Cycloheptanone环庚酮 环庚酮

CAS N/A MFCD00004159

化学结构图

N/A
SMILES:

化学属性

Mol. FormulaC7H12O
Mol. Weight112.17
Refractive index1.4600 to 1.4630
Boiling Point180°C
Density0.951
Flash Point56°C(lit.)
TSCAYes
Melting Point-21°
Solubility不溶

别名和识别编码

Chemical NameCycloheptanone环庚酮
CAS Number502-42-1
PubChem Substance ID87565587
EC Number207-937-6
Beilstein Registry Number7,13
MDL NumberMFCD00004159
Reaxys-RN969823
Merck Number2722
Synonym 软木酮 Ketoheptamethylene Suberone
Chemical Name Translation环庚酮
Wiswesser Line NotationL7VTJ
LabNetwork Molecule IDLN00120081
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分类

  • Building Blocks, C7 to C8, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; alicycle; large ring; 7ring; ketone; 1fragment
  • {SNA} Building Blocks, C7 to C8, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks

产品应用

  • 用作有机合成中间体,也用于化学研究。

相关文献及参考

  • Short: II/25D
  • Merck: 14,2722
  • Short: II/14a
  • Reaction with tributyl[(methoxymethoxy)methyl]stannane (see Tri-n-butyl­tin hydride, A13298) is the equivalent of attack by hydroxymethyl anion: Org. Synth. Coll., 9, 493 (1998):
  • Merck: 14,2722 Beilstein:7,13

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H318 Causes serious eye damage 严重伤害眼睛
Hazard Codes
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P305+P351+P338
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US)
RTECSGU3325000
UN Number 1224
Risk Statements
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Packing GroupIII
Hazard Class3
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 930 mg/kg
TOXIC EFFECTS :
   Autonomic Nervous System - other (direct) parasympathomimetic
   Behavioral - coma
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   AEXPBL Archiv fuer Experimentelle Pathologie und Pharmakologie.  (Leipzig,
   Ger. Dem. Rep.)  V.1-109, 1873-1925.  For publisher information, see NSAPCC.
    Volume(issue)/page/year: 50,199,1903

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 750 mg/kg
TOXIC EFFECTS :
   Behavioral - excitement
   Behavioral - coma
   Cardiac - arrhythmias (including changes in conduction)
REFERENCE :
   COREAF Comptes Rendus Hebdomadaires des Seances, Academie des Sciences.
   (Paris, France)  V.1-261, 1835-1965.  For publisher information, see CRASEV.
    Volume(issue)/page/year: 254,2245,1962

其他信息

  • 有薄荷气味,不溶于水,溶于乙醇等多数有机溶剂

系列性分类