Pentafluoropropionic anhydride 全氟丙酸酐

CAS 356-42-3 MFCD00000429

化学结构图

356-42-3
SMILES: O=C(OC(=O)C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)F

化学属性

TSCAT
Refractive index1.3
Flash PointNone
Melting Point-43 °C
Mol. FormulaC6F10O3
Mol. Weight310.05
Density1.59
Appearance colorless liq.
Stabilitymoisture sensitive
Boiling Point69-70 °C at 735 mmHg

别名和识别编码

Chemical NamePentafluoropropionic Acid Anhydride
Alfabeta NamePENTAFLUOROPROPIONICANHYDRIDE
EC Number206-604-2
Beilstein Registry Number1806446
Synonym Perfluoropropionic anhydride {LY} Perfluoropropionic anhydride pentafluoropropanoic anhydride pentafluoropropionic acid anhydride pentafluoropropionic anhydride perfluoropropionic anhydride {} {LY} Perfluoropropionic anhydride {} {} {LY} Perfluoropropionic anhydride {} {} {} {LY} Perfluoropropionic anhydride {} {} {} {} {} {} {} {} {LY} Perfluoropropionic anhydride {} {} {} {} {} {LY} Perfluoropropionic anhydride {} {} {} {} {} {} {LY} Perfluoropropionic anhydride {} {} {} {} {} {} {} {LY} Perfluoropropionic anhydride {} {} {} {} {} {} {} {} {LY} Perfluoropropionic anhydride {} {} {} {} {} {} {} {} {} {LY} Perfluoropropionic anhydride {} {} {} {} {} {} {} {} {} {} {LY} Perfluoropropionic anhydride {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluoropropionic anhydride {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluoropropionic anhydride {} {} {} {} {} {} {} {} {} {} {} {} {} {PubChem} PFPAH {} {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID67742
Chemical Name Translation全氟丙酸酐
Reaxys-RN1806446
LabNetwork Molecule IDLN00119397
MDL NumberMFCD00000429
CAS Number356-42-3
InChIInChI=1S/C6F10O3/c7-3(8,5(11,12)13)1(17)19-2(18)4(9,10)6(14,15)16
Canonical SMILESFC(C(F)(F)F)(F)C(OC(C(F)(F)C(F)(F)F)=O)=O
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分类

  • {SNA} β-Glucuronidase Drug Analysis Bundle, Analytical and Industrial Enzymes, Biochemicals and Reagents, Building Blocks, Carbonyl Compounds, Carboxylic Acid Anhydrides, Chemical Synthesis, Enzymes, Inhibitors, and Substrates, Organic Building Blocks, PFPA - Pentafluoropropionic anhydride
  • {SNA} β-Glucuronidase Drug Analysis Bundle, Alkyl Fluorinated Building Blocks, Analytical and Industrial Enzymes, Biochemicals and Reagents, Building Blocks,
  • {SNA} Acylation Reagents, Alkyl Fluorinated Building Blocks, Analytical Reagents, Analytical/Chromatography, Building Blocks, Carbonyl Compounds, Carboxylic Acid Anhydrides, Chemical Synthesis,
  • {
  • {SNA} Acylation Reagents,
  • {SNA} Acylation Reagents,

产品应用

  • GC-MS 分析合成肽立体异构体含量的衍生化试剂。还用于 GC-MS 检测膳食添加剂中的去氧肾上腺素。
  • 用于 EC/GC 中制备多种化合物（例如胺和醇）的挥发性五氟丙酰衍生?物。

相关文献及参考

  • Beilstein: 2,IV,741
  • Reagent for the preparation of volatile pentafluoropropionyl derivatives of amines, alcohols, etc. for GC, sensitive to electron-capture detection: J. Chromat., 60, 134 (1971); 69, 157 (1972); 97, 19, 175 (1974); Anal. Chem., 56, 1695 (1984). For monographs on GC reagents, see: D. R. Knapp, Handbook of Analytical Derivatisation Reactions, Wiley, N.Y. (1979); Handbook of Derivatives for Chromatography, 2nd ed., K. Blau and J. M. Halket, Eds., Wiley, Chichester (1993).

安全信息

Warnings MOISTURE SENSITIVE, CORROSIVE
Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R34 Causes burns 会导致灼伤
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P302+P361+P354
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupII
UN Number 1760 3265 UN 3265 8/PG 2 UN3265
Storage condition 2-8°C {LY} 2-8°C Moisture Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Codes 8 C
Hazard Class8

其他信息

  • 图谱信息:全氟丙酸酐(356-42-3)质谱(MS) 全氟丙酸酐(356-42-3)红外图谱(IR1)
  • TCI Shanghai:五氟丙酸酐 Pentafluoropropionic Anhydride,>;95.0%(GC)(356-42-3)
  • 全氟丙酸酐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0566 五氟丙酸酐 Pentafluoropropionic Anhydride 5G 365元 2014/06/02 P0566 五氟丙酸酐 Pentafluoropropionic Anhydride 25G 1100元 2010/06/21 416930050 全氟丙酸酐 Pentafluoropropionic anhydride 98% 5 GR 329元
  • Acros Organics:五氟丙酸酐 Pentafluoropropionic anhydride, 98%(356-42-3)
  • Sigma Aldrich:356-42-3(sigmaaldrich)
  • Hazard Note:Corrosive
  • MOL 文件:356-42-3.mol
  • F:10-21
  • MSDS 信息:Perfluoropropionic anhydride(356-42-3).msds
  • 敏感性:Moisture Sensitive
  • TSCA:T
  • Alfa Aesar:五氟丙酸酐,98% Pentafluoropropionic anhydride, 98%(356-42-3)

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents GC - Derivatization Reagents
  5. Reagents for Acylation - Derivatization Reagents GC
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acid Anhydrides 羧酸酐
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acid Anhydrides 羧酸酐
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carbonates
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. GC Derivatizing Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Analytical Reagents
  1. Organo Fluorine
  2. Fluorine

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