Methylmagnesium Chloride 甲基氯化镁

CAS 676-58-4 MFCD00000468

化学结构图

676-58-4
SMILES: [CH3-].[Cl-].[Mg+2]

化学属性

Density1.01
Autoignition Point609 °F
Solubility不溶于碳氢化合物
TSCAYes
Boiling Point66 ºC
Mol. FormulaCH3ClMg
Mol. Weight74.79
Flash Point1°F (THF)
Appearance liq.
Stabilityair sensitive, moisture sensitive
RedoxReduction

别名和识别编码

Chemical NameMethylmagnesium Chloride
EC Number211-629-7
Beilstein Registry Number3587199
PubChem Substance ID12670
Synonym METHYLMAGNESIUM CHLORIDE 甲基氯化镁, 3M IN THF, PACKAGED UNDER ARGON IN RESEALABLE 甲基氯化镁; 氯代甲基镁 Methylmagnesium chloride, 3M in THF, packaged under Argon in resealable ChemSealTM bottles 甲基氯化镁 溶液 methylmagnesium chloride solution Methylmagnesium Chloride 1.5 M in n-Butyl Ether Methylmagnesium chloride, 22 wt% solution in tetrahydrofuran Methylmagnesiumchloride,3MinTHF 氯化甲基鎂 Methylmagnesium Chloride 2.0 M In Diethyl Ether 氯代甲基镁 甲基氯化镁, 3M IN THF chloromethyl-magnesiu Methylmagnesium Chloride 1.5 M In Butyl Diglyme Methylmagnesium Chloride 2.2 M In Butyl Diglyme METHYLMAGNESIUM CHLORIDE IN TFE METHYLMAGNESIUM CHLORIDE SOLUTION, ~3 M IN THF METHYLMAGNESIUM CHLORIDE, 3 M in TETRAHYDROFURAN METHYLMAGNESIUM CHLORIDE, 2.5M SOLUTIONIN BUTYL DIGLYME METHYLMAGNESIUM CHLORIDE, 3.0M SOLUTION Methylmagnesium Chloride 3.0 M In Tetrahydrofuran METHYLMAGNESIUM CHLORIDE, 3.0M SOLUTION IN TETRAHYDROFURAN 甲基氯化镁 methylmagnesium chloride, 3m in thf, packaged under argon in resealable chemseal Methylmagnesium Chloride 2.0 M In Tetrahydrofuran Magnesium, chloromethyl-
Chemical Name Translation甲基氯化镁
LabNetwork Molecule IDLN00222985
InChIInChI=1S/CH3.ClH.Mg/h1H3;1H;/q-1;;+2/p-1
MDL NumberMFCD00000468
CAS Number676-58-4
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分类

  • {SNA} 25mL Sure/Seal Reagents, Acids & Bases, Alkyl, Bases, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents, Synthetic Reagents
  • {SNA} 25mL Sure/Seal Reagents, Alkyl, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents, Synthetic Reagents
  • {SA} 25mL Sure/Seal Reagents, Alkyl, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents, Synthetic Reagents

产品应用

  • 在有机合成中作为格氏试剂和烷基化试剂

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S29 Do not empty into drains 不要排入下水道；
  • S30 Never add water to this product 切勿将水加入该产品中；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
  • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37 Irritating to respiratory system 刺激呼吸道
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P231+
  • P231+P232
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P370+P378
  • P402+P404
  • P403+P235
  • P422 Store contents under… 存储目录在…之下。
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H351 Suspected of causing cancer 怀疑致癌
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupII
UN Number 3399
Storage condition Flammables + water-Freezer (-20°C)e area 充氩储存 Air & Moisture Sensitive
Hazard Codes 4.3 F,C
Hazard Class4.3
Restrict 危险品

其他信息

  • Acros Organics:甲基氯化镁 Methylmagnesium chloride, 22 wt% solution in tetrahydrofuran, AcroSeal?(676-58-4)
  • 存储注意事项:惰性气体保护;湿度敏感;空气敏感
  • Alfa Aesar:甲基氯化镁,3MinTHF,packagedunderArgoninresealableChemSeal^tbottles Methylmagnesium chloride, 3M in THF, packaged under Argon in resealable ChemSeal™ bottles(676-58-4)
  • Sigma Aldrich:676-58-4(sigmaaldrich)
  • F:1-3-10
  • 甲基氯化镁价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw070053 甲基氯化镁 250ml 400元 2010/06/21 252568000 甲基氯化镁 Methylmagnesium chloride , 22 wt% solution in tetrahydrofuran, AcroSeal® 800 ML 1849元 2010/06/21 252561000 甲基氯化镁 Methylmagnesium chloride , 22 wt% solution in tetrahydrofuran, AcroSeal® 100 ML 480元
  • MOL 文件:676-58-4.mol
  • 敏感性:Air & Moisture Sensitive
  • MSDS 信息:Methylmagnesium chloride (676-58-4).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Organic Acids - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkyl - Grignard Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkyl - Grignard Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkenyl
  1. Functional Group 官能团索引
  2. organomagnesium compound
  1. Grignard
  2. Magnesium

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