Acenaphthylene 1,8-亚乙基萘

CAS 208-96-8 MFCD00003806

化学结构图

208-96-8
SMILES: C1=CC=C2C=CC=C3C=CC1=C32

化学属性

Mol. FormulaC12H8
Mol. Weight152
Density0.899 g/mL at 25 °C(lit.)
Boiling Point280
Melting Point78-93
Flash Point122°(252°F)
TSCAYes
Refractive index1.6015
Solubility不溶于水，微溶乙醇，能溶于热醚、热苯、甲苯、冰醋酸、氯仿和石油醚。
Appearance 黄色棱柱状或板状结晶。熔点92-93℃，沸点265-275℃（部分分解），156-160℃（3.73千帕），相对密度0.8988（16/2℃），易溶于乙醇、甲醇、丙醇、乙醚、石油醚、苯，不溶于水。能在强酸中聚合。

别名和识别编码

Chemical NameAcenaphthylene
CAS Number208-96-8
Synonym acenaphthylene solution ACENAPHTHYLENE acenaphthylene,industrial Acenaphthylene, tech., 80% Acenaphthalene 萘嵌戊烯 Acenaphthyene 苊(工业) 乙烯合萘 二氢苊 cyclopenta(de)naphthalene acenaphthene 1,8-亚乙基萘 ACENAPHTHYLENE, 100MG, NEAT ACENAPHTHYLENE 95% 苊烯/萘嵌戊烯 萘并乙烯 ACENAPHTHALENE Cyclopenta(de)naphthalene Cyclopenta[de]naphthalene acenaphthylene Acenaphthylene, 80%,tech ACENAPHTHYLENE, 1X1ML, MEOH, 5000UG/ML 苊烯 苊烯; 1,8-亚乙基萘 萘并乙烯,萘嵌戊烯, 1,8-亚乙基萘 C12H8 (acenaphthylene) NSC 59821 ACENAPHTHYLENE 80+% 苊烯 溶液 ACENAPHTHYLENE, 99+% 苊烯, TECH
PubChem Substance ID87561711
EC Number205-917-1
Beilstein Registry Number774092
MDL NumberMFCD00003806
Reaxys-RN774092
Chemical Name Translation1,8-亚乙基萘
Wiswesser Line NotationL566 1A LJ
LabNetwork Molecule IDLN00189420
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分类

  • {SNA} All PAH Standards
  • A, A-B, AA to AL, All PAH Standards, Alpha Sort, Alphabetic,
  • {SNA} Arenes, Building Blocks, Chemical Synthesis, Organic Building Blocks
  • {SNA} A, A-B, AA to AL, All PAH Standards, Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Aromatics, Chemical Class, Chromatography, Environmental Standards, Hydrocarbons, Neats and Solutions, PAHs, Volatiles/ Semivolatiles, solutions
  • {SNA} Alphabetical Index of Anal

产品应用

  • 用作有机合成原料。如制硝基苊烯、萘二甲酸酐、苊醌等。合成染料如士林猩红、荧光增白剂、农药、防老剂及植物生长激素。

相关文献及参考

  • Hansen, B., et al.: Environ. Toxicol. Chem., 18, 772 (1999),
  • Czub, G., et al.: Environ. Sci. Technol., 38, 2406 (2004),
  • Beilstein:5(2)530
  • Short: II/27C
  • Short: II/27B

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xn,N,F,T Xn F,Xn,N Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter dust mask type N95 (US), Eyeshields, Gloves
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R20 Harmful by inhalation 吸入有害
  • R22 Harmful if swallowed 吞咽有害
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R38 Irritating to skin 刺激皮肤
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
  • R50/53
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
RTECSAB1254000
UN Number 3077 UN 1145 3/PG 2
Storage condition APPROX 4°C 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1760 mg/kg
TOXIC EFFECTS :
   Autonomic Nervous System - other (direct) parasympathomimetic
   Lungs, Thorax, or Respiration - respiratory depression
   Blood - hemorrhage
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 9(9),53,1965

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 14(6),46,1970

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 15 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 371,123,1996

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mmol/L/2H
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   39,4152,1979

其他信息

  • 用途二:用作有机合成原料。如制硝基苊烯、萘二甲酸酐、苊醌等。合成染料如士林猩红、荧光增白剂、农药、防老剂及植物生长激素。
  • 不溶于水，能溶于乙醇、甲醇、石油醚、丙醇；乙醚、苯、氯仿。易燃。能在强酸中聚合。即发生光化学二聚得七核环状物。一般条件下与马来酸酐反应很慢，在辐照下则给出加成物。高温煤焦油中含1.2％～1.8％。
  • 可燃性危险特性:可燃;加热分解释放刺激烟雾
  • Acros Organics:Acenaphthylene, 99+%(208-96
  • 曾误称为苊。白色或略带黄色斜方针状晶体。不溶于水，能溶于乙醇、甲醇、石油醚、丙醇；乙醚、苯、氯仿。易燃。能在强酸中聚合。即发生光化学二聚得七核环状物。一般条件下与马来酸酐反应很慢，在辐照下则给出加成物。高温煤焦油中含1.2％～1.8％。
  • {Chemic
  • 毒性分级:中毒
  • 方法一:由苊经气相催化脱氢而得：将工业苊投入熔融釜，用间接蒸汽加热使全部熔化。用压缩空气将液苊压入螺旋气化混合器，用蒸汽加热气化，直接蒸汽与苊蒸气混合进入过热炉，过热至450±20℃，进入脱氢反应器，经催化脱氢反应，然后冷凝、干燥而得粗苊烯。用乙醇溶解粗苊烯，除去炭化物和机械杂质，冷却、结晶、干燥而得成品。所用催化剂为氧化锌（85%）、氧化钙（5%）、硫酸钾（5%）、铬酸钾（3%）、氢氧化钾（2%）。
  • 用途一:苊烯是有机合成原料，用于电绝缘材料和离子交换树脂、染料等。市售商品纯度为95%时，熔点88-91℃，熔点下的相对密度0.899。
  • Sigma Aldrich:208-96-8(sigmaaldrich)
  • 图谱信息:1,8-亚乙基萘
  • MOL 文件:208-96-8.mol
  • 图谱信息:1,8-亚乙基萘 (208-96-8)核磁图( 1 HNMR) 1,8-亚乙基萘 (208-96-8)质谱(MS) 1,8-亚乙基萘 (208-96-8)红外图谱(IR1) 1,8-亚乙基萘 (208-96-8)核磁图( 13 CNMR) 1,8-
  • 下游产品:4-氨基-1,8-萘二胺 --> 1-乙酰氧基二氢苊
  • Alfa Aesar:苊烯,tech.80% Acenap
  • 灭火剂:干粉、泡沫、砂土和水
  • {C
  • 急性毒性:腹腔-大鼠LD50:1700毫克/公斤
  • 储运特性:库房通风低温干燥
  • TCI Shanghai:苊烯 Acenaphthylen

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Arenes 芳烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Hydrocarbons - Chemical Class
  5. Neats - Hydrocarbons
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Volatiles/ Semivolatiles - Environmental Standards
  6. PAHs - Volatiles/ Semivolatiles
  7. All PAH Standards - PAHs
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. A - Alphabetic
  5. AA to AL - A
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Volatiles/ Semivolatiles - Environmental Standards
  6. Alpha Sort - Volatiles/ Semivolatiles
  7. A-B - Alpha Sort
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Herbicides for Use in Environmental Chromatography Standards
  7. Benzofuranyl alkylsulfonate - Herbicides

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