2,4-Dibromo-1-Fluorobenzene 2,4-二溴氟苯

CAS 1435-53-6 MFCD00000283

化学结构图

1435-53-6
SMILES: Fc1ccc(Br)cc1Br

化学属性

Mol. FormulaC6H3Br2F
Mol. Weight253.90
Boiling Point214-216°C at 760 mmHg
Density2.047 g/mL at 25 °C(lit.)
Refractive index1.5810 to 1.5850
Flash Point92°C
TSCANo
Solubility不溶
Appearance 淡黄色液体。沸点216℃,熔点33℃-36℃,闪点101℃,比重2.03。
Melting Point69 °C

别名和识别编码

Chemical Name2,4-Dibromo-1-Fluorobenzene
CAS Number1435-53-6
Alfabeta NameDIBROMOFLUOROBENZENE 134---,
MDL NumberMFCD00000283
EC Number215-860-4
Beilstein Registry Number5(3)569
Synonym 2,4-Dibromo-1-fluorobenzene {LY} 2,4-Dibromo-1-fluorobenzene {} {LY} 2,4-Dibromo-1-fluorobenzene {} {} {LY} 2,4-Dibromo-1-fluorobenzene {} {} {} {LY} 2,4-Dibromo-1-fluorobenzene {} {} {} {} {LY} 2,4-Dibromo-1-fluorobenzene {} {} {} {} {} {LY} 2,4-Dibromo-1-fluorobenzene {} {} {} {} {} {} {LY} 2,4-Dibromo-1-fluorobenzene {} {} {} {} {} {} {} {LY} 2,4-Dibromo-1-fluorobenzene {} {} {} {} {} {} {} {} {LY} 2,4-Dibromo-1-fluorobenzene {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromo-1-fluorobenzene {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromo-1-fluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromo-1-fluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromo-1-fluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromo-1-fluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Dibromo-1-fluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID15034
Reaxys-RN1934822
Chemical Name Translation2,4-二溴氟苯
InChIKeyMKHDDTWHDFVYDQ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00116336
InChIInChI=1S/C6H3Br2F/c7-4-1-2-6(9)5(8)3-4/h1-3H
Canonical SMILESFC1=CC=C(Br)C=C1Br
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分类

  • {SNA} Aryl, Aryl Fluorinated Building Blocks, Building Blocks, C6, Chemical Synthesis, Fluorinated Building Blocks, Halogenated Hydrocarbons, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks
  • {SA} Aryl Fluorinated Building Blocks, Building Blocks, C6, Chemical Synthesis, Fluorinated Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks

产品应用

  • 用于卤氟芳烃的区域选择性锂化研究以及合成新型除虫菊酯。

相关文献及参考

  • Lithiation with lithium 2,2,6,6-tetramethylpiperidide at -75o occurs exclusively at the 6-position, affording 3,5-dibromo-2-fluorobenzoic acid in 82% yield after carboxylation: Tetrahedron Lett., 37, 6551 (1996).

安全信息

Warnings IRRITANT
WGK Germany3
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
Hazard Codes Xi
Signal word Warning
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
GHS Symbol
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 图谱信息:2,4-二溴-1-氟苯(1435-53-6)质谱(MS) 2,4-二溴-1-氟苯(1435-53-6)红外图谱(IR1) 2,4-二溴-1-氟苯(1435-53-6)核磁图( 13 CNMR) 2,4-二溴-1-氟苯(1435-53-6)核磁图( 1 HNMR)
  • 用途一:医药、农药、液晶材料中间体。
  • MOL 文件:1435-53-6.mol
  • TCI Shanghai:1,3-二溴-4-氟苯 1,3-Dibromo-4-fluorobenzene,>;97.0%(GC)(1435-53-6)
  • Acros Organics:2,4-二溴-1-氟苯 2,4-Dibromo-1-fluorobenzene, 98%(1435-53-6)
  • Alfa Aesar:2,4-二溴-1-氟苯,tech.90% 2,4-Dibromo-1-fluorobenzene, tech. 90%(1435-53-6)
  • Sigma Aldrich:1435-53-6(sigmaaldrich)
  • Hazard Note:Irritant
  • 2,4-二溴-1-氟苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D3489 1,3-二溴-4-氟苯 1,3-Dibromo-4-fluorobenzene 5G 390元 2014/06/02 D3489 1,3-二溴-4-氟苯 1,3-Dibromo-4-fluorobenzene 25G 1190元 2010/06/21 380700250 2,4-二溴-1-氟苯 2,4-Dibromo-1-fluorobenzene 98% 25 ML 1581元
  • 2,4-二溴-1-氟苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 D3489 1,3-二溴-4-氟苯 1,3-Dibromo-4-fluorobenzene 5G 644元 2011/04/16 D3489 1,3-二溴-4-氟苯 1,3-Dibromo-4-fluorobenzene 25G 1940元 2010/06/21 380700250 2,4-二溴-1-氟苯 2,4-Dibromo-1-fluorobenzene 98% 25 ML 1581元

系列性分类


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