2,4,6-Tri(pyridin-2-yl)-1,3,5-triazine 2,4,6-三(2-吡啶基)三嗪(TPTZ)

CAS 3682-35-7 MFCD00006045

化学结构图

3682-35-7
SMILES: C1=CC=CN=C1C1N=C(N=C(N=1)C1C=CC=CN=1)C1C=CC=CN=1

化学属性

Mol. FormulaC18H12N6
Mol. Weight312
Density1.276
Melting Point248-252
TSCAYes

别名和识别编码

Chemical Name2,4,6-Tri(pyridin-2-yl)-1,3,5-triazine
CAS Number3682-35-7
EC Number222-965-9
Beilstein Registry Number282581
MDL NumberMFCD00006045
Synonym 1,3,5-Triazine, 2,4,6-tri-2-pyridinyl- 2,4,6-三(2-吡啶)-1,3,5-三嗪 2,4,6-Tripyridyl-S-triazine 2,4,6-三(2-吡啶)-1,3,5-三嗪 TPTZ TPTZ,三吡啶三嗪 2,4,6-Tri(2-pyridyl)-s-triazine 2,4,6-Tri-2-pyridinyl-1,3,5-triazine TPTZ TPTZ (iron reagent) 2,4,6-三吡啶基三嗪 2,4,6-三(2-吡啶基)三嗪
Merck Number9750
PubChem Substance ID87576454
Chemical Name Translation2,4,6-三(2-吡啶基)三嗪(TPTZ)
Reaxys-RN282581
LabNetwork Molecule IDLN00194379
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分类

  • {SNA} Spectroscopy, UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy, 分析/色谱, 分析试剂
  • {SNA} Analytical Reagents, Analytical/Chromatography, Spectroscopy, UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy

产品应用

  • 光度法测铁Fe(II) 和总铁。
  • Fe2+复合物的颜色在pH 3.4-5.8(1:2,logK=20.4)时呈红紫色,TPTZ可被用作Fe的金属指示剂。但是TPTZ与Co、Cu、Ni这些金属离子也会显色,因此不能用作Fe的选择性比色试剂,如果存在大量的Co、Cu、Ni离子,会妨碍检测。除了血清和锅炉水里面的Fe离子以外,也有报道可以定量玻璃、煤炭、高纯度的各种金属、酒、维生素E等样品中的Fe。

相关文献及参考

  • Reagent for determination of Fe: Anal. Chem., 31, 1862 (1959).
  • Merck: 14,9750 Beilstein: 26,IV,4192
  • Merck: 14,9750

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
RTECSXZ2050000
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes Xi
Storage condition 储存温度: 2-8°C
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : >316 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EESADV Ecotoxicology and Environmental Safety.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802)  V.1-    1977-  Volume(issue)/page/year:
   6,149,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 5620 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,355,1983

其他信息

  • TPTZ不溶于水(0.03 g/100 ml)和有机溶剂,但是易溶于乙醇和稀酸pKa为3.1(µ=0.1 mol/l KCL,25℃)。

系列性分类