2-Nitrobenzyl Bromide 2-硝基苄溴

CAS 3958-60-9 MFCD00007184

化学结构图

3958-60-9
SMILES: O=[N+]([O-])c1ccccc1CBr

化学属性

Mol. FormulaC7H6BrNO2
Mol. Weight216
Density1.652
Melting Point44-46°C
Flash Point>110°C
TSCANo
Solubility不溶
Boiling Point275.2°C at 760 mmHg

别名和识别编码

Chemical Name2-Nitrobenzyl Bromide
CAS Number3958-60-9
Alfabeta NameNITROBENZYLBROMIDE 2-
MDL NumberMFCD00007184
EC Number223-558-9
Beilstein Registry Number638991
Synonym 1-(Bromomethyl)-2-nitrobenzene {LY} 1-(Bromomethyl)-2-nitrobenzene 1-Bromomethyl-2-nitro-benzene 1-Nitro-2-(bromomethyl)benzene 2-(BROMOMETHYL)NITROBENZENE 2-Benzyl bromide 2-NITROBENZYL BROMIDE 2-Nitrobenzyl 2-硝基溴化苄 2-硝基溴苄 2-硝基苄基溴 2-硝基苯甲基溴 2-硝基苯甲基溴, 98+% ALPHA-BROMO-2-NITROTOLUENE ALPHA-BROMO-O-NITROTOLUENE Benzene, 1-(bromomethyl)-2-nitro- NITROBENZYL-2 BROMIDE O-NITROBENZYL BROMIDE a-Bromo-2-nitrotoluene alpha-Bromo-2-nitrotoluene {} {LY} 1-(Bromomethyl)-2-nitrobenzene {} {} {LY} 1-(Bromomethyl)-2-nitrobenzene {} {} {} {LY} 1-(Bromomethyl)-2-nitrobenzene {} {} {} {} {LY} 1-(Bromomethyl)-2-nitrobenzene {} {} {} {} {} {LY} 1-(Bromomethyl)-2-nitrobenzene {} {} {} {} {} {} {LY} 1-(Bromomethyl)-2-nitrobenzene
PubChem Substance ID77569
Reaxys-RN638991
Chemical Name Translation2-硝基苄溴
InChIKeyHXBMIQJOSHZCFX-UHFFFAOYSA-N
LabNetwork Molecule IDLN00007847
InChIInChI=1S/C7H6BrNO2/c8-5-6-3-1-2-4-7(6)9(10)11/h1-4H,5H2
Canonical SMILESO=[N+](C1=CC=CC=C1CBr)[O-]
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Nitro Compounds, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • Photosensitive protecting reagent for alcohols, acids, phenols etc: J. Am. Chem. Soc., 91, 5694 (1969); J. Org. Chem., 37, 2281, 2285 (1972); Compare 4,5-Dimethoxy-2-nitrobenzyl­ alcohol, L00719. Has also been recommended for the protection of the imidazole function in histidine containing peptides: J. Am. Chem. Soc., 97, 440 (1975). See Appendix 6. It has been investigated as a photocleavable protecting group for various N-heterocycles: Tetrahedron Lett., 39, 359 (1998). For reviews of photoremovable groups in organic synthesis, see: Synthesis, 1 (1980); Org. Photochem., 9, 225 (1987).
  • Beilstein:5(1)164

安全信息

Warnings IRRITANT
Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R5 Heating may cause an explosion 加热会引起爆炸
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Packing GroupII
UN Number 3261 UN 3261 8/PG 2
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes 8 C
Hazard Class8
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 方法一:将四氯化碳、邻硝基甲苯及偶氮二异丁腈的水溶液加入反应罐内,搅拌加热,滴加溴的四氯化碳溶液,保持回流至滴加完毕,继续回流5-6h,溴化生成邻硝基苄基溴。
  • 下游产品:
  • 检测方法:GC
  • MSDS 信息:2-Nitrobenzyl bromide(3958-60-9).msds
  • 存储注意事项:湿度敏感
  • 上游原料:四氯化碳 --> 偶氮二异丁腈 --> 2-硝基甲苯
  • TCI Shanghai:2-硝基苄溴 2-Nitrobenzyl Bromide,>;98.0%(GC)(3958-60-9)
  • Sigma Aldrich:3958-60-9(sigmaaldrich)
  • 海关编码:29049085
  • Alfa Aesar:2-硝基苯甲基溴,98+% 2-Nitrobenzyl bromide, 98+%(3958-60-9)
  • F:4.8-19-21
  • Acros Organics:2-硝基苄溴 2-Nitrobenzyl bromide, 97%(3958-60-9)
  • MOL 文件:3958-60-9.mol
  • 2-硝基苄溴价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0404 2-硝基苄溴 2-Nitrobenzyl Bromide 5G 260元 2014/06/02 N0404 2-硝基苄溴 2-Nitrobenzyl Bromide 25G 850元 2010/06/21 148310050 2-硝基苄溴 2-Nitrobenzyl bromide 97% 5 GR 530元
  • 用途一:有机合成中间体。用于生产祛痰剂溴已胺盐酸盐。

系列性分类


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