N-(1-Cyclohexen-1-Yl)Morpholine 1-吗啉基-1-环己烯

CAS 670-80-4 MFCD00006163

化学结构图

670-80-4
SMILES: C1=C(N2CCOCC2)CCCC1

化学属性

Mol. FormulaC10H17NO
Mol. Weight167.25
Refractive index1.5130 to 1.5160
Boiling Point118120°C at 760 mmHg
Density0.995
Flash Point68°C(lit.)
TSCAYes

别名和识别编码

Chemical NameN-(1-Cyclohexen-1-Yl)Morpholine
MDL NumberMFCD00006163
CAS Number670-80-4
Synonym N-(1-Cyclohexen-1-yl)morpholine {LY} N-(1-Cyclohexen-1-yl)morpholine {} {LY} N-(1-Cyclohexen-1-yl)morpholine {} {} {LY} N-(1-Cyclohexen-1-yl)morpholine {} {} {} {LY} N-(1-Cyclohexen-1-yl)morpholine {} {} {} {} {LY} N-(1-Cyclohexen-1-yl)morpholine {} {} {} {} {} {LY} N-(1-Cyclohexen-1-yl)morpholine {} {} {} {} {} {} {LY} N-(1-Cyclohexen-1-yl)morpholine {} {} {} {} {} {} {} {LY} N-(1-Cyclohexen-1-yl)morpholine {} {} {} {} {} {} {} {} {LY} N-(1-Cyclohexen-1-yl)morpholine {} {} {} {} {} {} {} {} {} {LY} N-(1-Cyclohexen-1-yl)morpholine {} {} {} {} {} {} {} {} {} {} {LY} N-(1-Cyclohexen-1-yl)morpholine {} {} {} {} {} {} {} {} {} {} {} {LY} N-(1-Cyclohexen-1-yl)morpholine {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(1-Cyclohexen-1-yl)morpholine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(1-Cyclohexen-1-yl)morpholine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(1-Cyclohexen-1-yl)morp
PubChem Substance ID69589
EC Number211-579-6
Beilstein Registry Number118696
Chemical Name Translation1-吗啉基-1-环己烯
Reaxys-RN118696
InChIKeyIIQFBBQJYPGOHJ-UHFFFAOYSA-N
InChIInChI=1S/C10H17NO/c1-2-4-10(5-3-1)11-6-8-12-9-7-11/h4H,1-3,5-9H2
LabNetwork Molecule IDLN01307663
Canonical SMILESC1CC=C(CC1)N2CCOCC2
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分类

  • {SNA} Building Blocks, C4 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Morpholines/Thiomorpholines

相关文献及参考

  • Useful synthetic intermediate by reaction at the 2-position with various electrophiles. Reviews: Applications of enamines in organic synthesis: Synthesis, 510 (1970). Synthesis of carbonyl compounds from enamines by alkylation, acylation or addition to Michael acceptors: Synthesis, 517 (1983). Advances in enamine chemistry: Tetrahedron, 38, 1975, 3363 (1982). For an example of C-acylation using an acid chloride in the presence of triethylamine, see: Org. Synth. Coll., 5, 533 (1973).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Hazard Codes Xi
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 图谱信息:1-吗啉基-1-环己烯(670-80-4)质谱(MS) 1-吗啉基-1-环己烯(670-80-4)红外图谱(IR1)
  • MOL 文件:670-80-4.mol
  • TCI Shanghai:1-吗啉基-1-环己烯 1-Morpholino-1-cyclohexene,>;90.0%(GC)(670-80-4)
  • 1-吗啉基-1-环己烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0956 1-吗啉基-1-环己烯 1-Morpholino-1-cyclohexene 500ML 1840元 2014/06/02 C0956 1-吗啉基-1-环己烯 1-Morpholino-1-cyclohexene 25ML 245元 2010/05/25 B22004 1-(4-吗啡啉)环己烯, 98% 4-(1-Cyclohexen-1-yl)morpholine, 98% 25g 295元
  • F:9
  • MSDS 信息:N-(1-Cyclohexen-1-yl)morpholine(670-80-4).msds
  • Alfa Aesar:1-(4-吗啡啉)环己烯,98% 4-(1-Cyclohexen-1-yl)morpholine, 98%(670-80-4)
  • Sigma Aldrich:670-80-4(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Morpholines/Thiomorpholines 吗啉/硫吗啉
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Morpholines/Thiomorpholines 吗啉/硫吗啉
  5. C4 to C10 - Morpholines/Thiomorpholines

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