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triethyl borate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triethyl borate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triethyl borate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00009073
CAS Number150-46-9
EC Number205-760-9
Beilstein Registry Number1699052
Reaxys-RN1699052
PubChem Substance ID9009
Chemical Name Translation硼酸三乙酯
Wiswesser Line Notation2OBO2&O2
LabNetwork Molecule IDLN00193297
InChIInChI=1S/C6H15BO3/c1-4-8-7(9-5-2)10-6-3/h4-6H2,1-3H3
Canonical SMILESCCOB(OCC)OCC
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分类

  • {uni_hamburg} no charge; 1fragment

产品应用

  • 合成其他有机硼化合物。高纯度硼原料。增塑剂。制造半导体元件。焊接助熔剂。防腐剂。消毒剂。抗爆剂。

相关文献及参考

  • Short: III/35E
  • Short: III/38A
  • Beilstein:1(4)1365
  • Short: IV/16

安全信息

RTECSED5075000
Packing GroupII
UN Number 1176
Risk Statements
  • R11 Highly flammable 非常易燃
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S7 Keep container tightly closed 保存在严格密闭容器中；
Storage condition 2-8°C {LY} 2-8°C Moisture Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Codes 3
WGK Germany2
Signal word Danger
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P302+P352
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
GHS Symbol
Hazard Class3
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New
   York, John Wiley & Sons, Inc., 1964  Volume(issue)/page/year: -,693,1964

Restrict 危险品

其他信息

  • 毒性分级:中毒
  • 蒸气密度:5.04 (vs air)
  • 图谱信息:硼酸三乙酯(150-46-9)核磁图( 13 CNMR) 硼酸三乙酯(150-46-9)质谱(MS) 硼酸三乙酯(150-46-9)Raman光谱 硼酸三乙酯(150-46-9)核磁图( 1 HNMR) 硼酸三乙酯(150-46-9)红外图谱(IR1) 硼酸三乙酯(150-46-9)红外图谱(IR2)
  • 可燃性危险特性:易燃; 遇水分解易燃乙醇和有毒硼酸
  • Alfa Aesar:硼酸三乙酯,97% Triethyl borate, 97%(150-46-9)
  • 用途二:用于制造半导体元件、合成有机硼化物、增塑剂、焊接助熔剂等。
  • MSDS 信息:硼酸三乙酯(150-46-9).msds
  • 爆炸物危险特性:受热高温可爆
  • Sigma Aldrich:150-46-9(sigmaaldrich)
  • 急性毒性:口服-小鼠 LD50: 2100 毫克/公斤
  • 类别:易燃液体
  • 用途三:合成其他有机硼化合物。高纯度硼原料。增塑剂。制造半导体元件。焊接助熔剂。防腐剂。消毒剂。抗爆剂。
  • 下游产品:4-氟萘-1-硼酸 --> 2-呋喃硼酸
  • TSCA:Yes
  • 海关编码:29209085
  • 硼酸三乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0520 硼酸三乙酯 Triethyl Borate 25ML 90元 2014/06/02 B0520 硼酸三乙酯 Triethyl Borate 500ML 720元 2010/06/21 139580010 硼酸三乙酯 Triethyl borate 97% 1 LT 4099元
  • F:21
  • 敏感性:Moisture Sensitive
  • 灭火剂:干粉, 二氧化碳; 1211; 泡沫
  • 用途一:用于半导体元件的制做、其他有机硼化物的合成，也用作高纯度的原料及增塑剂及焊接助熔剂
  • TCI Shanghai:硼酸三乙酯 Triethyl Borate,>;97.0%(T)(150-46-9)
  • 外观性质:无色透明液体。
  • Acros Organics:硼酸三乙酯 Triethyl borate, 97%(150-46-9)
  • MOL 文件:150-46-9.mol
  • 刺激数据:眼睛-兔子 100 毫克 轻度
  • 有轻度气味。有显著的热稳定性。易吸湿，遇水易分解成乙醇和硼酸。易燃。
  • 储运特性:库房通风低温干燥; 与氧化剂分开储运存放

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronate Esters 硼酸酯
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Organoborates - Boronic Acids and Derivatives
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Borylation Reagents

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