CAS 100-01-6 MFCD00007858-4-Nitroaniline 4-硝基苯胺 -LabNovo

4-Nitroaniline 4-硝基苯胺

CAS 100-01-6 MFCD00007858

化学结构图

SMILES: Nc1ccc([N+](=O)[O-])cc1

化学属性

Mol. Formula	C6
Mol. Weight	138
Density	1.44
Flash Point	165°(329°F)
Solubility	不溶于水，微溶于苯，溶于乙醇、乙醚、丙酮，易溶于醇。
TSCA	Yes
Boiling Point	332°C(lit.)
Melting Point	147.0 to 150.0 deg-C
Stability	对光敏感
Appearance	crystalline

别名和识别编码

Chemical Name	4-Nitroaniline
CAS Number	100-01-6
MDL Number	MFCD00007858
EC Number	202-810-1
Merck Number	6584
Beilstein Registry Number	12,711
Synonym	{uni_hamburg} 4-nitro-benzenamin 4-硝基苯胺;1-氨基-4-硝基苯 Naphtoelan Red GG Base { 冰染重氮组分37 Aniline, p-nitro- benzenamine, 4-nitro- 4-nitrobenzenamine P-AMINONITROBENZENE Azoamine Red ZH 1-Amino-4-nitrobenzene P-NITRANILINE p-Aminonitrobenzene PNA C.I. Developer 17 4-Nitrophenylamine 4-Nitro-1-aminobenzene p-Nitroaniline; p-Nitr C.I. Azoic Diazo Component 37 P-NITROANILINE 1-氨基-4-硝基苯 Nitrazol CF extra Diazo Fast Red GG 对硝基苯胺 aniline, p-nitro {uni_ham 4-nitro-anilin Sh 4-硝基苯胺，1-氨基-4-硝基苯 p-Nitraniline Aniline, p 4-Nitro-phenylamine Fast Red 2G Salt {u Fast Red P Salt {C Fast Red Base GG Fast Red GG Bas p-Nitrophenylamine 1-AMINO-4-NITROBENZENE Fast Red 2G Base Fast Red GG Salt Devol Red GG 4-硝基苯胺 Fast Red Base 2J 4-Aminonitrobenzene Azofix Red GG Salt 對硝基苯胺 4-nitro-aniline Fast Red P Base {Chemicalbook C.I. 37035 aniline 4-Nitroaminobenzol AURORA KA-7786 Shinnippon Fast Red GG Base 4-Nitro aniline p-Nitroaniline AKOS 92446 对硝基苯胺 4-NITRO Fast Red MP Base 4 (4-Nitro)aniline p-Nitraniline 对硝极苯胺对硝基苯胺标准溶液 4-Amino-1-nitrobenzene Aniline, 4-nitro-
PubChem Substance ID	87573507
Chemical Name Translation	4-硝基苯胺
Wiswesser Line Notation	ZR DNW
LabNetwork Molecule ID	LN00196322
Reaxys-RN	508690
InChI	InChI=1S/C6H6N2O2/c7-5-1-3-6(4-2-5)8(9)10/h1-4H,7H2

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产品应用

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安全信息

Hazard statements

H301 Toxic if swallowed 吞食有毒
H301+H311+H331
H311 Toxic in contact with skin 皮肤接触中毒
H331 Toxic if inhaled 吸入中毒
H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。

Hazard Codes T T,F F,T

GHS Symbol

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P301+P310+P330
P302+P352+P312+P361+P364
P304+P340+P311
P308+P311
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word

WGK Germany2

RTECSBY7000000

Safety Statements

S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S7 Keep container tightly closed 保存在严格密闭容器中；
S1/2 None 上锁保管并避免儿童触及；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；

UN Number 1661

Risk Statements

R52/53
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R33 Danger of cumulative effects 有累积作用的危险
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Packing GroupII

Storage condition Store at R.T. 密封保存。密封避光保存。

Hazard Class6.1

Warnings 危化品目录(2015)

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 51500 mg/kg/2Y-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Vascular - tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-418,1993

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,92,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,355,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 450 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   VKMGA7 Voprosy Kommunal'noi Gigieny.  Problems of Communal Hygiene.  (Kiev,
   USSR)  V.6, 1966. For publisher information, see GNAMAP.
   Volume(issue)/page/year: 6,89,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 810 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   42,417,1977

TYPE OF TES

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 173 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 333 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 5(Suppl
   1),3,1983

TYPE OF TEST            : Phage inhibition capacity
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 100 mmol/L
REFERENCE :
   MDMIAZ Medycyna Doswiadczalna i Mikrobiologia.  For English translation, see
   EXMMAV.  (Ars Polona, POB 1001, 00-068 Warsaw 1, Poland)  V.1-    1949-
   Volume(issue)/page/year: 31,11,1979

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 5 mg/disc
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 170,11,1986

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 1500 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 173,233,1986

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 50 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 44,9,1977

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 9600 mg/kg
SEX/DURATION            : female 6-13 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured
   before birth)
   Reproductive - Effects on Newborn - live birth index (measured after birth)
   Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight
   gain)
REFERENCE :
   TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis.  (Alan R. Liss, Inc.,
   41 E. 11th St., New York, NY 10003)  V.1-    1980- Volume(issue)/page/year:
   7,29,1987

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1764 mg/kg
SEX/DURATION            : male 14 week(s) pre-mating
                          female 14 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - female fertility index (e.g. # females pregnant
   per # sperm positive females; # females pregnant per # females mated)
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   15,607,1990

Restrict 危险品

其他信息

用途二:用作分析试剂和染料中间体
用途三:对硝基苯胺是杀鼠剂灭鼠安、灭鼠优的中间体。
{
毒性分级:中毒
Alfa Aes
4-硝基苯胺价格(试剂级):更新日期产品编号产品名称
color:yellow
用途一:是各种直接、酸性、分散染料及颜料的中间体，重要的农药中间体
Hazard Note:Toxic
MSDS 信息:对硝基苯胺(100-01-6).msds
{Chemi
用途五:该品即冰染染料大红 GG色基，可作黑色盐 K，供棉麻织物染色、印花之用。但主要用作偶氮染料中间体。
方法一:其制备方法是将对氯硝基苯与氨在催化剂存在下反应或进行过氨化反应。
{Chemicalb
微有气味，易溶于甲醇，能溶于醇和醚，微溶于苯，不溶于水。溶于浓无机酸，几乎无色。1g溶于约1250ml水、45ml沸水、25ml乙醇、30ml乙醚。低毒，半数致死量（大鼠，经口）750mg/kg。有刺激性。
类别:有毒物品
下游产品:分散橙 29 --> 酸性绿A --> 6-氨基喹啉 --> 酸性黑 1 --> 对二硝基苯 --> 天狼黄 --> 安吖啶 --> 直接黑19 --> 2-溴-4-硝基苯胺 --> 弱酸性红棕 V --> 分散红 74 --> 5-溴-2-哌嗪基嘧啶 --> 直接耐晒黑G --> 6-硝基-3-氯喹啉 --> 灭鼠优 --> 直接深绿 2G --> 分散橙 73 --> 直接绿26 --> 酸性棕 75 --> 阳离子暗黄2RL --> 黑色盐K --> 分散红135 --> 直接灰D --> 酸性黑 210 --> 鲎试剂三肽 --> N-[5-[二(2-乙酰氧基)乙基]氨基]-2-[(2-氯-4-硝基苯基)偶氮]苯基丙酰胺 --> C.I.分散红17 --> 分散大红SE-R --> 黑色基LS --> 4-[(4-氨苯基)偶氮]-1-萘胺 --> 异氰酸对硝基苯 --> 阳离子可拔白性橙 D-3R --> 分散橙31号滤饼 --> 对硝基苯重氮氨基偶氮苯 --> 分散橙 25 --> 分散兰 183 --> 分散橙 2RL
用途六:该品即冰染
MOL 文件:100-01-6.mol
用途六:该品即冰染染料大红 GG色基，可作黑色盐 K，供棉麻织物染色、印花之用。但主要用作偶氮染料中间体。还可作农药和兽药的中间体，在医药工业中可用于生产氯硝柳胺、卡巴肿、硝基安定、喹啉脲硫酸盐等。还可用于生产对苯二胺、抗氧化剂和防腐剂等。用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。
检测方法:HPL
用途四:该品即冰染染料大红 GG色基，可作黑色盐 K，供棉麻织物染色、印花之用。但主要用作偶氮染料中间体，如用于生产直接墨绿B、酸性媒介棕G、酸性黑10B、酸性毛元ATT、毛
海关编码:29214210
4-硝基苯胺价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80089814 4-硝基苯胺（易制爆） 25g 15元 2011/08/23 80089824 4-硝基苯胺（易制爆） 25g 12元 2010/06/21 128371000 4-硝基苯胺 4-Nitroaniline 99% 100
TCI Shanghai:4-硝基苯胺 4-Nitroaniline,>;98.0%(GC)(100-01-6)
色指数:37035
防护措施:高毒。可引起比苯胺更强的血液中毒。如果同时存在有机溶剂或在饮酒后，这种作用更为强烈。急性中毒表现为开始头痛、颜面潮红、呼吸急促，有时伴有恶心、呕吐，之后肌肉无力、发绀、脉搏频弱及呼吸急促。
常规方法:内衬塑料袋、外套纤维板桶或铁桶包装，每桶30、35、40、45、50kg均可。贮运中防止曝晒、雨淋，防止压坏、碰破。贮存于干燥、通风处。按剧毒有机化合物规定贮运。

4-Nitroaniline 4-硝基苯胺

CAS 100-01-6 MFCD00007858

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化学结构图

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