Trimethylsilyl trifluoroacetate 三氟乙酸三甲硅脂
CAS 400-53-3 MFCD00000413
化学结构图
SMILES: C[Si](C)(C)OC(=O)C(F)(F)F
化学属性
| Mol. Formula | CF3CO2Si(CH3)3 |
|---|---|
| Mol. Weight | 186 |
| Boiling Point | 90°C(lit.) |
| Refractive index | 1.3360 to 1.3400 |
| Density | 1.078 g/mL at 25 °C(lit.) |
| Vapor Density | >;1 (vs air) |
| Flash Point | 13°C(lit.) |
别名和识别编码
| Chemical Name | Trimethylsilyl trifluoroacetate |
|---|---|
| CAS Number | 400-53-3 |
| Alfabeta Name | TRIMETHYLSILYLTRIFLUOROACETATE |
| MDL Number | MFCD00000413 |
| Synonym | 三甲基三氟乙酸 三氟乙酸三甲基硅酯 TRIFLUOROACETIC ACID TRIMETHYLSILYL ESTER Silanol, trimethyl-, trifluoroacetate Trifluoressigsαure-trimethylsilylester 三甲硅烷基三氟乙酸酯 Trimethylsilyltrifluoroacetate96% Trifluoressigsäure-(trimethylsilyl)ester Trimethyl(trifluoroacetoxy)silane trifluoro-acetic acid trimethylsilanyl ester Trifluoressigsäure-trimethylsilylester TRIMETHYLSILYL TRIFLUOROACETATE Trifluoroacetic acid trimethylsilyl ester Trimethylsilyl trifluoroacetate, GC 98% Trimethyl(trifluoroacetato)silane trifluoro-aceticacitrimethylsilylester (trifluoroacetyloxy)trimethylsilane Aceticacid,trifluoro-,trimethylsilylester Acetic acid, trifluoro-, trimethylsilyl ester Trimethylsilyl trifluoroacetate Trimethylsilyl trifluoroacetate 96% (Trifluoroacetoxy)trimethylsilane |
| PubChem Substance ID | 87561626 |
| EC Number | 206-923-7 |
| Beilstein Registry Number | 4(4)4004 |
| Reaxys-RN | 1773314 |
| Chemical Name Translation | 三氟乙酸三甲硅脂 |
| InChIKey | VIYXXANHGYSBLY-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00119492 |
| InChI | InChI=1S/C5H9F3O2Si/c1-11(2,3)10-4(9)5(6,7)8/h1-3H3 |
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分类
- {uni_hamburg} no charge; ester; 1fragment
- Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
相关文献及参考
- 1. M. Demuth et al. Helv. Chim. Acta 64 , 2759, (1981)
- 2. Y. Tanabe et al. J. Org. Chem. 53 , 4582, (1988)
- Beil. 4 ,IV,4004
- Aldrich MSDS 1 , 1802:C / Corp MSDS 1 (2), 3503:D / FT-IR 1 (2), 1112:D / FT-IR 2 (3), 4402:D / FT-NMR 1 (3), 689:B / RegBook 1 (2), 2985:K / Structure Index 1 , 473:C:1 / Vapor Phase 3 , 1660:B
- Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
- Short: III/35F Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Silicon-29 Author: Marsmann, H.C.; Uhlig, F.; Gupta, R.R.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35F Year: 2008 Keyword: NMR; Si-29; chemical shifts; coupling constants; nuclear magnetic resonance; silicon-29 ISBN: 978-3-540-45277-5 (print) ISBN: 978-3-540-45278-2 (elec
安全信息
GHS Symbol
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331+P310
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+P340
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P370+P378
- P403+P235
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R34 Causes burns 会导致灼伤
- R37 Irritating to respiratory system 刺激呼吸道
- R11 Highly flammable 非常易燃
其他信息
- Hazard Note:Flammable
- 蒸气密度:>;1 (vs air)
- MOL 文件:400-53-3.mol
- 三甲基三氟乙酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T2629 三氟乙酸三甲基硅酯 Trimethylsilyl Trifluoroacetate 5G 299元 2014/06/02 T2629 三氟乙酸三甲基硅酯 Trimethylsilyl Trifluoroacetate 25G 855元
- F:10-21
- TSCA:Yes
- Sigma Aldrich:400-53-3(sigmaaldrich)
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