3-Fluorotoluene 间氟甲苯

CAS 352-70-5 MFCD00000339

化学结构图

352-70-5
SMILES: Cc1cccc(F)c1

化学属性

Mol. FormulaC7H7F
Mol. Weight110
Boiling Point115°C
TSCAYes
Melting Point-87 °C(lit.)
Density0.991 g/mL at 25 °C(lit.)
Refractive index1.4680 to 1.4710
Flash Point9°C(lit.)
Solubility不溶
pH:A

别名和识别编码

Chemical Name3-Fluorotoluene
CAS Number352-70-5
Alfabeta NameFLUOROTOLUENE 3-
MDL NumberMFCD00000339
Synonym m-Fluortoluol M-FLUOROTOLUENE 1-fluoro-3-methyl-benzen meta-Fluorotoluene m-Fluoromethylbenzene 间甲(基)氟苯 3-fluorotoluene 3-Fluortoluol 间氟代甲苯 m-Fluoromethylbenzene 1-Fluoro-3-methylbenzene; m-Fluorotoluene 间氟苯甲烷 3-Fluorotoluene m-Fluorotoluene 一氟甲苯 Toluene, m-fluoro- 3-Fluor-toluol 3-氟甲苯 3-Fluorotoluene99% 1-Methyl-3-fluorobenzene m-fluorotoluene toluene, 3-fluoro- 1-氟-3-甲基苯;3-甲基氟苯;间氟代甲苯;间氟甲苯;间氟苯甲烷;间甲基氟苯 m-Fluro Toluene 3-fluoromethylbenzene 4,4''-DIISO-OCTANYLDIPHENYLAMINE(3-FLUOROTOLUENE) 1-Fluor-3-methylbenzen 4,4-Diiso-Octanyl Diphenylamine 3-fluoro-toluene 3-氟甲苯,98% Toluene,m-fluoro- 间甲基氟苯 m-Fluortoluen 3-甲(基)氟苯 Toluene, m-fluoro- 3-Fluorotoluene 99% 3-Fluorotoluene,98% benzene,1-fluoro-3-methyl- 1-氟-3-甲基苯 1-FLUORO-3-METHYLBENZENE Fluorotoluene2 benzene, 1-fluoro-3-methyl- 间氟代 toluene,3-fluoro- 3-FLUOROTOLUENE 1-fluoro-3-methylbenzene 1-fluoro-3-methyl-benzene 间氟甲苯
Beilstein Registry Number5,290
EC Number206-524-8
PubChem Substance ID87569847
Merck Number14,4180
Reaxys-RN1903631
Chemical Name Translation间氟甲苯
LabNetwork Molecule IDLN00238860
InChIInChI=1S/C7H7F/c1-6-3-2-4-7(8)5-6/h2-5H,1H3
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Aryl, Aryl Fluorinated Building Blocks, Building Blocks, C7, C7-C8, Chemical Synthesis, Fluorinated Building Blocks, Halogenated Hydrocarbons, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks

产品应用

  • 用作医药、农药中间体.

相关文献及参考

  • Short: II/3 Title: Luminescence of Organic Substances Author: Schmillen, A.; Legler, R. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/3 Year: 1967 ISBN: 3-540-03895-7 ISBN: 978-3-540-03895-5 Internet Resource: DOI:10.1007/b86158 RefComment: 270 figs., VIII, 416 pages. Hardcover Abstract: For more than 1000 luminescent organic substances the most important data are represented as wave numbers of absorption and emission bands, decay times and quantum efficiencies. Additional tables contain further information for restricted groups of substances (figures on typical spectra, wave numbers of sharp single bands, influence of surrounding molecules, etc.).
  • Short: II/6 Title: Molecular Constants from Microwave, Molecular Beam, and Electron Spin Resonance Spectroscopy Author: Demaison, J.; Hüttner, W.; Starck, B.; Buck, I.; Tischer, R.; Winnewisser, M. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/6 Year: 1974 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-05977-6 ISBN: 978-3-540-05977-6 Internet Resource: DOI:10.1007/b19951 RefComment: 153 figs., XIII, 688 pages
  • Short: III/35D2 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 2: Aromatic Compounds Author: Mikhova, B. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D2 Year: 2005 Keyword: aromatic compounds; carbon-13; chemical shift; coupling constant; molecular structure ISBN: 978-3-540-20189-2 ISBN: 3-540-20189-0 Internet Resource: DOI:10.1007/b83345 RefComment: VIII, 291 p., Hardcover RefComment: Written for Science and engineers in the fields of physics, chemistry and physical chemistry who inted to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, orie

安全信息

Warnings 危化品目录(2015) IRRITANT, FLAMMABLE
WGK Germany2
GHS Symbol
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupII
UN Number 2388 UN 2388 3/PG 2 UN2388
Risk Statements
  • R11 Highly flammable 非常易燃
  • R37 Irritating to respiratory system 刺激呼吸道
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
Hazard Codes F;Xi F,Xi
Hazard Class3
RTECSXT2578000
Restrict 危险品

其他信息

  • MSDS 信息:3-氟甲苯(352-70-5).msds
  • TCI Shanghai:3-氟甲苯 3-Fluorotoluene,>;99.0%(GC)(352-70-5)
  • 用途二:用于有机合成，经氯化、氧化制得2,4-二氯-5-氟苯甲酸；可用于制取医药、农药中间体
  • Hazard Note:Flammable/Irritant
  • 用途一:用作医药、农药中间体
  • 上游原料:3-甲基苯胺 --> 3-硝基甲苯
  • TSCA:T
  • Alfa Aesar:3-氟甲苯,98% 3-Fluorotoluene, 98%(352-70-5)
  • MOL 文件:352-70-5.mol
  • 外观性质:无色至浅黄色液体。
  • 下游产品:间氟苯甲酰氯
  • 海关编码:29036990
  • 图谱信息:3-氟甲苯(352-70-5)红外图谱(IR1) 3-氟甲苯(352-70-5)质谱(MS) 3-氟甲苯(352-70-5)核磁图( 13 CNMR) 3-氟甲苯(352-70-5)Raman光谱 3-氟甲苯(352-70-5)核磁图( 1 HNMR)
  • 方法一:以间硝基甲苯为原料，经还原制得间氨基甲苯，再经重氮化，热解而得。
  • Reaction of 3-fluorotoluene with excesses of methanol has been investigated on the large-pore catalysts and on the medium-pore HZSM-5.
  • Sigma Aldrich:352-70-5(sigmaaldrich)
  • 3-氟甲苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80065326 3-氟甲苯;间氟甲苯;间氟代叨;间氟苯甲烷 100ml 92元 2011/04/16 F0040 3-氟甲苯 3-Fluorotoluene 500ML 1550元 2011/04/16 F0040 3-氟甲苯 3-Fluorotoluene 25ML 182元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Fluorinated Building Blocks 氟化物砌块
  4. Organic Fluorinated Building Blocks - Fluorinated Building Blocks
  5. Other Fluorinated Organic Building Blocks - Organic Fluorinated Building Blocks
  6. Aryl Fluorinated Building Blocks 芳基氟化物
  7. C7-C8 - Aryl Fluorinated Building Blocks
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  6. C7 - Aryl
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物

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