(11bS,11'bS)-4,4'-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (11bS,11′bS)-4,4′-(9,9-二甲基-9H-氧杂蒽-4,5-二基)双-二萘并[2,1-d:1′,2′-f][1,3,2]二噁磷杂庚英

CAS 349114-57-4 MFCD09842740

化学结构图

349114-57-4
SMILES: CC1(C)C2C=CC=C(C=2OC2C(=CC=CC1=2)P1OC2C=CC3C=CC=CC=3C=2C2C3C=CC=CC=3C=CC=2O1)P1OC2C=CC3C=CC=CC=3C=2C2C3C=CC=CC=3C=CC=2O1

化学属性

Mol. FormulaC55H36O5P2
Mol. Weight838.82
Melting Point195-207 °C (dec.)

别名和识别编码

Chemical Name(11bS,11'bS)-4,4'-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
Synonym (11bS,11′bS)-4,4′-(9,9-二甲基-9H-氧杂蒽-4,5-二基)双-二萘并[2,1-d:1′,2′-f][1,3,2]二噁磷杂庚英 S,S-Reetz X-二亚磷酸酯
MDL NumberMFCD09842740
CAS Number349114-57-4
Chemical Name Translation(11bS,11′bS)-4,4′-(9,9-二甲基-9H-氧杂蒽-4,5-二基)双-二萘并[2,1-d:1′,2′-f][1,3,2]二噁磷杂庚英
PubChem Substance ID329760513
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydrogenation, Privileged Ligands and Complexes, Reetz Ligands
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydrogenation, Privileged Ligands and Complexes, Reetz Ligands

相关文献及参考

  • 1. Reetz, M. T.; Li, X., Asymmetric hydrogenation of quinolines catalyzed by iridium complexes of BINOL-derived diphosphonites Chem. Commun. , 2159-2160, (2006)
  • 2. Goertz, W.; et al., Asymmetric nickel-catalyzed hydrocyanation of vinylarenes by applying homochiral xantphos ligands Chem. Eur. J. 7 , 1614-1618, (2001)
  • 3. Reetz, M. T.; Li, X. J. Am. Chem. Soc. 128 , 1044, (2006) 摘要

安全信息

WGK Germany3

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. Reetz Ligands - Privileged Ligands and Complexes

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