3,4-Dichloronitrobenzene 3,4-二氯硝基苯

CAS 99-54-7 MFCD00007207

化学结构图

99-54-7
SMILES: O=[N+]([O-])c1ccc(Cl)c(Cl)c1

化学属性

Mol. FormulaCl2C6H3NO2
Mol. Weight192
Boiling Point255-256
Melting Point39-41
Flash Point123°(253°F)
TSCAYes
Solubility151 MG/L (20 ºC)
Density1.422

别名和识别编码

Chemical Name3,4-Dichloronitrobenzene
Synonym 1-硝基-3,4-二氯苯 1,2-dichloro-4-nitro-benzene 1，2-二氯-4-硝基苯 4-Chloro-o-dichlorobenzene 1,2-二氯-4-硝基苯 3,4-Dichlornitrobenzen Benzene, 1,2-dichloro-4-nitro- 不对称硝基邻二氯苯 3,4-DICHLORONITROBENZENE PESTANAL LABOTEST-BB LT00436959 3,4-dichloronitrobenzene dichloro-1,2nitro-4benzene 1-Nitro-3,4-dichlorobenzene ASYM-NITRO-O-DICHLOROBENZENE 3,4-Dichloronitrobenzene, asym.-Nitro-o-dichlorobenzene 3,4-DICHLORO-1-NITROBENZENE 1,2-dichloro-4-nitrobenzene 3,4-Dichloronitrobenzene 3,4-二氯硝基苯 不对称硝基邻二氯苯 3,4-DICHLORONITROBENZENE 1,2-DICHLORO-4-NITROBENZENE 1,2-二氯代-4-硝基苯 3, ai3-03268(usda)
CAS Number99-54-7
PubChem Substance ID7443
EC Number202-764-2
Beilstein Registry Number1818163
MDL NumberMFCD00007207
Reaxys-RN1818163
Chemical Name Translation3,4-二氯硝基苯
Wiswesser Line NotationWNR CG DG
LabNetwork Molecule IDLN00224536
InChIInChI=1S/C6H3Cl2NO2/c7-5-2-1-4(9(10)11)3-6(5)8/h1-3H
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分类

  • Building Blocks, Chemical Synthesis, Nitro Compounds, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Alphabetical Index of Analytical Standards,
  • {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, D, DIA - DIC, Environmenta

相关文献及参考

  • Beil. 5 ,IV,726
  • Aldrich MSDS 1 , 626:C / Corp MSDS 1 (1), 1148:A / FT-IR 1 (1), 1355:C / FT-IR 2 (2), 2290:D / FT-NMR 1 (2), 725:C / IR-Spectra (2), 717:F / IR-Spectra (3), 819:C / NMR-Reference 2 (1), 1159:B / RegBook 1 (1), 1575:C / Sax 6 , 953 / Structure Index 1 , 245:D:4 / Vapor Phase 3 , 1203:C
  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: IV/16 Title: Surface tension of pure liquids and binary mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/16 Year: 1997 Keyword: organic compounds; surface tension; liquids; mixtures ISBN: 3-540-63276-X ISBN: 978-3-540-63276-4 Internet Resource: DOI:10.1007/b60566 RefComment: VII, 439 pages.
  • Short: IV/1a Title: Densities of Liquid Systems: Nonaqueous Systems and Ternary Aqueous Systems Author: Lacmann, R.; Synowietz, C. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/1a Year: 1974 ISBN: 3-540-06269-6 ISBN: 978-3-540-06269-1 Internet Resource: DOI:10.1007/b20003 RefComment: X, 716 pages. Hardcover Abstract: Volume IV/1 contains information on the densities of liquid systems. It may be consi

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes
RTECSCZ5250000
Precautionary statements
  • P304+P340+P312
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P308+P313
  • P403+P233
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P405 Store locked up. 上锁保管。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P304+P340
  • P301+P312+P330
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
Signal word
UN Number UN3077 1578
Safety Statements
Risk Statements
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
  • R51/53
  • R22 Harmful if swallowed 吞咽有害
  • R36 Irritating to eyes 刺激眼睛
Packing GroupIII
Hazard Class6.1
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 10 gm/m3/4H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - effect, not otherwise
   specified
   Behavioral - somnolence (general depressed activity)
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0533734

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 400 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - muscle weakness
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientifi

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >200 mg/kg
TOXIC EFFECTS :
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0533734

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Cleari

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 250 ug/plate
REFERENCE :
   SAIGBL Sangyo Igaku.  Japanese Journal of Industrial Health.  (Nippon Sangyo
   Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160,
   Japan)  V.1-    1959-  Volume(issue)/page/year: 29,34,1987

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Parenteral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 200 ppm
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7,677,1985

其他信息

  • 凝固点:30~31℃
  • 毒性分级:中毒
  • 下游产品:氟哌酸 --> 3,4-二氯苯胺 --> 2-氯-4-硝基苯酚 --> 敌稗 --> 敌草隆
  • 刺激数据:皮肤-兔子 500 毫克/24小时 轻度; 眼睛-兔子 100 毫克/24小时 中度
  • TCI Shanghai:3,4-二氯硝基苯 3,4-Dichloronitrobenzene,>;97.0%(GC)(99-54-7)
  • 类别:有毒物品
  • Acros Organics:3,4-二氯硝基苯 3,4-Dichloronitrobenzene, 95%(99-54-7)
  • 用途一:是3-氯-4-氟硝基苯、3-氯-4-氟苯胺、3,4-二氯苯胺等有机化工产品的重要中间体
  • Sigma Aldrich:99-54-7(sigmaaldrich)
  • 用途二:医药、农药中间体。
  • 方法一:有两种主要生产方法。一是由邻二氯苯硝化，硝化温度可以控制在0℃左右，也可以在稍高于室温时进行；另一种生产方法是对硝基氯苯氯化。
  • 可燃性危险特性:明火可燃;燃烧释放有毒氮氧化物和氯化物烟雾;与氧化剂起作用
  • 职业标准:STEL 1 毫克/立方米
  • 海关编码:29049085
  • 图谱信息:3,4-二氯硝基苯(99-54-7)红外图谱(IR3) 3,4-二氯硝基苯(99-54-7)质谱(MS) 3,4-二氯硝基苯(99-54-7)红外图谱(IR2) 3,4-二氯硝基苯(99-54-7)核磁图( 13 CNMR) 3,4-二氯硝基苯(99-54-7)Raman光谱 3,4-二氯硝基苯(99-54-7)红外图谱(IR1) 3,4-二氯硝基苯(99-54-7)核磁图( 1 HNMR)
  • 上游原料:邻二氯苯 --> 4-硝基氯苯
  • MSDS 信息:3,4-二氯硝基苯(99-54-7).msds
  • 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
  • 外观性质:针状结晶。
  • 急性毒性:口服-大鼠 LD50: >;500 毫克/公斤; 口服-小鼠 1384 毫克/公斤
  • 灭火剂:雾状水、泡沫、二氧化碳、砂土。
  • Alfa Aesar:1，2-二氯-4-硝基苯,99% 1,2-Dichloro-4-nitrobenzene, 99%(99-54-7)
  • MOL 文件:99-54-7.mol
  • 3,4-二氯硝基苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0388 3,4-二氯硝基苯 3,4-Dichloronitrobenzene 25G 137元 2014/06/02 D0388 3,4-二氯硝基苯 3,4-Dichloronitrobenzene 500G 604元 2010/06/21 113530050 3,4-二氯硝基苯 3,4-Dichloronitrobenzene 95% 5 GR 224元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Nitro Compounds 硝基化合物
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Alpha sort - Pesticides & Metabolites
  7. D - Alpha sort
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. D - Alphabetic
  5. DIA - DIC - D
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Isocyanides

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