2-Bromo-5-nitropyridine 2-溴-5-硝基吡啶

CAS 4487-59-6 MFCD00006222

化学结构图

4487-59-6
SMILES: O=[N+]([O-])c1ccc(Br)nc1

化学属性

Mol. FormulaC5H3BrN2O2
Mol. Weight203
Boiling Point145-147
Melting Point139-141
Density1.834
TSCANo
Flash Point145-147°C/10mm

别名和识别编码

Chemical Name2-Bromo-5-nitropyridine
CAS Number4487-59-6
Alfabeta NameBROMONITROPYRIDINE 25---
MDL NumberMFCD00006222
Synonym 2-BORMO-5-NITROPYRIDINE 2-溴-5-硝基吡啶, 98+% 2-BROMO-5-NITROPYRIDINE NSC 73702 2-BROMO-5-NITROPYRIDINE 97% 2-溴-5-硝基砒啶 2-溴-5-硝基吡啶; 5-硝基-2-溴吡啶 TIMTEC-BB SBB003519 2-溴-5-硝基吡啶 5-Nitro-2-bromopyridine 5-硝基-2-溴吡啶 2-BROMO-5-NITROPYRIDINE 2-BROMO-5-NITROPYRIDINE
EC Number224-777-2
Beilstein Registry Number120901
PubChem Substance ID78240
Reaxys-RN120901
Chemical Name Translation2-溴-5-硝基吡啶
InChIKeyHUUFTVUBFFESEN-UHFFFAOYSA-N
LabNetwork Molecule IDLN00008169
InChIInChI=1S/C5H3BrN2O2/c6-5-2-1-4(3-7-5)8(9)10/h1-3H
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分类

  • Bases & Related Reagents
  • Nucleotides
  • {SNA} Building Blocks, C5, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Pyridines

相关文献及参考

  • Beilstein:20(5)5,455

安全信息

Warnings IRRITANT, IRRITANT-HARMFUL
Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P312+P330
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H301 Toxic if swallowed 吞食有毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes 6.1 Xn Xn,Xi
UN Number 2811 UN 2811 6.1/PG 3
Packing GroupIII
Storage condition Keep Cold

其他信息

  • Hazard Note:Irritant/Keep Cold
  • 下游产品:2-溴-5-羟基吡啶 --> 5-氨基吡啶-2-磺酸 --> 6-氨甲基-3-氨基吡啶 --> 3-氨基-6-溴吡啶 --> 5-乙酰氨基-2-溴砒啶
  • Sigma Aldrich:4487-59-6(sigmaaldrich)
  • 图谱信息:2-溴-5-硝基吡啶(4487-59-6)核磁图( 1 HNMR)
  • Alfa Aesar:2-溴-5-硝基吡啶,98+% 2-Bromo-5-nitropyridine, 98+%(4487-59-6)
  • 2-溴-5-硝基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xp300049 2-溴-5-硝基吡啶 5g 340元 2011/04/16 B2321 2-溴-5-硝基吡啶 2-Bromo-5-nitropyridine 5G 691元 2011/04/16 B2321 2-溴-5-硝基吡啶 2-Bromo-5-nitropyridine 1G 233元
  • 检测方法:HPLC
  • MOL 文件:4487-59-6.mol
  • TCI Shanghai:2-溴-5-硝基吡啶 2-Bromo-5-nitropyridine,>;98.0%(GC)(4487-59-6)
  • Acros Organics:2-Bromo-5-nitropyridine, 98%(4487-59-6)
  • 上游原料:乙醇 --> 三溴化磷 --> 氧溴化磷 --> 2-羟基-5-硝基吡啶

系列性分类


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