Heptafluorobutyric Acid 七氟丁酸

CAS 375-22-4 MFCD00004171

化学结构图

375-22-4
SMILES: O=C(O)C(F)(F)C(F)(F)C(F)(F)F

化学属性

Mol. FormulaC4HF7O2
Mol. Weight214
Boiling Point120
TSCAT
Refractive indexn20/D 1.3(lit.)
Density1.645
Flash PointNone
Melting Point-18°
Vapor Density7 (vs air)
Vapor Pressure~10 mmHg ( 25 °C)
SolubilitySoluble in water, toluene, ether, ethanol (0.1 ml/ml), and benzene.
Stability对光敏感

别名和识别编码

Chemical NameHeptafluorobutyric Acid
CAS Number375-22-4
Alfabeta NameHEPTAFLUOROBUTYRICACID
MDL NumberMFCD00004171
Synonym 2,2,3,3,4,4,4-heptafluoro-butyricacid Edman 试剂3 FC 23 FC-23 Fluorad FC 23 HFBA Heptafluorbuttersαure Heptafluorobutyric acid Hydrogenperfluorbutyrat Kyselina heptafluormaselna PERFLUOROBUTBUTYRIC ACID PERFLUOROBUTYRIC ACID Perfluorobutanoic acid Perfluorobutyric Acid Perfluorobutyric acid Perfluorobutyric acid; HFBA butanoicacid,heptafluoro- heptafluoro-butyric acid heptafluorobutanoic acid perfluoro butanoic acid 七氟丁酸 七氟丁酸 溶液 全氟丁酸 全氟丁酸,过氟丁酸 全氟丁酸/七氟丁酸 庚氟丁酸
PubChem Substance ID87575573
EC Number206-786-3
Beilstein Registry Number1426882
Reaxys-RN1426882
Chemical Name Translation七氟丁酸
Wiswesser Line NotationQVXFFXFFXFFF
InChIKeyYPJUNDFVDDCYIH-UHFFFAOYSA-N
LabNetwork Molecule IDLN00117777
InChIInChI=1S/C4HF7O2/c5-2(6,1(12)13)3(7,8)4(9,10)11/h(H,12,13)
信息真实价格透明    资金保障    专业采购外包团队在线服务   
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分类

  • Amino Acid Analysis, Analytical Reagents, Analytical/Chromatography, Application Specific Reagents, Biochemicals and Reagents, Hydrolysis Products for Amino Acid Analysis, Peptide Analysis and Characterization, Peptides, Products for Amino Acid Hydrolysis, Reagents for Amino Acid Analysis
  • {SNA} Alkyl Fluorinated Building Blocks, Building Blocks, C1 to C5, Carbonyl Compounds, Carboxylic Acids, Chemical Synthesi
  • {SNA} Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, Chromatography Reagents & Solvents, E-H, Puriss p.a., Ion Chromatography Reagents, Puriss p.a., Salts and Additives for IC

产品应用

  • 离子对试剂，蛋白质测序。

相关文献及参考

  • Cecchi, T., et al.: J. Chromatogr., 1216, 1789 (2009),
  • Short: II/27B
  • Anion-pairing agent in reverse-phase HPLC for purification of peptides and proteins: Biochemistry, 20, 4530 (1981).
  • Aso, K., et al.: Biosci. Biotech. Biochem., 56, 755 (1992),
  • Satake, I., et al.: Biopolymers, 15, 2263 (1976),
  • Beilstein: 2,IV,810

安全信息

Warnings STENCH, CORROSIVE 危化品目录(2015)
GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8 C
RTECSET4025000
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 3265 UN 3265 8/PG 2 UN3265
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R35 Causes severe burns 会导致严重灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Storage condition Light Sensitive 2-8°C 储存温度2-8℃,充氩保存
Packing GroupI
Hazard Class8 
TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >10 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 2,56,1950

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 68 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 2,56,1950

Restrict 危险品

其他信息

  • 外观性质:无色油状液体，具有丁酸的刺鼻味，易吸湿。
  • 蒸气密度:7 (vs air)
  • Sigma Aldrich:375-22-4(sigmaaldrich)
  • MOL 文件:375-22-4.mol
  • Alfa Aesar:七氟丁酸,99% Heptafluorobutyric acid, 99%(375-22-4)
  • 灭火剂:雾状水、泡沫、砂土、二氧化碳
  • 蒸气压:~10 mm Hg ( 25 °C)
  • 储运特性:库房通风低温干燥; 与食品、氧化剂、含水物品分开储运
  • Acros Organics:全氟丁酸/七氟丁酸 Heptafluorobutyric acid, for protein sequence analysis, 99%(375-22-4)
  • 七氟丁酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80066680 七氟丁酸;过氟丁酸;全氟丁酸 25ml 995元 2011/04/16 H0024 七氟丁酸 Heptafluorobutyric Acid 25G 620元 2011/04/16 A5713 七氟丁酸(约0.5mol/L的水溶液)[用于液相色谱-质谱的离子对试剂] Heptafluorobutyric Acid (ca. 0.5mol/L in Water) [Ion-Pair Reagent for LC-MS] 10ML 322元
  • TCI Shanghai:七氟丁酸[螯合试剂] Heptafluorobutyric Acid [Sequenation Reagent],>;99.0%(T)(375-22-4)
  • 下游产品:N-七氟丁酰基咪唑 --> 七氟丁酸酐
  • 图谱信息:七氟丁酸(375-22-4)质谱(MS)
  • 类别:腐蚀物品
  • TSCA:T
  • F:3-8-10
  • Hazard Note:Corrosive
  • Heptafluorobutyric acid is an anion-pairing agent for reverse phase HPLC purification of proteins and peptides.
  • 可燃性危险特性:遇热分解有毒氟化物气体; 遇水蒸气放出有毒氟化物烟雾
  • 用途二:离子对试剂，蛋白质测序。
  • 毒性分级:高毒
  • MSDS 信息:七氟丁酸(375-22-4).msds
  • 用途一:氨基糖甙类抗生素的检测衍生化试剂.
  • 急性毒性:腹腔-小鼠 LD50: 153 毫克/ 公斤

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Organic Acids - Synthetic Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. - Analytical Reagents for General Use
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acids - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acids - Carbonyl Compounds
  6. C1 to C5 - Carboxylic Acids
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Chromatography Reagents & Solvents - Analytical Reagents
  4. Ion Chromatography Reagents - Chromatography Reagents & Solvents
  5. Salts and Additives for IC - Ion Chromatography Reagents
  1. Life Science 生命科学
  2. Proteomics 蛋白质组学
  3. Protein Structural Analysis - Proteomics
  4. Protein Sequencing - Protein Structural Analysis
  5. Reagents for Protein Sequencing - Protein Sequencing
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Chromatography Reagents & Solvents - Analytical Reagents
  4. Ion Pair Reagents - Chromatography Reagents & Solvents
  5. Acidic Ion Pair Reagents (Anionic) - Ion Pair Reagents
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Peptides - Biochemicals and Reagents
  4. Peptide Analysis and Characterization - Peptides
  5. Amino Acid Analysis - Peptide Analysis and Characterization
  6. Hydrolysis Products for Amino Acid Analysis - Amino Acid Analysis
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Peptides - Biochemicals and Reagents
  4. Peptide Analysis and Characterization - Peptides
  5. Amino Acid Analysis - Peptide Analysis and Characterization
  6. Hydrolysis Products for Amino Acid Analysis - Amino Acid Analysis
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acids
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Fluorous Chemistry 氟化学
  1. Analytical & Chromatography 分析化学与色谱
  2. GC Derivatizing Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Ion-Pair Reagents for HPLC
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Proteomics
  4. Protein Structural Analysis
  5. Protein Sequencing
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Peptides
  4. Peptide Analysis and Characterization
  5. Amino Acid Analysis
  6. Detection Products for Amino Acid Analysis

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