2-Nitrobenzenesulfenyl Chloride 2-硝基苯亚磺酰氯

CAS 7669-54-7 MFCD00007128

化学结构图

7669-54-7
SMILES: O=[N+]([O-])c1ccccc1SCl

化学属性

Mol. FormulaC6H4ClNO2S
Mol. Weight189.62
Melting Point70-75 °C
TSCAYes
Solubility分解
Boiling Point350 °C at 760 mmHg

别名和识别编码

Chemical Name2-Nitrobenzenesulfenyl Chloride
Synonym 2-Nitrophenyl hypochlorothioite {LY} 2-Nitrophenyl hypochlorothioite {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {} {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {} {} {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Nitrophenyl hypochlorothioite {} {} {} {} {
MDL NumberMFCD00007128
CAS Number7669-54-7
EC Number231-644-2
Beilstein Registry Number473741
Chemical Name Translation2-硝基苯亚磺酰氯
Reaxys-RN473741
PubChem Substance ID24319
InChIKeyNTNKNFHIAFDCSJ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00730736
InChIInChI=1S/C6H4ClNO2S/c7-11-6-4-2-1-3-5(6)8(9)10/h1-4H
Canonical SMILESClSC1=CC=CC=C1[N+]([O-])=O
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different b

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Packing GroupII
UN Number 3261
Risk Statements
  • R34 Causes burns 会导致灼伤
Storage condition 2-8°C {LY} 2-8°C Moisture Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Codes 8
Hazard Class8
GHS Symbol
Signal word Danger
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛

其他信息

  • MOL 文件:7669-54-7.mol
  • 上游原料:四氯化碳 --> 1,3-二硝基苯
  • 图谱信息:2-硝基苯硫氯(7669-54-7)红外图谱(IR1)
  • TCI Shanghai:2-硝基苯硫氯 2-Nitrophenylsulfenyl Chloride [N-Protecting Agent for Peptides Research],>;95.0%(T)(7669-54-7)
  • 2-硝基苯硫氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0363 2-硝基苯硫氯[肽研究用N-保护试剂] 2-Nitrophenylsulfenyl Chloride [N-Protecting Agent for Peptides Research] 25G 1300元 2014/06/02 N0363 2-硝基苯硫氯[肽研究用N-保护试剂] 2-Nitrophenylsulfenyl Chloride [N-Protecting Agent for Peptides Research] 100G 3880元 2010/06/21 161330500 2-硝基苯硫氯 2-Nitrobenzenesulfenyl chloride 99% 50 GR 2480元
  • Acros Organics:2-硝基苯次磺酰氯 2-Nitrobenzenesulfenyl chloride, 99%(7669-54-7)
  • 用途二:肽合成的N-保护基。
  • Alfa Aesar:2-硝基苯亚磺酰氯,98% 2-Nitrobenzenesulfenyl chloride, 98%(7669-54-7)
  • 方法一:将干燥氯气通入二硫-2,2-二（硝基苯）、四氯化碳和少许碘的混合物中，温度保持在50-60℃。反应液冷至5℃，即结晶析出，得邻硝基苯硫氯，收率61-71%。
  • Sigma Aldrich:7669-54-7(sigmaaldrich)
  • 敏感性:Moisture Sensitive
  • 用途一:用作医药、染料中间体
  • MSDS 信息:2-Nitrophenylsulfenyl chloride(7669-54-7).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Nitro Compounds 硝基化合物
  1. Life Science 生命科学
  2. Biochemistry / Glyco-Chemistry
  3. Peptide Synthesis
  1. sulfenic acid halide

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