N,N-Diethylhydroxylamine N,N-二乙基羟胺

CAS 3710-84-7 MFCD00002126

化学结构图

3710-84-7
SMILES: CCN(O)CC

化学属性

Mol. FormulaC4H11NO
Mol. Weight89.14
Refractive index1.4170 to 1.4220
Boiling Point125-130 °C at 760 mmHg
Density0.867
Melting Point-26--25 °C
Vapor Density3.07 (vs air)
Vapor Pressure4 mmHg ( 0 °C)
Flash Point45°C(lit.)
TSCAYes
Solubility可溶
Appearance 无色透明液体。有氨味。 易溶于水,溶于乙醇、乙醚、氯仿、苯。
Stability易吸潮

别名和识别编码

Chemical NameN,N-Diethylhydroxylamine
Synonym N,N-Diethylhydroxylamine {LY} N,N-Diethylhydroxylamine {} {LY} N,N-Diethylhydroxylamine {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00002126
CAS Number3710-84-7
PubChem Substance ID19463
EC Number223-055-4
Beilstein Registry Number1731349
Reaxys-RN1731349
Chemical Name TranslationN,N-二乙基羟胺
Wiswesser Line NotationQN2&2
LabNetwork Molecule IDLN00222545
Canonical SMILESON(CC)CC
InChIInChI=1S/C4H11NO/c1-3-5(6)4-2/h6H,3-4H2,1-2H3
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Hydroxylamines, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 1、 做为乙烯基单体,用于共轭烯烃的高效阻聚剂。
  • 2、 在液相或气相中对已有端聚种子的情况下,可作为高效端聚抑制剂。
  • 3、 是丁苯乳聚过程的非常优异的终止剂。
  • 4、是不饱和油类及树脂的抗氧化剂。
  • 5、 是光敏树脂、感光乳剂、合成树脂的良好稳定剂。
  • 6、在环境保护中是良好的光化学烟雾抑制剂。
  • 7、是锅炉给水和蒸汽换热设备的缓蚀剂。

相关文献及参考

  • Beilstein: 4,IV,3304
  • Short: EINECS
  • Short: III/35E
  • Reagent for selective reduction of quinones to hydroquinones: Tetrahedron Lett., 1695 (1975).
  • Perfluoroalkenes undergo a novel epoxidation with the reagent at room temperature: Chem. Commun., 763 (1996).

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H312+H332
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSNC3500000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P352
  • P302+P352+P312+P362+P364
  • P303+P361+P353
  • P304+P312
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P311
  • P308+P316
  • P309+P311
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P317
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Packing GroupIII
UN Number 1993
Risk Statements
  • R10 Flammable 易燃
  • R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R38 Irritating to skin 刺激皮肤
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R53 May cause long-term adverse effects in the aquatic environment 对水生环境有长期的有害作用
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture Flammables area Hygroscopic {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {L
Hazard Codes 3
Hazard Class3
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 100 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KODAK* Kodak Company Reports.  (343 State St., Rochester, NY 14650)
   Volume(issue)/page/year: 21MAY1971

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1750 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,217,1969

TYPE OF TEST            : LD80 - Lethal Dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2150 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "T

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KODAK* Kodak Company Reports.  (343 State St., Rochester, NY 14650)
   Volume(issue)/page/year: 21MAY1971

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KODAK* Kodak Company Reports.  (343 State St., Rochester, NY 14650)
   Volume(issue)/page/year: 21MAY1971

TYPE OF TES

TYPE OF TEST            : Dominant lethal test
ROUTE OF EXPOSURE       : Parenteral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 180 mg/kg
REFERENCE :
   CAES** Reports Supported by the Pennwalt Corp. and the Center for Air
   Environment Studies at the Pennsylvania State University
   Volume(issue)/page/year: 492-78,1978

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 200 ppm
REFERENCE :
   CAES** Reports Supported by the Pennwalt Corp. and the Center for Air
   Environment Studies at the Pennsylvania State University
   Volume(issue)/page/year: 492-78,1978

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Human Leukocyte
DOSE/DURATION           : 4000 ppm
REFERENCE :
   ENVRAL Environmental Research.  (Academic Press, Inc., 1 E. First St.,
   Duluth, MN 55802) V.1-    1967-  Volume(issue)/page/year: 20,99,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Parenteral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 18 mg/kg
SEX/DURATION            : male 1 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   ENVRAL Environmental Research.  (Academic Press, Inc., 1 E. First St.,
   Duluth, MN 55802) V.1-    1967-  Volume(issue)/page/year: 20,99,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Parenteral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 180 mg/kg
SEX/DURATION            : male 1 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - pre-implantation mortality (e.g. reduction in
   number of implants per female; total number of implants per corpora lutea)
REFERENCE :
   ENVRAL Environmental Research.  (Academic Press, Inc., 1 E. First St.,
   Duluth, MN 55802) V.1-    1967-  Volume(issue)/page/year: 20,99,1979

其他信息

  • 贮存时间延长,颜色会逐渐变黄,阳光直射、大气贮存,变色速度快。激烈摇动后会暂时混浊,数小时后自然澄清。有胺味,溶于水,溶于乙醇、乙醚、氯仿、苯等有机溶剂。
  • F:3
  • 蒸气密度:3.07 (vs air)
  • Acros Organics:N,N-二乙基羟胺 N,N-Diethylhydroxylamine, 97%(3710-84-7)
  • 二乙基羟胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D1178 N,N-二乙基羟胺(约85%的水溶液,约8.6mol/L) N,N-Diethylhydroxylamine (ca. 85% in Water, ca. 8.6mol/L) 25ML 194元 2014/06/02 D1178 N,N-二乙基羟胺(约85%的水溶液,约8.6mol/L) N,N-Diethylhydroxylamine (ca. 85% in Water, ca. 8.6mol/L) 500ML 736元 2014/06/02 D1339 N,N-二乙基羟胺 N,N-Diethylhydroxylamine 25ML 160元
  • MOL 文件:3710-84-7.mol
  • MSDS 信息:Diethyl hydroxylamine(3710-84-7).msds
  • 用途二:1、 做为乙烯基单体,用于共轭烯烃的高效阻聚剂。2、 在液相或气相中对已有端聚种子的情况下,可作为高效端聚抑制剂。3、 是丁苯乳聚过程的非常优异的终止剂。4、是不饱和油类及树脂的抗氧化剂。5、 是光敏树脂、感光乳剂、合成树脂的良好稳定剂。6、在环境保护中是良好的光化学烟雾抑制剂。7、是锅炉给水和蒸汽换热设备的缓蚀剂。
  • 敏感性:Hygroscopic
  • 蒸气压:4 mm Hg ( 0 °C)
  • Sigma Aldrich:3710-84-7(sigmaaldrich)
  • 上游原料:三乙胺 --> 过氧化氢 --> 焦磷酸钠
  • Alfa Aesar:N,N-二乙基羟胺,97% N,N-Diethylhydroxylamine, 97%(3710-84-7)
  • 海关编码:29280090
  • 用途一:用作乙烯基单体及共轭烯烃的高效阻聚剂,是丁苯乳聚过程的终止剂,是不饱和油类等的抗氧化剂
  • 图谱信息:二乙基羟胺(3710-84-7)核磁图( 13 CNMR) 二乙基羟胺(3710-84-7)质谱(MS) 二乙基羟胺(3710-84-7)核磁图( 1 HNMR) 二乙基羟胺(3710-84-7)Raman光谱 二乙基羟胺(3710-84-7)红外图谱(IR1)
  • TCI Shanghai:N,N-二乙基羟胺(约85%的水溶液,约8.6mol/L) N,N-Diethylhydroxylamine (ca. 85% in Water, ca. 8.6mol/L)(3710-84-7)

系列性分类


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