Succinonitrile 丁二腈

CAS 110-61-2 MFCD00001949

化学结构图

110-61-2
SMILES: N#CCCC#N

化学属性

Mol. FormulaNCCH2CH2CN
Mol. Weight80
Boiling Point265-267
Density0.985
Melting Point50-54
Flash Point132°(269°F)
TSCAYes
Solubility溶于水、乙醇、氯仿。
Refractive index1.41734
Stability对空气敏感

别名和识别编码

Chemical NameSuccinonitrile
Synonym 1 1,2-DICYANOETHANE 1,2-Dicyanoethane, Butanedinitrile 1,2-Ethanedicarbonitrile 1,2-dicyanoethane 1,2-二氰乙烷 1,2-二氰基乙烷 1,4-Butanedinitrile 1,2-二氰基乙烷 sym-Dicyanoethane BISACETONITRILE Butandinitril Deprelin Dinile Disuxyl ETHYLENE CYANIDE ETHYLENE DICYANIDE Ethane-1,2-dicarbonitrile SUCCINODINITRILE Succinic dinitrile Succinil Succinodinitrile butanedinitrile ethane,1,2-dicyano- ethylene dicyanide malononitrile s-Dicyanoethane 琥珀腈
CAS Number110-61-2
PubChem Substance ID87575722
EC Number203-783-9
Beilstein Registry Number1098380
MDL NumberMFCD00001949
Reaxys-RN1098380
Merck Number8872
Chemical Name Translation丁二腈
Wiswesser Line NotationNC2CN
LabNetwork Molecule IDLN00194097
InChIInChI=1S/C4H4N2/c5-3-1-2-4-6/h1-2H2
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分类

  • Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks

产品应用

  • Succinonitrile dispersed with ionic liquids entrapped in a host polymer was used to constitute the gel polymer electrolytes. It was used as dopant to investigate the ionic conductivity and X-ray absorption spectroscopic results for lithium and copper salt doped succinonitrile.

相关文献及参考

  • Short: II/25C
  • Short: III/20a
  • Merck:14,8872
  • Merck:14,8872 Beilstein:2,615

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes Xn
RTECSWN3850000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P304+P340+P311
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 3276 3439 UN3439
Packing GroupIII
Hazard Class6.1
Storage condition 密封保存 充氩保存 2-8°C
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Bird - pigeon
DOSE/DURATION           : 2200 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Gastrointestinal - nausea or vomiting
REFERENCE :
   AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans
   Institute of Pharmacology, De Pintelaan

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 63110 ug/kg
TOXIC EFFECTS :
   Kidney, Ureter, Bladder - other changes in urine composition
REFERENCE :
   BCPCA6 Biochemical Pharmacology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.1-    1958-  Volume(issue)/page/year:
   27,1135,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 450 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton,
   G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82.
   Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985.
   Volume(issue)/page/year: 2C,4879,1982

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 150 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Gastrointestinal - nausea or vomiting
REFERENCE :
   AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans
   Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium)  V.4-   
   1898-  Volume(issue)/page/year: 3,77,1897

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - hamster
DOSE                    : 365 mg/kg
SEX/DURATION            : female 8 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - Central Nervous System
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   3,41,1983

其他信息

  • 上游原料:氰化钾 --> 乙醇溶液 --> 1,2-二溴乙烷 --> 乙二醇甲醚 --> 氢酸
  • 丁二腈价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 S0109 丁二腈 Succinonitrile 500G 1300元 2011/04/16 S0109 丁二腈 Succinonitrile 25G 167元 2010/06/21 171185000 丁二腈 Succinonitrile 99+% 500 GR 2189元
  • 用途三:主要用作喹吖酮类颜料的原料。此种颜料广泛应用于汽车和镀锌铁皮涂料、彩色印刷颜料和塑料制品的着色剂。也用于生产尼龙-4及医药中间体。还可用作试剂。
  • 外观性质:无色无臭的蜡状物。
  • 类别:有毒物品
  • 用途二:主要用作喹吖酮类颜料的原料。此种颜料广泛应用于汽车和镀锌铁皮涂料、彩色印刷颜料和塑料制品的着色剂。也用于生产尼龙-4及医药中间体。还可用作试剂。
  • 溶于丙酮、氯仿、二氧六环,微溶于水、乙醇、乙醚、二硫化碳和苯。与氢反应还原生成亚丁基二胺。
  • Sigma Aldrich:110-61-2(sigmaaldrich)
  • 海关编码:29269095
  • Alfa Aesar:丁二腈,98% Succinonitrile, 98%(110-61-2)
  • 灭火剂:干粉、泡沫、二氧化碳、砂土
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类、食品添加剂分开存放
  • 职业标准:TWA 5 PPM
  • 用途一:用作从石油馏分中萃取芳香烃的溶剂和镀镍的上光剂,也用于有机合成
  • 可燃性危险特性:明火可燃;高热分解有毒氮氧化物烟雾;遇酸放出氰化物气体;与氧化剂起作用
  • MOL 文件:110-61-2.mol
  • MSDS 信息:丁二腈(110-61-2).msds
  • 急性毒性:口服-大鼠 LD50: 450 毫克/公斤; 口服-小鼠 LD50: 129 毫克/公斤
  • 图谱信息:丁二腈(110-61-2)质谱(MS) 丁二腈(110-61-2)核磁图( 13 CNMR) 丁二腈(110-61-2)Raman光谱 丁二腈(110-61-2)核磁图( 1 HNMR) 丁二腈(110-61-2)红外图谱(IR1)
  • 毒性分级:高毒
  • 丁二腈价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 S0109 丁二腈 Succinonitrile 500G 1230元 2014/06/02 S0109 丁二腈 Succinonitrile 25G 159元 2010/06/21 171185000 丁二腈 Succinonitrile 99+% 500 GR 2189元
  • 方法一:以丙烯腈为原料,在碱性条件下与氰氢酸反应制得。收率95%以上。也可将氰化钠水溶液加热,滴加1,2-二溴乙烷的乙醇溶液,回流反应35h,可生成丁二腈。
  • Acros Organics:丁二腈 Succinonitrile, 99+%(110-61-2)
  • TCI Shanghai:琥珀腈 Succinonitrile,>;99.0%(GC)(110-61-2)

系列性分类


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