Bis(Trimethylsilyl)Hydroxylamine N,O-双(三甲基硅基)羟胺

CAS 22737-37-7 MFCD00008266

化学结构图

22737-37-7
SMILES: C[Si](C)(C)ON[Si](C)(C)C

化学属性

Mol. Formula(CH3)3SiONHSi(CH3)3
Mol. Weight177
Refractive index1.4120 to 1.4140
Boiling Point78-80 °C/100 mmHg(lit.)
Density0.83 g/mL at 25 °C(lit.)
Flash Point29°C(lit.)
TSCANo

别名和识别编码

Chemical NameBis(Trimethylsilyl)Hydroxylamine
Synonym N,O-bis(trimethylsilyl)-hydroxylamine {uni_hamburg} N,O-双(三甲基硅基)羟胺 N,O-Bis-(trimethylsilyl)-hydroxylamin N,O-bis(trimethylsilyl)hydroxylamine 1,1,1-trimethyl-N-[(trimethylsilyl)oxy]silylamine Silanamine, 1,1,1-trimethyl-N-[(trimethylsilyl)oxy]-
PubChem Substance ID87564715
EC Number245-188-7
Beilstein Registry Number1920452
MDL NumberMFCD00008266
CAS Number22737-37-7
Reaxys-RN1920452
Chemical Name TranslationN,O-双(三甲基硅基)羟胺
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Hydroxylamines, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
  • Short: III/35F Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Silicon-29 Author: Marsmann, H.C.; Uhlig, F.; Gupta, R.R.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35F Year: 2008 Keyword: NMR; Si-29; chemical shifts; coupling constants; nuclear magnetic resonance; silicon-29 ISBN: 978-3-540-45277-5 (print) ISBN: 978-3-540-45278-2 (electronic) Internet Resource: DOI: 10.1007/978-3-540-45278-2 RefComment: X, 463 p. 40 illus., Hardcover RefComment: Written for: Scientists and engineers in the fields of physics, chemistry, and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, oriented by a magnetic field, and absorb

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+
  • P304+P340
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Hazard Codes C
Risk Statements
  • R10 Flammable 易燃
  • R34 Causes burns 会导致灼伤
Packing GroupII
UN Number 2920 UN2920
Storage condition 0-10 0-10°C
Hazard Class8/3

系列性分类


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