Pentachloropyridine 五氯吡啶

CAS 2176-62-7 MFCD00006230

化学结构图

2176-62-7
SMILES: Clc1nc(Cl)c(Cl)c(Cl)c1Cl

化学属性

Mol. FormulaC5Cl5N
Mol. Weight251.31
Density1.764
Vapor Density8.4 (vs air)
Vapor Pressure0.01 mmHg ( 20 °C)
Melting Point124°C
TSCAYes
Solubility不溶于水,溶于热乙醇、,溶于乙醇、乙醚。
Boiling Point282.3°C at 760 mmHg

别名和识别编码

Chemical NamePentachloropyridine
Synonym Perchloropyridine {LY} Perchloropyridine {} {LY} Perchloropyridine {} {} {LY} Perchloropyridine {} {} {} {LY} Perchloropyridine {} {} {} {} {LY} Perchloropyridine {} {} {} {} {} {LY} Perchloropyridine {} {} {} {} {} {} {LY} Perchloropyridine {} {} {} {} {} {} {} {LY} Perchloropyridine {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} Perchloropyridine {} {} {} {} {} {} {} {} {} {LY} Perchloropyridine {} {} {} {} {} {} {} {} {} {} {LY} Perchloropyridine {} {} {} {} {} {} {} {} {} {} {} {LY} Perchloropyridine {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perchloropyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perchloropyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perchloropyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perchloropyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number2176-62-7
EC Number218-535-5
Beilstein Registry Number155197
MDL NumberMFCD00006230
PubChem Substance ID16584
Reaxys-RN155197
Chemical Name Translation五氯吡啶
Wiswesser Line NotationT6NJ BG CG DG EG FG
LabNetwork Molecule IDLN00201474
InChIInChI=1S/C5Cl5N/c6-1-2(7)4(9)11-5(10)3(1)8
Canonical SMILESClC1=NC(Cl)=C(Cl)C(Cl)=C1Cl
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分类

  • {uni_hamburg} no charge; nitrogen heterocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Building Blocks, C5, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Pyridines

相关文献及参考

  • Short: III/20a
  • Short: EINECS
  • Beilstein:20(5)5,422
  • Reacts with magnesium at the 4-position to give the Grignard reagent, convertible to the corresponding organocopper reagent by reaction with copper(I) halides: Org. Prep. Proced. Int., 1, 187 (1969).

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下,戴呼吸防护。
  • P301+P312
  • P301+P312+P330
  • P302+P350
  • P302+P352
  • P304+P340
  • P304+P341
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P333+P313
  • P337+P313
  • P342+P311
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSUT7000000
Packing GroupIII
UN Number UN3077
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes Xn Xn,Xi Xi
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 235 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - antipsychotic
   Liver - fatty liver degeneration
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   11,361,1967

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 435 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0536503

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 图谱信息:五氯吡啶(2176-62-7)核磁图( 13 CNMR) 五氯吡啶(2176-62-7)质谱(MS) 五氯吡啶(2176-62-7)红外图谱(IR2) 五氯吡啶(2176-62-7)红外图谱(IR1)
  • 五氯吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1661 五氯吡啶 Pentachloropyridine 25G 273元 2010/06/21 160220050 五氯吡啶 Pentachloropyridine 98% 5 GR 231元 2010/06/21 160221000 五氯吡啶 Pentachloropyridine 98% 100 GR 805元
  • 外观性质:白色小片状固体。
  • 上游原料:氯
  • TCI Shanghai:五氯吡啶 Pentachloropyridine,>;98.0%(GC)(2176-62-7)
  • 蒸气密度:8.4 (vs air)
  • 下游产品:毒死蜱 --> 甲基毒死蜱
  • Sigma Aldrich:2176-62-7(sigmaaldrich)
  • MSDS 信息:五氯吡啶(2176-62-7).msds
  • 用途一:用作农药及医药中间体,可用于生产毒死蜱、二氯吡啶酸等杀虫剂
  • 海关编码:29333999
  • Acros Organics:五氯吡啶 Pentachloropyridine, 98%(2176-62-7)
  • MOL 文件:2176-62-7.mol
  • 用途二:农药中间体。
  • Alfa Aesar:五氯吡啶,98% Pentachloropyridine, 98%(2176-62-7)
  • 蒸气压:0.01 mm Hg ( 20 °C)

系列性分类


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