3-Bromopyridine 3-溴吡啶

CAS 626-55-1 MFCD00006373

化学结构图

626-55-1
SMILES: Brc1cccnc1

化学属性

Mol. FormulaC5H4BrN
Mol. Weight158.00
Boiling Point168.2°C at 760 mmHg
Density1.640
Refractive index1.5680 to 1.5720
Flash Point52°C
TSCAYes
Melting Point-27°C
Stability对光敏感

别名和识别编码

Chemical Name3-Bromopyridine
CAS Number626-55-1
Alfabeta NameBROMOPYRIDINE 3-
MDL NumberMFCD00006373
Synonym 3-Bromopyridine {LY} 3-Bromopyridine {} {LY} 3-Bromopyridine {} {} {LY} 3-Bromopyridine {} {} {} {LY} 3-Bromopyridine {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromopyridine {} {} {} {} {} {} {} {} {} {} {} {}
EC Number210-952-0
Beilstein Registry Number105880
PubChem Substance ID12286
Reaxys-RN105880
Chemical Name Translation3-溴吡啶
LabNetwork Molecule IDLN00170216
InChIInChI=1S/C5H4BrN/c6-5-2-1-3-7-4-5/h1-4H
Canonical SMILESBrC1=CC=CN=C1
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分类

  • {SNA} Building Blocks, C5, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Pyridines
  • {SNA} Baran Sulfinate Building Block Collection, Building Blocks, C5, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Pyridines, {Untitled Section}
  • Heterocycles
  • {SNA} Baran Sulfinate Building Block Collection, Building Blocks, C5, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Pyridines
  • {uni_hamburg} no charge; nitrogen heterocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • Aromatics

产品应用

  • Pyridine as novel substrate for regioselective oxygenation with aromatic peroxygenase from Agrocybe aegerita.

相关文献及参考

  • Beilstein:20,233
  • Colby, J., et al.: Biochem. J., 165, 395 (1977),
  • Short: II/14a
  • Short: III/35B
  • Short: III/38B
  • Undergoes lithiation with LDA at low temperatures in the 4-position: Heterocycles, 35, 151 (1993). Formation of the Grignard by Mg exchange with i-PrMgCl: Tetrahdron Lett., 40, 4339 (1999). Transmetallation of the lithiated derivative with ZnCl2 followed by treatment with an electrophile has been described, as a route to 4-substituted 3-bromopyridines: Org. Lett., 3, 835 (2001).

安全信息

Warnings LIGHT SENSITIVE, IRRITANT-HARMFUL, FLAMMABLE
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R10 Flammable 易燃
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P312
  • P301+P312+P330
  • P302+P352
  • P302+P352+P312+P362+P364
  • P303+P361+P353
  • P304+P312
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H301 Toxic if swallowed 吞食有毒
  • H302 Harmful if swallowed 吞食有害
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupIII
UN Number 1993 UN2810
Hazard Codes 3
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class3

其他信息

  • 储运特性:库房通风低温干燥; 与酸,氧化剂分开存放
  • MOL 文件:626-55-1.mol
  • 下游产品:3-吡啶甲醛 --> 3-苯基哌啶 --> 3-吡啶-3-基苯甲酸 --> 3-(3-吡啶基)丙酸 --> 吡啶-3-硼酸 --> 3-(3-吡啶)丙烯酸 --> 3-溴吡啶-4-醛
  • MSDS 信息:3-Pyridyl bromide(626-55-1).msds
  • 灭火剂:泡沫、二氧化碳、雾状水
  • 用途一:抗抑郁药盐酸齐美定的中间体。
  • 爆炸物危险特性:有强碱性; 与乙酸-过氧化氢混合物反应爆炸(50℃以上时)
  • Acros Organics:3-溴吡啶 3-Bromopyridine, 99%(626-55-1)
  • Hazard Note:Toxic/Flammable/Irritant
  • 图谱信息:3-溴吡啶(626-55-1)质谱(MS) 3-溴吡啶(626-55-1)核磁图( 1 HNMR) 3-溴吡啶(626-55-1)红外图谱(IR1) 3-溴吡啶(626-55-1)核磁图( 13 CNMR)
  • Sigma Aldrich:626-55-1(sigmaaldrich)
  • 可燃性危险特性:热分解排出有毒氮氧化物和溴化物
  • 3-溴吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0651 3-溴吡啶(含稳定剂铜屑) 3-Bromopyridine (stabilized with Copper chip) 25G 463元 2010/06/21 107411000 3-溴吡啶 3-Bromopyridine 99% 100 ML 2200元 2010/06/21 107410250 3-溴吡啶 3-Bromopyridine 99% 25 ML 721元
  • TCI Shanghai:3-溴吡啶(含稳定剂铜屑) 3-Bromopyridine (stabilized with Copper chip),>;98.0%(GC)(626-55-1)
  • 水中溶解度:31 g/l (25 C)，溶于大多数有机溶剂。
  • 海关编码:29333999
  • Alfa Aesar:3-溴吡啶,98+% 3-Bromopyridine, 98+%(626-55-1)
  • 存储注意事项:光敏感
  • 检测方法:GC,HPLC,NMR
  • F:8
  • 类别:爆炸物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Halogenated Heterocycles 卤代杂环
  5. Pyridines - Halogenated Heterocycles
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Halogenated Heterocycles 卤代杂环
  5. Pyridazines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶

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