Bisphenol F 4,4-二羟基二苯甲烷

CAS 620-92-8 MFCD00002385

化学结构图

620-92-8
SMILES: Oc1ccc(Cc2ccc(O)cc2)cc1

化学属性

Mol. FormulaC13H12O2
Mol. Weight200.24
Melting Point162-164°C
TSCAYes
Appearance 白色叶状结晶。熔点160℃，紫外线可引起变色。
Boiling Point297.96 °C at 760 mmHg

别名和识别编码

Chemical NameBisphenol F
CAS Number620-92-8
Synonym 4,4'-Dihydroxydiphenylmethane {LY} 4,4'-Dihydroxydiphenylmethane {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {} {} {} {} {} {}
Beilstein Registry Number6,995
PubChem Substance ID12111
EC Number210-658-2
MDL NumberMFCD00002385
Reaxys-RN2049425
Chemical Name Translation4,4-二羟基二苯甲烷
Wiswesser Line NotationQR D1R DQ
LabNetwork Molecule IDLN00224367
InChIInChI=1S/C13H12O2/c14-12-5-1-10(2-6-12)9-11-3-7-13(15)8-4-11/h1-8,14-15H,9H2
Canonical SMILESOC1=CC=C(CC2=CC=C(O)C=C2)C=C1
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分类

  • Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Polyols
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Polyols

产品应用

  • Bisphenol F is a bisphenol derivative with antioxidant activities. Bisphenol F has been reported to exhibit estrogen agonistic properties.

相关文献及参考

  • Higashihara, N. et al.: Arch. Toxicol., 81, 825 (2007); Kanai, H. et al.: Int. J. Cancer, 93, 20 (2001); Pospisil, J. et al.: Kinet. Mech. Polyreacti.Int. Symp. Macromol. Chem. Prepr.,5, 383 (1969);
  • Beil. 6 ,IV,6664
  • FT-IR 1 (1), 1118:D / FT-IR 2 (2), 1906:B / FT-NMR 1 (2), 322:B / IR-Spectra (3), 671:F / IR-Spectra (2), 599:E / NMR-Reference 2 (1), 916:A / RegBook 1 (1), 1309:L / Sax 6 , 490 / Structure Index 1 , 200:C:4

安全信息

Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P332+P313
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
WGK Germany2
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H303 May be harmfully swallowed 吞食可能有害
Hazard Codes Xi
RTECSSL9625000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4950 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

其他信息

  • 下游产品:草酸亚铁二水合物
  • 方法一:由苯酚与甲醛在酸性介质中反应而得。以强无机酸（如硫酸、盐酸）为催化剂的生产工艺有许多缺点，如设备易腐蚀，杂质多（如副反应生成氯甲基醚和氯甲基酚），分离困难。美国孟山都公司采用磷酸作催化剂，产品颜色好，产量高。最大优点是苯酚在磷酸中的溶解度低，有利于产品分离和催化剂的循环使用。甲醛的转化率为90%，4,4'-、2,4-2,2'-异构物之比为55：37：8。有机相经中和、过滤、蒸馏，得到产品双酚F 。
  • 图谱信息:4,4'-二羟基二苯甲烷(620-92-8)红外图谱(IR1) 4,4'-二羟基二苯甲烷(620-92-8)红外图谱(IR2) 4,4'-二羟基二苯甲烷(620-92-8)核磁图( 1 HNMR) 4,4'-二羟基二苯甲烷(620-92-8)核磁图( 13 CNMR) 4,4'-二羟基二苯甲烷(620-92-8)质谱(MS)
  • 储运特性:库房通风低温干燥
  • 毒性分级:中毒
  • 4,4'-二羟基二苯甲烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0819 4,4'-二羟基二苯基甲烷 4,4'-Dihydroxydiphenylmethane 5G 803元 2014/06/02 B0819 4,4'-二羟基二苯基甲烷 4,4'-Dihydroxydiphenylmethane 25G 2330元 2010/05/25 A11417 4,4'-二羟基二苯基甲烷, 97% 4,4'-Dihydroxydiphenylmethane, 98% 5g 1134元
  • 急性毒性:口服-大鼠 LD50: 4950 毫克/公斤
  • MOL 文件:620-92-8.mol
  • 灭火剂:干粉,泡沫,砂土,二氧化碳, 雾状水
  • 可燃性危险特性:可燃; 受热分解刺激烟雾
  • 用途一:适用加工软片、电子分色软片、激光照排软片、明室拷贝软片
  • 4,4'-二羟基二苯甲烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 B0819 4,4'-二羟基二苯基甲烷 4,4'-Dihydroxydiphenylmethane 5G 663元 2011/04/16 B0819 4,4'-二羟基二苯基甲烷 4,4'-Dihydroxydiphenylmethane 25G 1910元 2010/05/25 A11417 4,4'-二羟基二苯基甲烷, 97% 4,4'-Dihydroxydiphenylmethane, 98% 5g 1134元
  • Alfa Aesar:4,4'-二羟基二苯基甲烷,97% 4,4'-Dihydroxydiphenylmethane, 98%(620-92-8)
  • 用途二:（1）环氧树脂 以双酚F为原料的环氧树脂与以双酚A为原料的环氧树脂相比，有粘度低、作业性优良等特点，可应用于无溶剂型至超高固体份涂料，也可应用于衬里材料、地板材料、注型材料、浸渍材料、层压材料等领域。（2）聚碳酸酯树脂 由双酚F与光气制成的聚碳酸酯树脂易溶于二氯甲烷等低沸点有机溶剂，软化点低，加工成型性好，即使在受到非常大的破坏时也用伸缩性，适于制造成型材料或薄膜等。（3）聚酯树脂 双酚F与环氧烷加成制得的联苯型二醇，与二元酸等反应所制得的树脂，粘度低，机械性能和化学性能均优异，特别适宜于制造耐腐蚀材料。双酚F还可用于生产油溶性酚醛树脂、阻燃剂、抗氧剂和表面活性剂等。
  • TCI Shanghai:4,4'-二羟基二苯基甲烷 4,4'-Dihydroxydiphenylmethane,>;99.0%(GC)(620-92-8)
  • 上游原料:甲酚 --> 甲基醚
  • Sigma Aldrich:620-92-8(sigmaaldrich)
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Polyols - Oxygen Compounds
  1. Materials Science 材料科学
  2. Pressure & Heat Sensitive Recording Materials

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