N,N-Dimethylglycine N,N-二甲基甘氨酸
CAS 1118-68-9 MFCD00004283
化学结构图
SMILES: CN(C)CC(=O)O
化学属性
| Mol. Formula | C4H9NO2 |
|---|---|
| Mol. Weight | 103 |
| Melting Point | 178-182 |
| TSCA | Yes |
| Density | 1.422 |
| Solubility | 可溶 |
别名和识别编码
| Chemical Name | N,N-Dimethylglycine |
|---|---|
| CAS Number | 1118-68-9 |
| Alfabeta Name | DIMETHYLAMINOACETICACID () |
| MDL Number | MFCD00004283 |
| Synonym | (DIMETHYLAMINO)ACETIC ACID (Dimethylamino)acetic acid N,N-DIMETHYLGLYCINE FREE BASE N,N-dimethyl-glycine N,N-二甲基甘氨酸, 98+% N-Methylsarcosine dimethylaminoacetic acid |
| Beilstein Registry Number | 1700261 |
| PubChem Substance ID | 87559938 |
| EC Number | 214-267-8 |
| Reaxys-RN | 1700261 |
| Merck Number | 3244 |
| Chemical Name Translation | N,N-二甲基甘氨酸 |
| LabNetwork Molecule ID | LN00007877 |
| InChI | InChI=1S/C4H9NO2/c1-5(2)3-4(6)7/h3H2,1-2H3,(H,6,7) |
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分类
- {SNA} Amino Acid, Amino Acid Library, Cell Biology, Chemical Biology, Chemical Synthesis, Metabolic Libraries, Metabolic Pathways, Metabolites and Cofactors on the Metabolic Pathways Chart, Metabolomics, N-Methyl Amino Acids, Peptide Chemistry, Unnatural Amino Acid Derivatives
- {SNA} Amino Acid, Chemical Biology, Chemical Synthesis, N-Methyl Amino Acids, Peptide Chemistry, Proteins and Amino Acids for Protein Stabilization, Reagents for Protein Stabilization, Unnatural Amino Acids & Derivatives, 代谢组学, 代谢通路, 代谢通路图中的代谢产物和辅酶分子, 生化试剂,
- {SNA} Amino
相关文献及参考
- Short: III/35E
- Additive which promotes the Heck coupling reaction of unactivated aryl chlorides with alkenes, catalyzed by Pd(II) in the presence of Tetraphenylphosphonium chloride, A10575: Angew. Chem. Int. Ed., 37, 481 (1998). The combination with Bis(benzonitrile)dichloropalladum constitutes a highly active phosphine-free catalyst system for Heck reactions of aryl bromides: Tetrahedron Lett., 39, 8449 (1998); see also: Tetrahedron Lett., 39, 8449 (1998). Promotes the copper(I)-catalyzed Ullmann-type coupling of aryl bromides and iodides with amines: Org. Lett., 5, 2453 (2003), and phenols: Org. Lett., 5, 3799 (2003), to give substituted anilines and diaryl ethers, respectively. Aryl iodides can also be coupled with aliphatic alcohols to give aryl alkyl ethers: Synlett, 243 (2007). In combinatiion with CuI, vinyl halides with phenols give aryl vinyl ethers: Synlett, 1767 (2005).
安全信息
GHS Symbol
- H302 Harmful if swallowed 吞食有害
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P301+P312+P330
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- R22 Harmful if swallowed 吞咽有害
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : >650 mg/kg TOXIC EFFECTS : Behavioral - ataxia Gastrointestinal - hypermotility, diarrhea Blood - changes in spleen REFERENCE : ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,199,1992
其他信息
- MOL 文件:1118-68-9.mol
- TCI Shanghai:N,N-二甲基甘氨酸 N,N-Dimethylglycine,>;98.0%(T)(1118-68-9)
- Acros Organics:N,N-二甲基甘氨酸 N,N-Dimethylglycine, 97%(1118-68-9)
- 用途一:用作医药中间体
- F:3
- 检测方法:T,NMR
- Sigma Aldrich:1118-68-9(sigmaaldrich)
- Alfa Aesar:N,N-二甲基甘氨酸,98+% N,N-Dimethylglycine, 98+%(1118-68-9)
- N,N-二甲基甘氨酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D3585 N,N-二甲基甘氨酸 N,N-Dimethylglycine 5G 570元 2014/06/02 D3585 N,N-二甲基甘氨酸 N,N-Dimethylglycine 25G 1740元 2010/06/21 345200050 N,N-二甲基甘氨酸 N,N-Dimethylglycine 97% 5 GR 742元
- 敏感性:Hygroscopic
- 图谱信息:N,N-二甲基甘氨酸(1118-68-9)红外图谱(IR1) N,N-二甲基甘氨酸(1118-68-9)核磁图( 13 CNMR) N,N-二甲基甘氨酸(1118-68-9)核磁图( 1 HNMR) N,N-二甲基甘氨酸(1118-68-9)质谱(MS) N,N-二甲基甘氨酸(1118-68-9)红外图谱(IR2)
- 下游产品:1-(咪唑-1-基)苯酚
- MSDS 信息:N,N-Dimethylglycine(1118-68-9).msds
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